Non-Linear Enthalpy-Entropy Correlation for Nitrogen Adsorption in Zeolites
Abstract
:1. Introduction
2. Outline of the VTIR Method
3. Experimental Protocol
4. Results and Discussion
4.1. Dinitrogen Adsorption in Na-Y
4.2. Dinitrogen Adsorption in Ca-Y and Sr-Y
Author Contributions
Funding
Conflicts of Interest
References
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Sample Availability: Samples of the compounds are not available from the authors. |
Zeolite | −ΔH0 (kJ mol−1) | −ΔS0 b (J mol−1 K−1) | Ref |
---|---|---|---|
H-MCM-56 | 13 | 106 | [32] |
H-MCM-22 | 14.5 | 107 | [32] |
H-Y | 15.7 | 123 | [30] |
H-FER | 19.1 | 133 | [30,31] |
H-ZSM-5 | 19.7 | 127 | [30] |
Na-Y | 19.7 | 143 | This work |
Sr-Y | 29 | 150 | This work |
Ca-Y | 33.5 | 151 | This work |
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Delgado, M.R.; Arean, C.O. Non-Linear Enthalpy-Entropy Correlation for Nitrogen Adsorption in Zeolites. Molecules 2018, 23, 2978. https://doi.org/10.3390/molecules23112978
Delgado MR, Arean CO. Non-Linear Enthalpy-Entropy Correlation for Nitrogen Adsorption in Zeolites. Molecules. 2018; 23(11):2978. https://doi.org/10.3390/molecules23112978
Chicago/Turabian StyleDelgado, Montserrat R., and Carlos O. Arean. 2018. "Non-Linear Enthalpy-Entropy Correlation for Nitrogen Adsorption in Zeolites" Molecules 23, no. 11: 2978. https://doi.org/10.3390/molecules23112978