Two New Tetravacant Organometallic Keggin-Type Heteropolyoxomolybdates-Supported Manganese Carbonyl Derivatives
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis
2.2. Crystal Structures
2.3. Electrochemistry
2.4. UV–Vis Spectroscopy
2.5. IR Spectroscopy
2.6. Thermogravimetric Analysis
3. Experimental Section
3.1. Materials and General Methods
3.2. Synthesis of [(CH3)4N]6H6{MnII(GeMo8O31)[MnI(CO)3]2}2·12H2O (1)
3.3. Synthesis of [(CH3)4N]4H6{MnII(PMo8O31) [MnI(CO)3]2}2·14H2O (2)
3.4. Crystallography
4. Conclusions
Supplementary Materials
Acknowledgments
Authors Contributions
Conflicts of Interest
References
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Sample Availability: Samples of the compounds 1 and 2 are available from the authors. |
Year | Formula | Reference |
---|---|---|
2008 | Cs6[SiW11O39RuII(CO)]·8H2O | [19] |
2011 | (NH4)4[H4{[H2Mo8O30][Mn(CO)3]2}]·12H2O | [24] |
(NH4)4[{H6Mo8O30}−{Re(CO)3}2]·14H2O | ||
2013 | H6[Na(H2O)5]2{[H2W8O30][Mn(CO)3]2}·13H2O | [23] |
H2[Na(H2O)5]2[Na(H2O)4]2[Na(H2O)2]2{[H2W8O30][Re(CO)3]2} | ||
[Na(H2O)5]2[Na2(µ2-H2O)2(H2O)4]2[Mn(H2O)2]{[H2W8O30][Mn(CO)3]2} | ||
2016 | KH[(CH3)4N]3{[Re(CO)3]4[(μ2-OH)(μ3-O)(W5O18)]}·6H2O | [26] |
2013 | Na11H[Sb2W20O70{Re(CO)3}2]·34H2O | [21] |
Na11H[Bi2W20O70{Re(CO)3}2]·33H2O | ||
K9Na3[Sb2W20O70{Mn(CO)3}2]·32H2O | ||
K9Na3[Bi2W20O70{Mn(CO)3}2]·32H2O | ||
2013 | [P2W17O61{Re(CO)3}3{ORb(H2O)}(μ3-OH)]9− | [14] |
2014 | [P4W35O124{Re(CO)3}2]16− | [22] |
2012 | K8[(OC)3Mn(A-α-H2GeW9O34)]·10H2O | [20] |
K8[(OC)3Mn(A-α-H2SiW9O34)]·11H2O | ||
2014 | [(CH3)4N]5H23{(PW11O39){Re(CO)3}3(µ3-O)(µ2-OH)]4·24H2O | [27] |
2015 | {[PMo3O16][Re(CO)3]4}5− | [25] |
2016 | [(M4(H2O)10(XW9O33)2{Mn(CO)3}2]n− (X = Sb/Bi; Mn = Mn/Mn3.5W0.5) | [28] |
2015 | (NH4)3H3[{Mn(CO)3}(Mn(H2O)2(Mn(H2O)3)(TeW9O33)]2·31H2O | [29] |
Atoms | 1 | 2 |
---|---|---|
Mo | 5.99–6.09 | 6.17–6.62 |
Mn | 2.30 | 2.42 |
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Singh, V.; Zhang, Y.; Yang, L.; Ma, P.; Zhang, D.; Zhang, C.; Yu, L.; Niu, J.; Wang, J. Two New Tetravacant Organometallic Keggin-Type Heteropolyoxomolybdates-Supported Manganese Carbonyl Derivatives. Molecules 2017, 22, 1351. https://doi.org/10.3390/molecules22081351
Singh V, Zhang Y, Yang L, Ma P, Zhang D, Zhang C, Yu L, Niu J, Wang J. Two New Tetravacant Organometallic Keggin-Type Heteropolyoxomolybdates-Supported Manganese Carbonyl Derivatives. Molecules. 2017; 22(8):1351. https://doi.org/10.3390/molecules22081351
Chicago/Turabian StyleSingh, Vikram, Yujiao Zhang, Linping Yang, Pengtao Ma, Dongdi Zhang, Chao Zhang, Li Yu, Jingyang Niu, and Jingping Wang. 2017. "Two New Tetravacant Organometallic Keggin-Type Heteropolyoxomolybdates-Supported Manganese Carbonyl Derivatives" Molecules 22, no. 8: 1351. https://doi.org/10.3390/molecules22081351