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Molecules 2016, 21(8), 990;

Isolation of a Cyclic (Alkyl)(amino)germylene

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore
NTU-CBC Crystallography Facility, Nanyang Technological University Nanyang Link 21, Singapore 637371, Singapore
Author to whom correspondence should be addressed.
Academic Editor: Mitsuo Kira
Received: 7 July 2016 / Revised: 25 July 2016 / Accepted: 26 July 2016 / Published: 29 July 2016
(This article belongs to the Special Issue Advances in Silicon Chemistry)
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A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively. View Full-Text
Keywords: germylene; low-valent germanium; sulfur; TEMPO; nitrous oxide germylene; low-valent germanium; sulfur; TEMPO; nitrous oxide

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Wang, L.; Lim, Y.S.; Li, Y.; Ganguly, R.; Kinjo, R. Isolation of a Cyclic (Alkyl)(amino)germylene. Molecules 2016, 21, 990.

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