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Some Brief Notes on Theoretical and Experimental Investigations of Intramolecular Hydrogen Bonding

1
Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie Str., 50-383 Wrocław, Poland
2
Faculty of Physics, A. Mickiewicz University, Umultowska 85, 61-614 Poznan, Poland
3
Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, 141980 Dubna, Russia
4
Center for Magnetic Resonance, St. Petersburg State University, St. Petersburg 198504, Russia
*
Author to whom correspondence should be addressed.
Academic Editor: Steve Scheiner
Molecules 2016, 21(12), 1657; https://doi.org/10.3390/molecules21121657
Received: 22 October 2016 / Revised: 18 November 2016 / Accepted: 28 November 2016 / Published: 2 December 2016
(This article belongs to the Special Issue Intramolecular Hydrogen Bonding 2017)
A review of selected literature data related to intramolecular hydrogen bonding in ortho-hydroxyaryl Schiff bases, ortho-hydroxyaryl ketones, ortho-hydroxyaryl amides, proton sponges and ortho-hydroxyaryl Mannich bases is presented. The paper reports on the application of experimental spectroscopic measurements (IR and NMR) and quantum-mechanical calculations for investigations of the proton transfer processes, the potential energy curves, tautomeric equilibrium, aromaticity etc. Finally, the equilibrium between the intra- and inter-molecular hydrogen bonds in amides is discussed. View Full-Text
Keywords: intramolecular hydrogen bond; Schiff base; Mannich base; proton sponge; acetophenone; salicylamide; pyridoxal intramolecular hydrogen bond; Schiff base; Mannich base; proton sponge; acetophenone; salicylamide; pyridoxal
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MDPI and ACS Style

Sobczyk, L.; Chudoba, D.; Tolstoy, P.M.; Filarowski, A. Some Brief Notes on Theoretical and Experimental Investigations of Intramolecular Hydrogen Bonding. Molecules 2016, 21, 1657. https://doi.org/10.3390/molecules21121657

AMA Style

Sobczyk L, Chudoba D, Tolstoy PM, Filarowski A. Some Brief Notes on Theoretical and Experimental Investigations of Intramolecular Hydrogen Bonding. Molecules. 2016; 21(12):1657. https://doi.org/10.3390/molecules21121657

Chicago/Turabian Style

Sobczyk, Lucjan; Chudoba, Dorota; Tolstoy, Peter M.; Filarowski, Aleksander. 2016. "Some Brief Notes on Theoretical and Experimental Investigations of Intramolecular Hydrogen Bonding" Molecules 21, no. 12: 1657. https://doi.org/10.3390/molecules21121657

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