Next Article in Journal
Synthesis and Characterization of Two Sulfonated Resorcinarenes: A New Example of a Linear Array of Sodium Centers and Macrocycles
Previous Article in Journal
Chelation-Assisted Substrate-Controlled Asymmetric Lithiation-Allylboration of Chiral Carbamate 1,2,4-Butanetriol Acetonide
Previous Article in Special Issue
Optimization of Solid-Supported Glaser-Hay Reactions in the Microwave
Open AccessCommunication

Reactivity of Aryl Halides for Reductive Dehalogenation in (Sea)water Using Polymer-Supported Terpyridine Palladium Catalyst

Department of Chemistry, University of the Ryukyus, Okinawa 903-0213, Japan
*
Author to whom correspondence should be addressed.
Academic Editor: Fernando Albericio
Molecules 2015, 20(6), 9906-9914; https://doi.org/10.3390/molecules20069906
Received: 18 March 2015 / Accepted: 26 May 2015 / Published: 28 May 2015
(This article belongs to the Special Issue Organic Synthesis on Solid Phase)
A polymer-supported terpyridine palladium complex was prepared. The complex was found to promote hydrodechlorination of aryl chlorides with potassium formate in seawater. Generally, reductive cleavage of aryl chlorides using transition metal catalysts is more difficult than that of aryl bromides and iodides (reactivity: I > Br > Cl); however, the results obtained did not follow the general trend. Therefore, we investigated the reaction inhibition agents and found a method to remove these inhibitors. The polymeric catalysts showed high catalytic activity and high reusability for transfer reduction in seawater. View Full-Text
Keywords: palladium; polymer-support; hydrodechlorination; seawater palladium; polymer-support; hydrodechlorination; seawater
Show Figures

Graphical abstract

MDPI and ACS Style

Suzuka, T.; Sueyoshi, H.; Maehara, S.; Ogasawara, H. Reactivity of Aryl Halides for Reductive Dehalogenation in (Sea)water Using Polymer-Supported Terpyridine Palladium Catalyst. Molecules 2015, 20, 9906-9914.

Show more citation formats Show less citations formats

Article Access Map by Country/Region

1
Only visits after 24 November 2015 are recorded.
Back to TopTop