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Open AccessArticle

Copolymers of Vinyl-Containing Benzoxazine with Vinyl Monomers as Precursors for High Performance Thermosets

Department of Environmental and Life Sciences, Toyohashi University of Technology, Tempaku-cho, Toyohashi 441-8580, Japan
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Academic Editor: Atsushi Sudo
Molecules 2015, 20(4), 6488-6503; https://doi.org/10.3390/molecules20046488
Received: 27 February 2015 / Revised: 27 March 2015 / Accepted: 7 April 2015 / Published: 10 April 2015
(This article belongs to the Special Issue Ring-Opening Polymerization)
A benzoxazine containing a vinyl group (P-4va) was prepared by the reaction of phenol, 4-vinylaniline, and paraformaldehyde. A differential scanning calorimetry (DSC) study revealed that ring-opening polymerization of the benzoxazine and chain polymerization of the vinyl group occurred in the same temperature range. When 2,2'-azobisisobutyronitrile was added as a radical initiator to P-4va, however, only the vinyl groups were polymerized at lower temperature, giving oligo(P-4va) that contains pendent benzoxazine units. Radical copolymerization of P-4va with various vinyl monomers such as styrene, methyl methacrylate (MMA), and n-butyl acrylate (BuA) was examined. The chemical structure of the copolymers was confirmed by FT-IR and 1H-NMR to be one of polyolefins bearing benzoxazine units as the pendant groups. The weight-average molecular weights of the copolymers determined by size exclusion chromatography were to be in the range of 1900–51,500 depending on the comonomers. DSC of the copolymers showed that the maxima of the exothermic peaks corresponding to the ring-opening polymerization of the pendent benzoxazine units were observed in the temperature range of 229–250 °C. Thermal cure up to 240 °C of the copolymer films afforded homogenous transparent films with improved thermal properties. Tough cured film was obtained by the copolymerization with MMA, while a tough and flexible film was obtained by the copolymerization with BuA. View Full-Text
Keywords: benzoxazine; vinyl monomer; radical polymerization; high molecular weight benzoxazine; ring-opening polymerization benzoxazine; vinyl monomer; radical polymerization; high molecular weight benzoxazine; ring-opening polymerization
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Takeichi, T.; Thongpradith, S.; Kawauchi, T. Copolymers of Vinyl-Containing Benzoxazine with Vinyl Monomers as Precursors for High Performance Thermosets. Molecules 2015, 20, 6488-6503.

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