Citric Acid as an Alternative to Sulfuric Acid for the Hard-Anodizing of AA6061
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Anodizing Process
- ➢
- Degreased and pickling for 5 s in 50 wt. % HCl solution.
- ➢
- Three rinses in deionized water, each of 3 s duration.
- ➢
- Anodizing Bath:
- 2M sulfuric acid solution (196 g/L of H2SO4).
- 1M citric acid solution (192 g/L) with the addition of sulfuric acid of 5 and 10 mL/L.
- 2M citric acid solution (384 g/L) with the addition of sulfuric acid of 5 and 10 mL/L.
- The current generator used was a Model XLN30052-GL High Power Programmable DC Power Supply with a capacity of 300 Volts (V) and 5 Amperes (A). Current densities used, 3 and 4.5 A/dm2
- Time 60 min.
- Temperature at 5 °C ± 2 °C.
- ➢
- Rinse in deionized water for 5 s.
- ➢
- Sealing treatment, in H2O solution at 95 °C for 60 min.
2.3. Microstructural Characterization
2.4. Vickers Microhardness (HV)
2.5. Corrosion Test
3. Results
3.1. Chemical Composition
3.2. Microstructural Characterization (SEM)
3.2.1. Surface Morphology
3.2.2. Cross-Sectional Morphology
3.2.3. Thickness of Anodized Materials
3.3. Vickers Microhardness (HV)
3.4. Corrosion Test
3.4.1. Cyclic Potentiodynamic Polarization (CPP)
3.4.2. Electrochemical Impedance Spectroscopy (EIS)
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Alloy | Anodizing | Sealing | Nomenclature | |||
---|---|---|---|---|---|---|
Bath | Current Density (A/dm2) | Time (min) | ||||
Citric Acid | Sulfuric Acid | |||||
AA6061 | --- | 2M | 3 | 60 | Deionized water at 95 °C for 60 min | 3A C0M S2M |
1M | 5 mL/L | 3A C1M S5 | ||||
1M | 10 mL/L | 3A C1M S10 | ||||
2M | 5 mL/L | 3A C2M S5 | ||||
2M | 10 mL/L | 3A C2M S10 | ||||
--- | 2M | 4.5 | 60 | Deionized water at 95 °C for 60 min | 4.5A C0M S2M | |
1M | 5 mL/L | 4.5A C1M S5 | ||||
1M | 10 mL/L | 4.5A C1M S10 | ||||
2M | 5 mL/L | 4.5A C2M S5 | ||||
2M | 10 mL/L | 4.5A C2M S10 |
Elements | Al | Cu | Mg | Mn | Fe | Si | Zn | Cr | Ti |
---|---|---|---|---|---|---|---|---|---|
6061 | Bal. | 0.08 ± 0.004 | 2.14 ± 0.107 | 0.03 ± 0.0015 | 0.11 ± 0.0055 | 2.14 ± 0.107 | 0.15 ± 0.0075 | 0.12 ± 0.006 | 0.08 ± 0.004 |
Samples | Ecorr (V vs. SCE) | Epit (V vs. SCE) | E(Anodic to Cathodic Transition) (V vs. SCE) | ipass (A/cm2) | icorr (A/cm2) | Hysteresis |
---|---|---|---|---|---|---|
AA6061 | −1.02 | −0.689 | −0.858 | 2.22 × 10−5 | 9.47 × 10−6 | + |
3A C0M S2M | −0.767 | −0.124 | −0.793 | 7.41 × 10−9 | 4.48 × 10−9 | − |
3A C1M S5 | −0.230 | --- | 0.112 | 4.32 × 10−9 | 3.14 × 10−10 | − |
3A C1M S10 | −0.551 | −0.161 | --- | 2.06 × 10−9 | 1.02 × 10−9 | + |
3A C2M S5 | −0.734 | −0.387 | −0.844 | 3.55 × 10−9 | 1.57 × 10−9 | + |
3A C2M S10 | −0.857 | −0.540 | −0.820 | 1.30 × 10−9 | 6.47 × 10−9 | + |
4.5A C0M S2M | −0.293 | --- | 0.131 | 5.91 × 10−9 | 1.27 × 10−9 | − |
4.5A C1M S5 | −0.590 | --- | 0.065 | 4.09 × 10−9 | 4.79 × 10−10 | − |
4.5A C1M S10 | −0.230 | --- | 0.150 | 5.39 × 10−9 | 1.15 × 10−9 | − |
4.5A C2M S5 | −0.926 | --- | --- | 3.16 × 10−9 | 8.35 × 10−10 | − |
Sample | Rs (Ω·cm2) | CPEp (Ω−1 sαp cm−2) | Rp (Ω·cm2) | αp | CB (F/cm2) | RB (Ω·cm2) | αB | WB (Ω·cm2/s0.5) | Error (%) | χ2 |
---|---|---|---|---|---|---|---|---|---|---|
AA 6061 | 21.61 | --- | --- | --- | 6.84 × 10−6 | 0.17 × 106 | 0.94 | --- | <2.58 | 3 × 10−2 |
3A C0M S2M | 27.28 | --- | --- | --- | 1.82 × 10−9 | 3.90 × 106 | 0.83 | --- | <1.33 | 1 × 10−2 |
3A C1M S5 | 14.17 | 0.46 × 10−8 | 2.67 × 106 | 0.77 | 1.04 × 10−9 | --- | --- | 8.63 × 106 | <2.35 | 8 × 10−3 |
3A C1M S10 | 26.34 | 0.94 × 10−8 | 2.32 × 106 | 0.84 | 5.49 × 10−9 | --- | --- | 20.60 × 106 | <2.01 | 3 × 10−2 |
3A C2M S5 | 14.99 | 7.40 × 10−8 | 1.05 × 106 | 0.62 | 31.10 × 10−9 | --- | --- | 23.90 × 106 | <5.39 | 1 × 10−2 |
3A C2M S10 | 18.85 | 85.30 × 10−8 | 0.02 × 106 | 0.67 | 1.53 × 10−9 | --- | --- | 3.20 × 106 | <2.50 | 3 × 10−3 |
4.5A C0M S2M | 15.20 | 0.44 × 10−8 | 1.54 × 106 | 0.79 | 2.74 × 10−9 | --- | --- | 2.40 × 106 | <2.83 | 1 × 10−3 |
4.5A C1M S5 | 24.73 | 7.18 × 10−8 | 0.30 × 106 | 0.68 | 15.20 × 10−9 | --- | --- | 3.32 × 106 | <3.61 | 2 × 10−3 |
4.5A C1M S10 | 35.38 | 5.03 × 10−8 | 0.40 × 106 | 0.72 | 6.71 × 10−9 | --- | --- | 3.00 × 106 | <2.56 | 2 × 10−3 |
4.5A C2M S5 | 42.74 | --- | --- | --- | 228.00 × 10−9 | 8.65 × 106 | 0.76 | --- | <1.73 | 1 × 10−2 |
4.5A C2M S10 | 21.67 | 62.3 × 10−8 | 0.04 × 106 | 0.70 | 551.00 × 10−9 | --- | --- | 128.00 × 106 | <3.55 | 5 × 10−3 |
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Cabral-Miramontes, J.; Almeraya-Calderón, F.; López, F.E.; Lara Banda, M.; Olguín-Coca, J.; López-León, L.D.; Castañeda-Robles, I.; Alcalá, M.Á.E.; Zambrano-Robledo, P.; Gaona-Tiburcio, C. Citric Acid as an Alternative to Sulfuric Acid for the Hard-Anodizing of AA6061. Metals 2021, 11, 1838. https://doi.org/10.3390/met11111838
Cabral-Miramontes J, Almeraya-Calderón F, López FE, Lara Banda M, Olguín-Coca J, López-León LD, Castañeda-Robles I, Alcalá MÁE, Zambrano-Robledo P, Gaona-Tiburcio C. Citric Acid as an Alternative to Sulfuric Acid for the Hard-Anodizing of AA6061. Metals. 2021; 11(11):1838. https://doi.org/10.3390/met11111838
Chicago/Turabian StyleCabral-Miramontes, José, Facundo Almeraya-Calderón, Francisco Estupinán López, María Lara Banda, Javier Olguín-Coca, Luis Daimir López-León, Ivan Castañeda-Robles, Miguel Ángel Esneider Alcalá, Patricia Zambrano-Robledo, and Citlalli Gaona-Tiburcio. 2021. "Citric Acid as an Alternative to Sulfuric Acid for the Hard-Anodizing of AA6061" Metals 11, no. 11: 1838. https://doi.org/10.3390/met11111838