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Article

Long-Range Electron Transport Donor-Acceptor in Nonlinear Lattices

1
Department of Physics, Saratov State University, Astrakhanskaya 83, 410012 Saratov, Russia
2
Institut für Physik, Humboldt-Universität Berlin, Newtonstraße 15, 12489 Berlin, Germany
3
Instituto Pluridisciplinar, Universidad Complutense, Paseo Juan XXIII, 1, 28040 Madrid, Spain
*
Author to whom correspondence should be addressed.
These authors contributed equally to this work.
Academic Editors: Ignazio Licata and Sauro Succi
Entropy 2016, 18(3), 92; https://doi.org/10.3390/e18030092
Received: 20 November 2015 / Revised: 22 February 2016 / Accepted: 7 March 2016 / Published: 11 March 2016
(This article belongs to the Special Issue Non-Linear Lattice)
We study here several simple models of the electron transfer (ET) in a one-dimensional nonlinear lattice between a donor and an acceptor and propose a new fast mechanism of electron surfing on soliton-like excitations along the lattice. The nonlinear lattice is modeled as a classical one-dimensional Morse chain and the dynamics of the electrons are considered in the tight-binding approximation. This model is applied to the processes along a covalent bridge connecting donors and acceptors. First, it is shown that the electron forms bound states with the solitonic excitations in the lattice. These so-called solectrons may move with supersonic speed. In a heated system, the electron transfer between a donor and an acceptor is modeled as a diffusion-like process. We study in detail the role of thermal factors on the electron transfer. Then, we develop a simple model based on the classical Smoluchowski–Chandrasekhar picture of diffusion-controlled reactions as stochastic processes with emitters and absorbers. Acceptors are modeled by an absorbing boundary. Finally, we compare the new ET mechanisms described here with known ET data. We conclude that electron surfing on solitons could be a special fast way for ET over quite long distances. View Full-Text
Keywords: electron transport; electron-surfing; donor-acceptor; thermal solitons; solectrons electron transport; electron-surfing; donor-acceptor; thermal solitons; solectrons
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MDPI and ACS Style

Chetverikov, A.P.; Ebeling, W.; Velarde, M.G. Long-Range Electron Transport Donor-Acceptor in Nonlinear Lattices. Entropy 2016, 18, 92. https://doi.org/10.3390/e18030092

AMA Style

Chetverikov AP, Ebeling W, Velarde MG. Long-Range Electron Transport Donor-Acceptor in Nonlinear Lattices. Entropy. 2016; 18(3):92. https://doi.org/10.3390/e18030092

Chicago/Turabian Style

Chetverikov, Alexander P., Werner Ebeling, and Manuel G. Velarde 2016. "Long-Range Electron Transport Donor-Acceptor in Nonlinear Lattices" Entropy 18, no. 3: 92. https://doi.org/10.3390/e18030092

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