Search Results (8)

Controlling fluid loss during acid fracturing remains challenging, as acid may partially or completely leak into reservoir pores and fractures, preventing effective flow within the formation and thereby reducing stimulation effectiveness. The acid leakoff mechanism is fundamentally distinct from that of non-reactive pad fluid (fracturing fluid), with the most critical distinction manifested through wall-confined acid-etched wormholes formed during reactive flow processes, which exert a dominant influence on acid filtration behavior. To address this challenge, a modified dual-scale continuum model based on the Brinkman equation was developed. This model establishes a numerical simulation framework for acid fracturing–etching processes in dolomite reservoirs of the Xi Xiangchi Formation. The study systematically reveals acid leakoff patterns at fracture walls under the influence of operational parameters (injection rate, acid concentration, acid viscosity) and reservoir characteristics (porosity heterogeneity). For field operations, medium-viscosity acid initially enhances distal fracture communication, followed by viscosity reduction to promote non-uniform etching. Prioritizing acid concentration over injection rate optimizes fracture connectivity, while minimizing leakoff. In high-porosity reservoirs, process parameters require optimization through acid retardation and leakoff control strategies. Full article

This research makes a strong focus on improving fluid dynamics inside the reservoir after stimulation for enhancing oil and gas well performance, particularly in terms of increasing the Gas–oil ratio (GOR) and injectivity leading to a better productivity index (PI). Advanced stimulation operation using new formulated emulsified acid treatment greatly improves the reservoir permeability, allowing for better fluid movement and less formation damage. This, in turn, results in injectivity increases of at least 2.5 times and, in some situations, up to five times the original rate, which is critical for sustaining reservoir pressure and ensuring effective hydrocarbon recovery. The emulsified acid outperforms typical 15% HCl treatments in terms of dissolving and corrosion rates, as it is tuned for the reservoir’s pressure, temperature, permeability, and porosity. This dual-phase technology increases injectivity by five times while limiting the environmental and material consequences associated with spent and waste acid quantities. Field trials reveal significant improvements in injection pressure and a marked reduction in circulation pressure during stimulation, underscoring the treatment’s efficient penetration within the rock pores to enhance oil flow and sweep. This increase in performance is linked to the creation of the wormholing impact of the emulsified acid, resulting in improved fluid dynamics and optimized reservoir efficiency, as shown by the enhanced gas–oil ratio (GOR) in the four mentioned cases. A critical component of attaining such improvements is the capacity to effectively analyze and forecast reservoir behavior prior to executing the stimulation in real life. Engineers can accurately forecast injectivity gains and improve fluid injection tactics by constructing an advanced predictive model with low error margins, decreasing the need for time-consuming and costly trial-and-error approaches. Importantly, the research utilizes sophisticated neural network modeling to forecast stimulation results with minimal inaccuracies. This predictive ability not only diminishes the dependence on expensive and prolonged trial-and-error methods but also enables the proactive enhancement of treatment designs, thereby increasing efficiency and cost-effectiveness. This modeling approach based on several operational and reservoir factors, combines real-time field data, historical well performance records, and fluid flow simulations to verify that the expected results closely match the actual field outcomes. A well-calibrated prediction model not only reduces uncertainty but also improves decision making, allowing operators to create stimulation treatments based on unique reservoir features while minimizing unnecessary costs. Furthermore, enhancing fluid dynamics through precise modeling helps to improve GOR management by keeping gas output within appropriate limits while optimizing liquid hydrocarbon recovery. Finally, by employing data-driven modeling tools, oil and gas operators can considerably improve reservoir performance, streamline operational efficiency, and achieve long-term production growth through optimal resource usage. This paper highlights a new approach to optimizing reservoir productivity, aligning with global efforts to minimize environmental impacts in oil recovery processes. The use of real-time monitoring has boosted the study by enabling for exact measurement of post-injectivity performance and oil flow rates, hence proving the efficacy of these advanced stimulation approaches. The study offers unique insights into unconventional reservoir growth by combining numerical modeling, real-world data, and novel treatment methodologies. The aim is to investigate novel simulation methodology, advanced computational tools, and data-driven strategies for improving the predictability, reservoir performance, fluid behavior, and sustainability of heavy oil recovery operations. Full article

The homogeneous acid etching of conventional acid in porous heterogeneous carbonate reservoirs leads to a large amount of consumption in the near-wellbore area, which makes the acidification effect often not ideal. In order to improve the acidizing effect of porous heterogeneous carbonate reservoirs, viscous acid is used to increase the stimulation of the target block in this paper. Through systematic experiments, the adaptability of the viscous acid in the four layers of the M reservoir in the target block was evaluated, and the MD and ME layers suitable for acidizing stimulation were determined in combination with physical property analysis. Finally, based on the geological characteristics and experimental data of the preferred layers, a two-scale acid wormhole growth radial model was established, and the construction parameters of acidizing stimulation were optimized. The results show that (1) The preferred viscous acid system has a dissolution rate of more than 95% for the rock powder in the four layers. When the matrix permeability is high, the effect of the acid wormhole is obvious and the permeability increase is higher. (2) The steel sheet corrosion and residual acid damage experiments showed that the acid system was not corrosive to the wellbore, and the reservoir damage rate of the residual acid after the reaction was low. (3) Based on the relationship between reservoir porosity and permeability and the position of edge and bottom water, the MD and ME layers with more potential for acidizing stimulation are selected. (4) The results of the numerical simulation show that the optimal acid pump rate of the MD and ME layers is 1.4 bpm and 1.0 bpm, and the acidizing fluid volume is 255 bbl, which can form effective acid wormholes, and the range of reservoir permeability transformation is the largest. The field application results show that the optimization scheme effectively improves the production of oil wells, verifies the practicability of the scheme, and provides a reference for the process optimization of viscous acid in the same type of porous heterogeneous carbonate reservoir stimulation. Full article

Successful matrix acidizing for extremely thick carbonate reservoirs with long horizontal well sections and strong heterogeneity requires efficient temporary plugging and diverting of acid fluid, ensuring acid fluid distribution to each production layer. Foamed-viscoelastic-surfactant (Foamed-VES) acid combines the benefits of both foam acid and viscoelastic surfactant (VES) acid, integrating foam plugging and viscous plugging. It can achieve uniform acid distribution in highly heterogeneous reservoirs. However, little research has been conducted on the wormhole propagation law of foamed-VES acid. To address this gap, this study established a mathematical model of foamed-VES acid wormhole propagation based on the dual-scale model. The model was coupled with a random porosity distribution generated with geological statistical software. The effects of different factors on foamed-VES acid etching were simulated. Numerical results show that foamed-VES acid can stimulate low-permeability reservoirs with a permeability differential of 20. Its inherent mechanism lies in the synergy of foam plugging and VES viscous plugging. This study enhances our understanding of the acid diversion mechanism of foamed-VES acid, providing a theoretical foundation for on-site acidizing treatment. Full article

Michigan State University-2 (MSU-2) is notable potential adsorbent for carbon dioxide (CO₂) due to its intrinsic properties, which include its highly interconnected three-dimensional (3D) wormhole-like framework structure, high specific surface area, and its large total pore volume, as well as its large amount of surface silanol hydroxyl groups, which facilitate the amine functionalization process. In this study, unfunctionalized MSU-2 was synthesized via a fluoride-assisted two-step process via the solution precipitation method, using Triton X-100 as the surfactant and tetraethylorthosilicate (TEOS) as the silica precursor. Then, the synthesized MSU-2 was functionalized using varying tetraethylenepentamine (TEPA) loadings of 20–60 wt%. The effect of different TEPA loadings on the properties and CO₂ adsorption capacity of the MSU samples was investigated. Studies of the CO₂ adsorption of the unfunctionalized and TEPA-functionalized MSU-2 samples was conducted at 40 °C and 1 bar of pressure. Furthermore, scanning electron microscopy (SEM); surface area and porosity (SAP) analysis; carbon, hydrogen, nitrogen, and sulfur (CHNS) analysis, X-ray diffractometry (XRD); Fourier transform infrared (FTIR) spectrometry; and thermogravimetric analysis (TGA) were utilized to characterize the resultant unfunctionalized and TEPA-functionalized MSU-2 with different TEPA loadings in order to study their morphologies, pore characteristics, elemental compositions, crystallographic structures, functional groups, chemical bonding, and thermal stability, respectively. The comprehensive results obtained from the analytical instruments and the CO₂ adsorption studies indicated that the TEPA-functionalized MSU-2 with 40 wt% of TEPA loading achieved the highest average CO₂ adsorption capacity of 3.38 mmol-CO₂/g-adsorbent. Full article

Since its first use as a drug delivery system, mesoporous silica has proven to be a surprisingly efficient vehicle due to its porous structure. Unfortunately, most synthesis methods are based on using large amounts of surfactants, which are then removed by solvent extraction or heat treatment, leading to an undesired environmental impact because of the generated by-products. Hence, in the present study, we followed the synthesis of a silica material with a wormhole-like pore arrangement, using two FDA-approved substances as templates, namely Tween-20 and starch. As far as we know, it is the first study using the Tween-20/starch combo as a template for mesoporous silica synthesis. Furthermore, we investigated whether the obtained material using this novel synthesis had any potential in using it as a DDS. The material was further analyzed by XRD, TEM, FT-IR, N₂ adsorption/desorption, and DLS to investigate its physicochemical features. Vancomycin was selected as the active molecule based on the extensive research engaged towards improving its bioavailability for oral delivery. The drug was loaded onto the material by using three different approaches, assuming its full retention in the final system. Thermal analysis confirmed the successful loading of vancomycin by all means, and pore volume significantly decreased upon loading, especially in the case of the vacuum-assisted method. All methods showed a slower release rate compared to the same amount of the pure drug. Loadings by physical mixing and solvent evaporation released the whole amount of the drug in 140 min, and the material loaded by the vacuum-assisted method released only 68.2% over the same period of time, leading us to conclude that vancomycin was adsorbed deeper inside the pores. The kinetic release of the three systems followed the Higuchi model for the samples loaded by physical mixing and vacuum-assisted procedures, while the solvent evaporation loading method was in compliance with the first-order model. Full article

The distribution of acid over all layers of interest is a critical measure of matrix acidizing efficiency. Chemical and mechanical techniques have been widely adapted for enhancing acid diversion. However, it was demonstrated that these often impact the formation with damage after the acid job is completed. This study introduces, for the first time, a novel solution to improve acid diversion using thermochemical fluids. This method involves generating nitrogen gas at the downhole condition, where the generated gas will contribute in diverting the injected acids into low-permeability formations. In this work, both lab-scale numerical and field-scale analytical models were developed to evaluate the performance of the proposed technique. In addition, experimental measurements were carried out in order to demonstrate the application of thermochemical in improving the acid diversion. The results showed that a thermochemical approach has an effective performance in diverting the injected acids into low-permeability rocks. After treatment, continuous wormholes were generated in the high-permeability rocks as well as in low-permeability rocks. The lab-scale model was able to replicate the wormholing impact observed in the lab. In addition, alternating injection of thermochemical and acid fluids reduced the acid volume 3.6 times compared to the single stage of thermochemical injection. Finally, sensitivity analysis indicates that the formation porosity and permeability have major impacts on the acidizing treatment, while the formations pressures have minor effect on the diversion performance. Full article

In this work we report the effects of support structural properties and its modification with some metal oxides modifiers on the catalytic behavior of Au catalysts in the total CO oxidation at 20 °C. Au catalysts were supported on mesoporous silica materials (MSM) having different structural properties: Channel-like (SBA-15), cage-like (SBA-16), hexagonal (HMS), and disordered (DMS-1) structures. The effect of the modifier was evaluated by comparison of the catalytic response of the SBA-15-based catalysts modified with MgO, Fe₂O₃, TiO₂, and CeO₂. The chemical, structural, and electronic properties of the catalysts were investigated by a variety of techniques (metal content analysis by ICP-OES, N₂ physisorption, XRD, UV-vis DRS, DRIFTS of adsorbed CO and OH regions, oxygen storage capacity (OSC), HR-TEM, and XPS). The activity of calcined catalysts in the CO oxidation reaction were evaluated at steady state conditions, at 20 °C, atmospheric pressure, and when using, as feed, a 1%CO/1%O₂/98% gas mixture. The work clearly demonstrated that all Au catalysts supported on the mesoporous silicas modified with metal oxides were more active than the Au/SBA-15 and Au/MgO reference ones. The support structural properties and type of dopant were important factors influencing on the catalyst behavior. Concerning the support textural properties, it was found that the HMS substrate with the wormhole-structure offers better porosity and specific surface area than their silica counterparts having channel-like (SBA-15), cage-like (SBA-16), and disordered (DMS-1) mesoporous structures. Concerning the effect of modifier, the best catalytic response was achieved with the catalysts modified with MgO. After activation by calcination at 200 °C for 4 h, the Au/MgO/HMS catalyst exhibited the best catalytic performance, which was ascribed to the combined effects of the best structural properties, a large support oxygen storage capacity and homogeneous distribution of gold particles on the support (external and inner). Implications of the type of active sites (Au¹⁺ or Au⁰), support structural properties and role of modifier on the catalytic activity are discussed. Full article