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Keywords = waste brown eggshells

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21 pages, 30191 KiB  
Article
Mechanical Properties of a Bio-Composite Produced from Two Biomaterials: Polylactic Acid and Brown Eggshell Waste Fillers
by Duncan Cree, Stephen Owuamanam and Majid Soleimani
Waste 2023, 1(3), 740-760; https://doi.org/10.3390/waste1030044 - 1 Sep 2023
Cited by 7 | Viewed by 3549
Abstract
An option to reduce the exploitation and depletion of natural mineral resources is to repurpose current waste materials. Fillers are often added to polymers to improve the properties and lower the overall cost of the final product. Very few studies have assessed the [...] Read more.
An option to reduce the exploitation and depletion of natural mineral resources is to repurpose current waste materials. Fillers are often added to polymers to improve the properties and lower the overall cost of the final product. Very few studies have assessed the use of waste brown eggshell powder (BESP) as filler in polylactic acid (PLA). The addition of mineral fillers in a polymer matrix can play an important role in the performance of a composite under load. Therefore, tailoring the amount of filler content can be a deciding factor as to which filler amount is best. The goal of this study was to investigate the effect of brown eggshells compared to conventional limestone (LS) powder on the mechanical properties of PLA composites. One-way analysis of variance (ANOVA) was used to carry out the statistical analysis on the average values of each composite mechanical property tested. Scanning electron microscopy (SEM) was used to view if there were any differences in the fractured surfaces. Overall, the LS performed marginally better than the BESP fillers. The highest ultimate tensile and ultimate flexural strengths for eggshell composites containing 32 µm fillers had values of 48 MPa (5–10 wt.% BESP) and 67 MPa (10 wt.%. BESP), respectively. Both the tensile and flexural modulus improved with filler contents and were highest at 20 wt.% with values of 4.5 GPa and 3.4 GPa, respectively. The Charpy impact strength decreased for all filler amounts. SEM micrographs identified changes in the fractured surfaces due to the additions of the filler materials. The ANOVA results showed statistically significant differences for the composite materials. After five weeks of soaking in distilled water, the composites containing 20 wt.% BESP fillers had the highest weight gain. The study demonstrated that waste brown eggshells in powdered form can be used as a filler in PLA composites. Full article
(This article belongs to the Special Issue Agri-Food Wastes and Biomass Valorization)
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16 pages, 1790 KiB  
Review
Waste Management in the Agri-Food Industry: The Conversion of Eggshells, Spent Coffee Grounds, and Brown Onion Skins into Carriers for Lipase Immobilization
by Sandra Budžaki, Natalija Velić, Marta Ostojčić, Marija Stjepanović, Blanka Bilić Rajs, Zita Šereš, Nikola Maravić, Jovana Stanojev, Volker Hessel and Ivica Strelec
Foods 2022, 11(3), 409; https://doi.org/10.3390/foods11030409 - 30 Jan 2022
Cited by 30 | Viewed by 7199
Abstract
One of the major challenges in sustainable waste management in the agri-food industry following the “zero waste” model is the application of the circular economy strategy, including the development of innovative waste utilization techniques. The conversion of agri-food waste into carriers for the [...] Read more.
One of the major challenges in sustainable waste management in the agri-food industry following the “zero waste” model is the application of the circular economy strategy, including the development of innovative waste utilization techniques. The conversion of agri-food waste into carriers for the immobilization of enzymes is one such technique. Replacing chemical catalysts with immobilized enzymes (i.e., immobilized/heterogeneous biocatalysts) could help reduce the energy efficiency and environmental sustainability problems of existing chemically catalysed processes. On the other hand, the economics of the process strongly depend on the price of the immobilized enzyme. The conversion of agricultural and food wastes into low-cost enzyme carriers could lead to the development of immobilized enzymes with desirable operating characteristics and subsequently lower the price of immobilized enzymes for use in biocatalytic production. In this context, this review provides insight into the possibilities of reusing food industry wastes, namely, eggshells, coffee grounds, and brown onion skins, as carriers for lipase immobilization. Full article
(This article belongs to the Section Food Security and Sustainability)
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