Search Results (33)

This study examined the impact of tempering temperature on the microstructure and properties of vanadium (V)-microalloyed medium-carbon bainitic steel. A series of heat treatments were performed on the steel, and the microstructural evolution and mechanical properties were systematically investigated through X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and mechanical testing systems (MTS). The findings revealed that tempering temperature has a significant influence on microstructural changes. Specifically, at 350–450 °C, retained austenite begins to decompose and carbides start to precipitate. At 550–600 °C, bainitic ferrite laths undergo coarsening. Regarding mechanical properties, both tensile strength and yield strength initially increase with tempering temperature before decreasing as the temperature continues to rise. The diffusion and redistribution of carbon atoms during tempering enhance the elongation of all tempered samples compared to their untempered counterparts. Optimal comprehensive mechanical properties are achieved at 450 °C, where precipitation strengthening from vanadium, enhanced stability of retained austenite, and synergistic strengthening effects of decomposition products are most pronounced. This research provides a theoretical foundation for optimizing the heat treatment process of such steels and offers insights into the synergistic effects of V-microalloying and tempering. Full article

This study focuses on the effects of vanadium and niobium microalloying elements on the mechanical properties and high-temperature oxidation behavior of austenitic stainless steels. Vanadium–niobium elements were confirmed to play an effective role in fine-grain strengthening at room temperature, achieving a tensile strength and yield strength of approximately 768.8 MPa and 464.6 MPa, respectively, with the additions of 0.32 wt% V and 0.21 wt% Nb. During the high-temperature oxidation process, the weight gain and cracking of the oxide layer increased with increasing niobium–vanadium content. The loose structure and delamination of the oxide layer during the oxidation process were caused by the enhanced internal stress of the oxide layer and the molten state of V₂O₅ at 850 °C. Full article

High-strength low-alloy (HSLA) steels have garnered significant attention owing to their widespread applications across various industries, with weldability being a particularly critical aspect. However, the impact toughness of the coarse-grained heat-affected zone (CGHAZ) remains a notable challenge under high-heat-input welding conditions. Despite existing research acknowledging the beneficial effects of micro-alloying elements on steel properties, there are still numerous uncertainties and controversies regarding the specific influence of these elements on the microstructure and impact toughness of the CGHAZ under specific welding conditions. To address this issue, this study presents a comprehensive review of the impact of common micro-alloying elements on the microstructure and toughness of the CGHAZ during high-heat-input welding. The results indicate that elements such as cerium, magnesium, titanium, vanadium, nitrogen, and boron significantly improve the toughness of the CGHAZ by promoting intragranular nucleation of acicular ferrite and inhibiting the coarsening of austenite grains. In contrast, the addition of elements such as aluminum and niobium adversely affect the toughness of the CGHAZ. These findings offer crucial theoretical guidance and experimental evidence for further optimizing the welding performance of HSLA steels and enhancing the impact toughness of the CGHAZ. Full article

In this study, we investigated the effect of grain size of an initial microstructure (pearlite + ferrite) on a resulting microstructure of induction-hardened microalloyed steel 38MnVS6, which is one topical medium carbon vanadium microalloyed non-quenched and tempered steel used in manufacturing crankshafts for high-power engines. The results show that a coarse initial microstructure could contribute to the incomplete transformation of pearlite + ferrite into austenite in reaustenitization transformation by rapid heating, and the undissolved ferrite remains and locates between the neighboring prior austenite grains after the induction-hardening process. As the coarseness level of the initial microstructure increases from 102 μm to 156 μm, the morphology of undissolved ferrite varies as granule, film, semi-network, and network, in sequence. The undissolved ferrite structures have a thickness of 250–500 nm and appear dark under an optical metallographic view field. To achieve better engineering applications, it is not recommended to eliminate the undissolved ferrite by increasing much heating time for samples with coarser initial microstructures. It is better to achieve a fine original microstructure before the induction-hardening process. For example, microalloying addition of vanadium and titanium plays a role of metallurgical grain refinement via intragranular ferrite nucleation on more sites, and the heating temperature and time of the forging process should be strictly controlled to ensure the existence of fine prior austenite grains before subsequent isothermal phase transformation to pearlite + ferrite. Full article

In the quest to produce high-strength steel, the preparation technology for vanadium–nitrogen alloy (VN) was refined through thermodynamic analysis, employing it as an additive to enhance the strength and hardness of microalloyed steel. Changes in the Gibbs free energies associated with the reactions between vanadium oxides and carbon in a nitrogen atmosphere were meticulously calculated and examined. This study explored the effects of the carbon to V₂O₅ ratio, the nitrogen to V₂O₅ ratio, and the pressure on the production of VN and CO at various temperatures. The results indicate that the productivity of VN is highest under conditions of approximately 1000 °C, a C:N₂:V₂O₅ ratio of 10:8:1, and a pressure of 1 bar. Under these conditions, VN constitutes approximately 70% of solid products, with a conversion rate of around 67.92%. CO accounts for approximately 38.17% of the exhaust gas, resulting in a yield of approximately 45.28%. The CO generated can be utilized as fuel in the production of iron in blast furnaces, providing an opportunity for secondary use of resources. Full article

High-carbon hardline steels are primarily used for the manufacture of tire beads for both automobiles and aircraft, and vanadium (V) microalloying is an important means of adjusting the microstructure of high-carbon hardline steels. Using scanning electron microscopy (SEM), X-ray diffraction (XRD), and transmission electron microscopy (TEM), the microstructure and precipitation phases of continuous cooled high-carbon steels were characterized, and the vanadium content, carbon diffusion coefficient, and critical precipitation temperature were calculated. The results showed that as the V content increased to 0.06 wt.%, the interlamellar spacing (ILS) of the pearlite in the experimental steel decreased to 0.110 μm, and the carbon diffusion coefficient in the experimental steel decreased to 0.98 × 10⁻³ cm²·s⁻¹. The pearlite content in the experimental steel with 0.02 wt.% V reached its maximum at a cooling rate of 5 °C·s⁻¹, and a small amount of bainite was observed in the experimental steel at a cooling rate of 10 °C·s⁻¹. The precipitated phase was VC with a diameter of ~24.73 nm, and the misfit between ferrite and VC was 5.02%, forming a semi-coherent interface between the two. Atoms gradually adjust their positions to allow the growth of VC along the ferrite direction. As the V content increased to 0.06 wt.%, the precipitation-temperature-time curve (PTT) shifted to the left, and the critical nucleation temperature for homogeneous nucleation, grain boundary nucleation, and dislocation line nucleation increased from 570.6, 676.9, and 692.4 °C to 634.6, 748.5, and 755.5 °C, respectively. Full article

The variations of the microstructure and mechanical properties of medium-Mn steel after vanadium (V) microalloying with different contents were investigated. After a one-step intercritical annealing (IA) at 730 °C, the steel containing 0.04 wt.% of V exhibited excellent comprehensive properties. The steel maintained an ultimate tensile strength (UTS) of 1000 MPa while also exhibiting a total elongation (TEL) of 37% and a product of strength and plasticity (PSE) of 37.7 GPa%. V-microalloying improved the yield strength (YS) and UTS of the experimental steel by refining ferrite grains and precipitation strengthening, however, it deteriorated its plasticity, which is difficult to compensate for through grain refinement and due to the TRIP effect of retained austenite (RA). The largest amount of RA and the appropriate stability also make a significant contribution to the outstanding UTS of the steel containing 0.04 wt.% of V through the TRIP effect. However, the further increase of V content led to decreased RA content and stability, weakening the TRIP effect and resulting in a weaker strength ductility balance. Full article

In this work, the effect of nitrogen doping on vanadium micro-alloyed P460NL1 steel is studied in terms of microstructures and impact toughness. As the nitrogen content increased from 0.0036% to 0.0165%, the number of V (C,N) particles increased. The fine precipitates of V (C,N) effectively pin the prior austenite grain boundary, resulting in the refinement of the austenite grain. The intragranular and intergranular V-containing coarse particles enhanced the nucleation of intragranular ferrite and the grain boundaries of polygonal ferrite during air cooling. Accordingly, the proportion of heterogeneously nucleated ferrite increased, and the grain size of ferrite decreased. Notably, the size of the pearlite microstructure decreased, and the bainite microstructure appeared with a high doping of N. With the increase in N content, the impact toughness of vanadium micro-alloyed P460NL1 steel was enhanced. This can be attributed to the refinement of ferrite and the reduction in pearlite, which, in turn, was ascribed to the increase in nitrogen. Full article

In this work, the influence of normalizing temperature on vanadium micro-alloyed P460NL1 steel is studied in terms of microstructures and impact toughness. With the normalizing temperature increased from 850 °C to 950 °C, the V(C,N) particles are dissolved. The dissolution of V(C,N) particles leads to a reduction in their ability to pin the primitive austenite grain boundaries, resulting in the coarsening of the primitive austenite grain. Simultaneously, the number of precipitated particles promoting ferrite nucleation decreased. The combination of these two effects led to the coarsening of ferrite grains in the steel samples. Of note, in the sample normalized at a temperature of 850 °C, the ferrite and pearlite crystals clearly exhibited banded structures. As the normalizing temperature increased, the ferrite–pearlite belt phase weakened. The highly distributed belt phase resulted in poor impact toughness of the steel sample normalized at 850 °C. The belt phase was improved at a normalizing temperature of 900 °C. In addition to that, the microstructure did not undergo significant coarsening at this normalizing temperature, thereby allowing it to achieve the highest toughness among all samples that were prepared for this study. The belt phase almost vanished at the normalizing temperature of 950 °C. However, microstructure coarsening occurred at this temperature, resulting in the deterioration of impact toughness. Full article

Press hardening steel standardly relies on titanium microalloying for protecting boron from being tied up by residual nitrogen. This practice safeguards the hardenability effect of boron during die quenching. More recently, additional microalloying elements were added to press hardening steel to further improve properties and service performance. Niobium was found to induce microstructural refinement, leading to better toughness, bendability, and hydrogen embrittlement resistance. In that respect, niobium also extends the operating window of the press hardening process. Vanadium microalloying has been proposed to provide hydrogen trapping by its carbide precipitates. A recently developed press hardening steel employs all three microalloying elements in an attempt to further enhance performance. The current study analyses the microstructure of such multiple microalloyed press hardening steel, and compares it to the standard grade. Particularly, the effect of various heat treatments is investigated, indicating that the multiple microalloyed steel is more resistant against grain coarsening. TEM analysis is used to identify the various particle species formed in the steels, to track their formation, and to determine their size distributions. Nanosized microalloy carbide particles typically comprise a mixed composition involving niobium, titanium, and vanadium. Furthermore, these precipitates are incoherent to the matrix. Regarding tensile properties, it is found that the multiple microalloyed press hardening steel is superior to the standard grade. Full article

The inter-critically reheated grain coarsened heat affected zone (IC GC HAZ) has been reported as one of the most brittle section of high-strength low-alloy (HSLA) steels welds. The presence of micro-alloying elements in HSLA steels induces the formation of microstructural constituents, capable to improve the mechanical performance of welded joints. Following double welding thermal cycle, with second peak temperature in the range between Ac1 and Ac3, the IC GC HAZ undergoes a strong loss of toughness and fatigue resistance, mainly caused by the formation of residual austenite (RA). The present study aims to investigate the behavior of IC GC HAZ of a S355 steel grade, with the addition of different vanadium contents. The influence of vanadium micro-alloying on the microstructural variation, RA fraction formation and precipitation state of samples subjected to thermal cycles experienced during double-pass welding was reported. Double-pass welding thermal cycles were reproduced by heat treatment using a dilatometer at five different maximum temperatures of the secondary peak in the inter-critical area, from 720 °C to 790 °C. Although after the heat treatment it appears that the addition of V favors the formation of residual austenite, the amount of residual austenite formed is not significant for inducing detrimental effects (from the EBSD analysis the values are always less than 0.6%). Moreover, the precipitation state for the variant with 0.1 wt.% of V (high content) showed the presence of vanadium rich precipitates with size smaller than 60 nm of which, more than 50% are smaller than 15 nm. Full article

In this paper, we investigate the effects of vanadium on the strength and ductility of medium-manganese steels by analyzing the microstructural evolution and strain hardening rates and performing quantitative calculations. Two significantly different contents of vanadium, 0.05 and 0.5 wt.%, were independently added to model steel (0.12C-10Mn) and annealed at different intercritical temperatures. The results show that higher vanadium addition increases the yield strength but decreases the ductility. The maximum yield strength can increase from 849 MPa to 1063 MPa at low temperatures. The model calculations reveal that this is due to a precipitation strengthening increment of up to 148 MPa and a dislocation strengthening increment of 50 MPa caused by a higher quantity of V₄C₃ precipitates. However, the high density of vanadium carbides leads them to easily segregate at grain boundaries or phase interfaces, which prevents strain from uniformly distributing throughout the phases. This results in stress concentrations which cause a high strain hardening rate in the early stages of loading and a delayed transformation-induced plasticity (TRIP) effect. Additionally, the precipitates decrease the austenite proportion and its carbon concentrations, rendering the TRIP effect unsustainable. Accordingly, the ductility of high vanadium steels is relatively low. Full article

Microalloyed steels have emerged to replace conventional plain-carbon steels to achieve longer wheel life on Chinese railroads. In this work, with the aim of preventing spalling, a mechanism that consists of ratcheting and shakedown theory correlated with steel properties is systematically investigated. Mechanical and ratcheting tests were carried out for microalloyed wheel steel to which vanadium was added in the range of 0–0.15 wt.% and the results were compared with that obtained for conventional plain-carbon wheel steel. The microstructure and precipitation were characterized via microscopy. As a result, the grain size was not obviously refined, and the pearlite lamellar spacing decreased from 148 nm to 131 nm in microalloyed wheel steel. Moreover, an increase in the number of vanadium carbide precipitates was observed, which were mainly dispersed and uneven, and precipitated in the pro-eutectoid ferrite region, in contrast to the observation of lower precipitation in the pearlite. It has been found that vanadium addition can lead to an increase in yield strength by precipitation strengthening, with no reduction or increase in tensile strength, elongation or hardness. The ratcheting strain rate for microalloyed wheel steel was determined to be lower than that for plain-carbon wheel steel via asymmetrical cyclic stressing tests. An increase in the pro-eutectoid ferrite content leads to beneficial wear, which can diminish spalling and surface-initiated RCF. Full article

Industrial fusion of microalloying elements in steelmaking is imperative in defining and optimizing certain steel properties due to their strengthening and significant grain refinements effects at minute quantities. Copper, vanadium, and columbium are explored in this investigation to monitor their respective dissolution processes in a ladle metallurgy furnace (LMF), with concise parametric studies on effects of number of plugs and variations in argon gas flow rates for stirring. To track particle disintegration in the molten bath inside, intricate numerical processing was carried out with the use of mathematical models and to simulate the mixing process; turbulent multiphase computational fluid dynamics (CFD) models were combined with a user-defined function. The numerical findings highlight the connection between mixing time and gas blowing since the quantity of stirring plugs employed and the gas flow rates directly affect mixing effectiveness. The amount of particles to be injected and their total injection time were validated using industrial measurement; an average difference of 9.9% was achieved. In order to establish the need for an exceptionally high flow rate and inevitably reduce resource waste, extreme charging of flow rates for gas stirring were compared to lesser gas flow rates in both dual- and single-plug ladles. The results show that a single-plug ladle with a flow rate of 0.85 m³/min and a dual-plug ladle with a total flow rate of 1.13 m³/min have the same mixing time of 5.6 min, which was the shortest among all scenarios. Full article

Based on theoretical calculations, laboratory simulation research and industrial production data analysis combined with characterisations such as metallographic microscope, scanning electron microscope (SEM), transmission electron microscope (TEM) and microhardness testing, this study investigated the state of occurrence and the precipitation law of vanadium (V) in microalloyed steel to determine a reasonable production process for V microalloyed steel. The results showed that the V(C,N) precipitation phase was the main form of V in microalloyed steel that precipitated after the transformation of austenite to ferrite. The amount of V precipitation was positively correlated with the amount of V that was added. However, the precipitation temperature was not significantly correlated with the amount added. When the V content increased from 0.03% to 0.06%, the initial precipitation temperature only increased by 23 °C. The coiling temperature was identified as the core factor affecting the strength of V microalloyed steel. When the effects of precipitation strengthening and microstructure strengthening were considered, as the coiling temperature decreased, the strength first increased, then decreased and finally increased again. Under different processing conditions, the strengthening of vanadium in the material increased first and then decreased as the temperature decreased (700–200 °C). The corresponding temperatures for the best strengthening effect of aging treatment, industrial statistical data and simulating coiling were 550, 470 and 400 °C, respectively. The difference between laboratory research results and industrial production was found. When V precipitation strengthening was used to improve material properties, it was necessary to determine a reasonable quantity of V to add and the production process, according to different alloy systems, to make more effective use of V microalloyed resources. Full article