Search Results (11)

Froth flotation predominantly separates particles according to their differences in wettability. However, other particle properties such as size, shape or density significantly influence the separation outcome as well. Froth flotation is most efficient for particles within a size range of about 20–200 μm, but challenges arise for very fine or coarse particles that are accompanied by low recoveries and poor selectivity. While the impact of particle size on the separation behavior in flotation is well known by now, the effect of particle shape is less studied and varies based on the investigated zone (suspension or froth) and separation apparatus used. Beyond these complexities, many particle properties are correlated, making it challenging to analyze the isolated impact of individual properties on the separation behavior. Therefore, a multidimensional perspective on the separation process, considering multiple particle properties, enhances the understanding of their collective influence. In this paper, the two-dimensional case is studied; i.e., a parametric modeling approach is applied to determine bivariate Tromp functions from scanning electron microscopy-based image data of the feed and the separated fractions. With these functions it is possible to characterize the separation behavior of particle systems. Using a model system of ultrafine (<10 μm) particles, consisting of either glass spheres or glass fragments with different wettability states as the floatable fraction and magnetite as the non-floatable fraction, allows for the investigation of the influence of descriptor vectors consisting of size, shape and wettability, on the separation. In this way, the present paper contributes to a better understanding of the complex interplay between certain descriptor vectors for the case of ultrafine particles. Furthermore, it demonstrates the benefits of using multivariate Tromp functions for evaluating separation processes and points out the limitations of SEM-based image measurements by means of mineral liberation analysis (MLA) for the studied particle size fraction. Full article

The characteristics of iron minerals in cyanidation tailings with a low iron grade were determined via chemical composition analysis, iron phase analysis, and mineral liberation analysis (MLA). The results showed that the cyanidation tailings contained 15.68% iron, mainly occurring in the form of magnetite (19.66%) and limonite (79.91%), in which 16.52% magnetite and 65.90% limonite particles were fully liberated. Most ultra-fine magnetite grains were adjacent and wrapped with limonite to form complex intergrowths, which resulted in low-efficiency magnetite recovery in low-intensity magnetic separation (LIMS) and adversely affected the downstream high-gradient magnetic separation (HGMS) process. Thus, in this work, the optimization of the flow field was proposed to enhance the separation of ultra-fine magnetite from the cyanidation tailings using pilot-scale LIMS separation, and the controllable parameters (including feed flow, separation gap, drum rotating speed, and solid weight) affecting ultra-fine magnetite capture were investigated. Under optimized conditions, a high-grade magnetite concentrate assaying 63.31% Fe with 86.46% magnetite recovery was produced, which, respectively, increased by 0.76% and 15.22%, compared with those obtained from industrial production. In addition, from the flow dynamics simulation, it was found that the magnetite particles in the −6 µm ultra-fine fraction were lost much more easily than those of coarser fractions due to the relatively enhanced hydrodynamic drag force acting on the particles compared with the magnetic force. However, this loss would be effectively reduced with the regulation and control of the flow field. The iron recoveries in the −16~+6 µm and −6 µm fractions of magnetite concentrate increased by 3.66% and 4.42%, respectively, under optimized hydrodynamic conditions. This research outcome provides a valuable reference for the economic and effective utilization of iron resources from such solid wastes. Full article

The toxicological impact of airborne polluting ultrafine particles (UFPs, also classified as nanoparticles with average sizes of less than 100 nm) is an emerging area of research pursuing a better understanding of the health hazards they pose to humans and other organisms. Hemolytic activity is a toxicity parameter that can be assessed quickly and easily to establish part of a nanoparticle’s behavior once it reaches our circulatory system. However, it is exceedingly difficult to determine to what extent each of the nanoparticles present in the air is responsible for the detrimental effects exhibited. At the same time, current hemolytic assessment methodologies pose a series of limitations for the interpretation of results. An alternative is to synthesize nanoparticles that model selected typical types of UFPs in air pollution and evaluate their individual contributions to adverse health effects under a clinical assay of osmotic fragility. Here, we discuss evidence pointing out that the absence of hemolysis is not always a synonym for safety; exposure to model nanopollutants, even at low concentrations, is enough to increase erythrocyte susceptibility and dysfunction. A modified osmotic fragility assay in combination with a morphological inspection of the nanopollutant–erythrocyte interaction allows a richer interpretation of the exposure outcomes. Membrane–nanoparticle interplay has a leading role in the vulnerability observed. Therefore, future research in this line of work should pay special attention to the evaluation of the mechanisms that cause membrane damage. Full article

The magnetic susceptibility measured in an alternating field is made up of in-phase and out-of-phase components. The in-phase Anisotropy of Magnetic Susceptibility (ipAMS) measures the bulk response of all minerals in a sample; however, out-of-phase AMS (opAMS) is sensitive to only select ferromagnetic minerals such as hematite, titanomagnetite, and ultrafine magnetite. The opAMS can be harnessed as a tool for the direct determination of magnetic subfabrics defined by ferromagnetic minerals. This work focuses on the following three Portuguese plutons: Lamas de Olo, Lavadores-Madalena, and Santa Eulália. The results show that the magnetic susceptibility is lower in opAMS, the degree of magnetic anisotropy is much higher in the opAMS, and the ellipsoid shape parameter has no significant differences. The ipAMS and opAMS tensors are, in general, coaxial, which indicates that the standard AMS fabric is parallel to the subfabric of minerals such as hematite, titanomagnetite, and ultrafine magnetite. Full article

Annually, hundreds of thousands of tons of slags are involved in the reverberator and flash smelting as well as converting operations of Cu-Fe sulfide concentrates to produce matte in the Sar Cheshmeh copper smelter plant, Iran, disposed in the landfill and cooled in air. Due to their relatively high average copper content (about 1.5 wt%), a mineral processing plant based on the flotation process has recently been established to produce thousands of tons of Cu-sulfide concentrate after slag crushing and fine grinding operation. In order to make the flotation process more efficient, more knowledge is required on the form and origin of the copper losses in the slag. To achieve this, mineralogical studies of the slags using optical microscopy, X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods have been carried out. Mineralogical analyses showed the main part of copper losses into the semi- to fully-crystallized magnetite-rich reverberator and flash slags characterized by crystal–glass matrix ratio ≤ 1 is moderate to coarse particles of Cu-Fe sulfides, i.e., chalcopyrite (CuFeS₂) and bornite (Cu₅FeS₄), that are mainly chemically entrapped. In contrast, the mechanically entrapped fine- to coarse-grain (from 20 up to 200 µm) spherical-shaped of high-grade matte particles with chalcocite (Cu₂S) composition containing droplets or veinlets of metallic copper (Cu⁰) are the dominant forms of copper losses into the converter slags characterized by crystal–glass matrix ratio > 1. From the value recovery point of view, our result show that the fully crystallized slags containing moderate- to coarse-grain copper-bearing particles will result in efficient recovery of a significant amount of entrained copper due to better milling response compared to semi-crystallized ones due to locking the fine- to moderate-grain copper particles in the silicate glassy matrix. Laboratory-scale grinding experiments showed that normal (≤74 μm) to fine (≤44 μm) grinding of high- Cu grade slags lead to a significant increase in the liberation degree of copper particles. in contrast, the increase in fine particle fractions (<37 μm) due to re-grinding or ultra-fine grinding of the originally low-Cu grade slags does not lead to the liberation of copper particles, but it will reduce the efficiency of the flotation process. This study suggests that the highest rate of copper recovery of the slag by the flotation process will be obtained at particle size 80% passing 44 µm which has also reached the optimal liberation degree of copper-bearing particles. Full article

Magnetite ores are among the most important sources of iron, which is in high demand in the global economy. Metallurgical properties of the magnetite concentrate significantly depend on impurities of silicon- and aluminum-bearing minerals. These impurities have to be separated from ore by magnetic separation and flotation techniques. Reverse column flotation is one of the methods applied for reducing the content of impurities in magnetite concentrate. This method allows recovering impurities from ore in the froth product (flotation tailings). However, the efficiency of this method significantly decreases with the decrease in particle size. As previously demonstrated, the effectiveness of fine particle column flotation can be increased if, before feeding the pulp into a column, fine bubbles are introduced into the pulp and the pulp is then passed through a tubular reactor. The major purpose of this study was to define the effectiveness of the reverse column flotation performance of ultrafine magnetite from the mixture with fine glass beads (ballotini) when, before the pulp is fed into the flotation column, it is mixed with fine air-in-water dispersion, and the mixture is then passed through a tubular flotation reactor (TFR). The obtained experimental findings allowed the definition of the optimal conditions of the mixture treatment in TFR that ensured high concentrate grade and iron recovery for the initial iron content in the mixture of 63.76%. These conditions were defined as follows: treatment time of the mixture in the TFR—7.5 s; average flow shear rate inside the TFR—1000 s⁻¹; volume dosage of fine bubbles per solid mass unit—0.032 or 0.21 mL/g. At the fine bubble dosage of 0.032 mL/g, the iron recovery and the concentrate grade were, respectively, 88.1% and 68.3% Fe, and at the dosage of 0.21 mL/g, the iron recovery reached 89.4% for the concentrate grade of 68.7% Fe. Full article

The occurrence features of ultrafine iron minerals in a cyanide leaching residue produced from a superlarge gold mining company in Yunnan Province were determined with chemical composition analysis, iron phase analysis, and mineral liberation analysis (MLA). The results show that the residue contains 26.74% iron, mainly occurring in the form of magnetite (26.33%) and limonite (69.41%), in which 67.40% magnetite and 73.00% limonite particles are fully liberated with particle sizes ranging from 9.6 µm to 75.0 µm. The rest are adjacent and wrapped intergrowths. Low-intensity magnetic separation and pulsating high-gradient magnetic separation were, respectively, proposed to recover magnetite and limonite from the residue, and under the optimized conditions, a high-grade magnetite concentrate assaying 64.05% Fe with 85.59% magnetite recovery and a qualified limonite concentrate assaying 50.94% Fe with 54.33% limonite recovery were, respectively, produced. The iron recovery for −30 µm fraction in the magnetite and limonite concentrates reached as high as 51.46%. It was found that the iron recovery for −30µm ultrafine fraction is lower than those of coarser fractions, as a result of the relatively enhanced hydrodynamic drag acting onto the particles, compared with the magnetic force. Entrainment occurs between the ultrafine iron minerals and gangues, thereby reducing the iron grade for the ultrafine fraction. This research outcome would provide a valuable reference for the economic and effective utilization of iron resources from such residues. Full article

Nuclear technology benefits humans, but it also produces nuclear radiation that harms human health and the environment. Based on the modified Andreasen and Andersen particle packing model for achieving a densely compacted cementitious matrix, a new magnetite ultra-high-performance concrete (MUHPC) was designed using magnetite fine aggregate as a substitute for river sands with 0%, 20%, 40%, 60%, 80%, and 100% replacement ratios. The comprehensive properties of the developed MUHPC were tested and evaluated. These properties were fluidity, static and dynamic compressive strengths, high-temperature performance, antiradiation behaviors, hydration products, and micropore structures. Experimental results indicate that the developed MUHPC has high work performance and static and dynamic mechanical properties. The gamma ray shielding performance of MUHPC substantially improves with increased magnetite fine aggregate. Corresponding with 100% magnetite fine aggregate substitution, the linear attenuation coefficient of MUHPC is enhanced by 56.8% compared with that of ordinary concrete. Magnetite addition does not change the type of cement hydration products but improves the micropore structures of MUHPC and effectively reduces its total porosity and average pore diameter, thereby contributing to its mechanical and radiation shielding properties. The compressive strength and linear attenuation coefficient of the MUHPC can reach 150 MPa and 0.2 cm⁻¹, respectively. In addition, the MUHPC also exhibits superior mechanical and radiation shielding performance at elevated temperatures (<400 °C). Finally, high strength and antiradiation performance support the use of MUHPC in radiation protection materials in the future. Full article

Simple magnetic separation for a certain magnetite mine with ultrafine disseminated lean ores has resulted in low performance, as the fine sizes and aggregation of ground mineral particles have caused inefficient recovery of the ultrafine minerals. In this study, we attempt to increase the apparent sizes of target mineral particles, and improve the separation indices, by using a multi-stage grinding-dispersion-selective flocculation-weak magnetic separation process. The results showed that under the conditions of 500 g/t sodium hexametaphospate (SHMP) as dispersant, 750 g/t carboxymethyl starch (CMS) as flocculant, agitating at 400 rpm for 10 min, with slurry pH 11, and final grinding fineness of 93.5% less than 0.03 mm, the obtained concentrate contained 62.82% iron, with recovery of 79.12% after multi-stage magnetic separation. Compared to simple magnetic separation, the concentrate’s iron grade increased by 1.26%, and a recovery rate by 5.08%. Fundamental analysis indicated that, in a dispersed state of dispersion, magnetite particles had weaker negative surface charges than quartz, allowing the adsorption of negative CMS ions via hydrogen bonding. Consequently, the aggregate size of the initial concentrate increased from 24.30 to 38.37 μm, accomplishing the goal of selective flocculation, and increasing the indices of separation. Full article

Particulate air pollution is a health concern. This study determines the microscopic make-up of different varieties of sand particles collected at a sand dune site in Badr, Saudi Arabia in 2012. Three categories of sand were studied: black sand, white sand, and volcanic sand. The study used multiple high resolution electron microscopies to study the morphologies, emission source types, size, and elemental composition of the particles, and to evaluate the presence of surface “coatings or contaminants” deposited or transported by the black sand particles. White sand was comprised of natural coarse particles linked to wind-blown releases from crustal surfaces, weathering of igneous/metamorphic rock sources, and volcanic activities. Black sand particles exhibited different morphologies and microstructures (surface roughness) compared with the white sand and volcanic sand. Morphological Scanning Electron Microscopy (SEM) and Laser Scanning Microscopy (LSM) analyses revealed that the black sand contained fine and ultrafine particles (50 to 500 nm ranges) and was strongly magnetic, indicating the mineral magnetite or elemental iron. Aqueous extracts of black sands were acidic (pH = 5.0). Fe, C, O, Ti, Si, V, and S dominated the composition of black sand. Results suggest that carbon and other contaminant fine particles were produced by fossil-fuel combustion and industrial emissions in heavily industrialized areas of Haifa and Yanbu, and transported as cloud condensation nuclei to Douf Mountain. The suite of techniques used in this study has yielded an in-depth characterization of sand particles. Such information will be needed in future environmental, toxicological, epidemiological, and source apportionment studies. Full article

Arsenic (As) contamination in groundwater is a great environmental health concern and is often the result of contact between groundwater and arsenic-containing rocks or sediments and from variation of pH and redox potentials in the subsurface. In the past decade, magnetite nanoparticles (MNPs) have been shown to have high adsorption activity towards As. Alerted by the reported cytotoxicity of 5–12 nm MNP, we studied the adsorption behavior of 1.15 nm MNP and a MNP composite (MNPC), MNPs interlinked by silane coupling agents. With an initial concentration of As at 25 mg L⁻¹, MNPs exhibited high adsorption capacity for As(V) and As (III), 206.9 mg·g⁻¹ and 168.6 mg·g⁻¹ under anaerobic conditions, respectively, and 109.9 mg·g⁻¹ and 108.6 mg·g⁻¹ under aerobic conditions, respectively. Under aerobic conditions, MNPC achieved even higher adsorption capacity than MNP, 165.1 mg·g⁻¹ on As(V) and 157.9 mg·g⁻¹ on As(III). For As(V) at 50 mg L⁻¹, MNPC achieved an adsorption capacity as high as 341.8 mg·g⁻¹, the highest in the literature. A kinetic study indicated that this adsorption reaction can reach equilibrium within 15 min and the rate constant of As(V) is about 1.9 times higher than that of As(III). These results suggested that MNPC can serve as a highly effective adsorbent for fast removal of As. Full article