HZSM-5 (MFI type) of composition (H
x)[Al
3+xSi
12−xO
24] ×
wH
2O and nanocomposites NA/HZSM-5, NA:
M/HZSM-5 (NA—nanoscale anatase;
M = V, Ni, Ag) with Si/Al = 12, 25, 40, 300 (sp.gr.
Pnma or
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HZSM-5 (MFI type) of composition (H
x)[Al
3+xSi
12−xO
24] ×
wH
2O and nanocomposites NA/HZSM-5, NA:
M/HZSM-5 (NA—nanoscale anatase;
M = V, Ni, Ag) with Si/Al = 12, 25, 40, 300 (sp.gr.
Pnma or
P2
1/n; z = 8), as well as zeolites [(Ti
4+xSi
12−xO
24] ×
wH
2O (TS) with Si/Ti = 47, 53, 73.5 (sp.gr.
Pnma) were studied by XRPD, XAS, FTIR-spectroscopy, BET, XPS, SEM, EDX, TPD, UV–VIS-spectroscopy, UV–DRS, and chemiluminescence methods. The results obtained together with photocatalytic, adsorption, antimicrobial, catalytic properties were analyzed using crystallochemical concepts and literature data. It was shown that NA or NA:
M introduction into HZSM-5 leads, respectively, to the photodegradation of MeO dye in the UV region or difenoconazole in the visible range, and contributes to the appearance in the dark of adsorption (almost complete extraction of P(V), As(V), and Se(V) from aquatic environment) and bacteriostatic properties in respect to
Staphylococcus epidermidis,
Bacillus antracoides, and
Escherichia coli for NA:Ag/HZSM-5(40, 300). The presence of titanium ions in NA nanoparticles on the HZSM-5 surface improves the catalytic activity in ethanol and propane (the best performance for NA/HZSM-5(25) and NA/HZSM-5(40), respectively) conversion. Determination of the composition (surface and bulk) and structure (statistical and local) of TS zeolites together with the found correlations made it possible to propose new catalysts in the reactions of propane, ethanol, and allyl chloride conversion.
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