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Keywords = textile wet processing

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17 pages, 2105 KiB  
Review
Fibrous Microplastics Release from Textile Production Phases: A Brief Review of Current Challenges and Applied Research Directions
by Md Imran Hossain, Yi Zhang, Abu Naser Md Ahsanul Haque and Maryam Naebe
Materials 2025, 18(11), 2513; https://doi.org/10.3390/ma18112513 - 27 May 2025
Cited by 1 | Viewed by 747
Abstract
Microplastics (MPs), particularly fibrous MPs, have emerged as a significant environmental concern due to their pervasive presence in aquatic and terrestrial ecosystems. The textile industry is a significant contributor to MP pollution, particularly through the production of synthetic fibers and natural/synthetic blends, which [...] Read more.
Microplastics (MPs), particularly fibrous MPs, have emerged as a significant environmental concern due to their pervasive presence in aquatic and terrestrial ecosystems. The textile industry is a significant contributor to MP pollution, particularly through the production of synthetic fibers and natural/synthetic blends, which release substantial amounts of fibrous MPs. Among the various types of MPs, fibrous MPs account for approximately 49–70% of the total MP load found in wastewater globally, primarily originating from textile manufacturing processes and the domestic laundering of synthetic fabrics. MP shedding poses a significant challenge for environmental management, requiring a comprehensive examination of the mechanisms and strategies for the mitigation involved. To address the existing knowledge gaps regarding MP shedding during the textile production processes, this brief review examines the current state of MP shedding during textile production, covering both dry and wet processes, and identifies the sources and pathways of MPs from industrial wastewater treatment plants to the environment. It further provides a critical evaluation of the existing recycling and upcycling technologies applicable to MPs, highlighting their current limitations and exploring their potential for future applications. Additionally, it explores the potential for integrating sustainable practices and developing regulatory frameworks to facilitate the transition towards a circular economy within the textile industry. Given the expanding application of textiles across various sectors, including medical, agricultural, and environmental fields, the scope of microplastic pollution extends beyond conventional uses, necessitating urgent attention to the impact of fibrous MP release from both synthetic and bio-based textiles. This brief review consolidates the current knowledge and outlines the critical research gaps to support stakeholders, policymakers, and researchers in formulating effective, science-based strategies for reducing textile-derived microplastic pollution and advancing environmental sustainability. Full article
(This article belongs to the Special Issue Leather, Textiles and Bio-Based Materials)
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33 pages, 785 KiB  
Review
Sustainable Wet Processing Technologies for the Textile Industry: A Comprehensive Review
by Maria L. Catarino, Filipa Sampaio and Ana L. Gonçalves
Sustainability 2025, 17(7), 3041; https://doi.org/10.3390/su17073041 - 29 Mar 2025
Cited by 1 | Viewed by 2995
Abstract
The textile industry ranks among the highest water-consuming sectors globally, with annual usage reaching billions of cubic meters. In manufacturing, wet processing, including dyeing, printing, and finishing, accounts for 72% of this water demand. These stages not only require vast water volumes but [...] Read more.
The textile industry ranks among the highest water-consuming sectors globally, with annual usage reaching billions of cubic meters. In manufacturing, wet processing, including dyeing, printing, and finishing, accounts for 72% of this water demand. These stages not only require vast water volumes but also produce wastewater containing hazardous chemicals, polluting ecosystems and reducing soil fertility. Furthermore, the energy-intensive nature of these processes, combined with a heavy reliance on fossil fuels, contributes significantly to greenhouse gas emissions. In response to these environmental challenges, innovative technologies have emerged, such as waterless dyeing using supercritical carbon dioxide, digital printing, ultrasonic-assisted processing, foam dyeing, laser-based denim finishing, and dope dyeing for man-made fibers. These methods drastically reduce water consumption, lower energy use, and minimize emissions while maintaining textile quality. However, the widespread adoption of these alternatives faces challenges, including high implementation costs, process scalability, and compatibility with existing infrastructure. This review critically explores current advancements in sustainable textile wet processing, analyzing their effectiveness, limitations, and industrial viability. By addressing these challenges, the textile industry can transition toward environmentally friendly and resource-efficient manufacturing processes. Full article
(This article belongs to the Section Environmental Sustainability and Applications)
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18 pages, 5061 KiB  
Article
Durable Textile Dyeing/Printing Using Natural Indigo Dyes and Leaves, and Mayan-Inspired Blue Indigo Pigments
by Nemeshwaree Behary and Nicolas Volle
Colorants 2025, 4(1), 2; https://doi.org/10.3390/colorants4010002 - 14 Jan 2025
Viewed by 1811
Abstract
Indigo leaves from various plant species are sources of dyes/pigments, not fully exploited for making sustainable textiles. Blue indigo vat dye extracted from indigo leaves yields high wash color fastness but fades slowly with light, and is not easily used for direct printing. [...] Read more.
Indigo leaves from various plant species are sources of dyes/pigments, not fully exploited for making sustainable textiles. Blue indigo vat dye extracted from indigo leaves yields high wash color fastness but fades slowly with light, and is not easily used for direct printing. Indigo leaves can be used to produce textiles of various color shades, while light-resistant Mayan-inspired hybrid pigments have not yet been used for textile coloring. Using blue indigo dyes from three plant species, with exhaustion dyeing, intense wash-resistant blue-colored textiles are produced, and in the case of Indigofera Persicaria tinctoria, textiles have antibacterial activity against S. epidermis and E. coli. A 100% natural Mayan-inspired blue indigo pigment, made from sepiolite clay and natural indigo dye, was used both in powdered and paste forms to perform pigment textile dyeing by pad cure process, and direct screen printing on textiles. A water-based bio-binder was used efficiently for both padding and printing. Bio-based Na Alginate thickener allowed to produce prints with good color-fastness on both polyester and cotton fabrics, while bio-based glycerin produced excellent print color fastness on polyester only: wash fastness (5/5), dry and wet rub fastness (5/5) and light fastness (7/8). Full article
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17 pages, 1457 KiB  
Article
Membrane Treatment to Improve Water Recycling in an Italian Textile District
by Francesca Tuci, Michele Allocca, Donatella Fibbi, Daniele Daddi and Riccardo Gori
Membranes 2025, 15(1), 18; https://doi.org/10.3390/membranes15010018 - 9 Jan 2025
Cited by 1 | Viewed by 1141
Abstract
The textile district of Prato (Italy) has developed a wastewater recycling system of considerable scale. The reclaimed wastewater is characterized by high levels of hardness (32 °F on average), which precludes its direct reuse in numerous wet textile processes (e.g., textile dyeing). Consequently, [...] Read more.
The textile district of Prato (Italy) has developed a wastewater recycling system of considerable scale. The reclaimed wastewater is characterized by high levels of hardness (32 °F on average), which precludes its direct reuse in numerous wet textile processes (e.g., textile dyeing). Consequently, these companies utilize ion exchange resins for water softening. However, the regeneration of the resins results in an increased concentration of chlorides in the reclaimed wastewater that exceeds the limit set by Italian regulations for the reuse of water for irrigation purposes. The objective of this study is to investigate the potential of membrane filtration as an alternative method for removing hardness from water. Therefore, an industrial-scale ultrafiltration-nanofiltration (UF-NF) pilot plant was installed to test the rejection of hardness from the reclaimed wastewater. The experiment employed two types of NF membranes and three permeate fluxes (27, 35, and 38 L·m−2·h−1) for testing. The results demonstrated that the system could remove hardness with efficiencies exceeding 98% under all conditions tested. The experimental findings indicate that the UF-NF system has the potential to be employed as a post-treatment step to render the reclaimed wastewater suitable for all textile finishing processes and to expand the scope for reuse. Full article
(This article belongs to the Section Membrane Applications for Water Treatment)
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16 pages, 3333 KiB  
Article
Evaluation of Alpaca Yarns Dyed with Buddleja Coriaceous Dye and Metallic Mordants
by Arturo Quispe-Quispe, Franklin Lozano, Luz María Pinche-Gonzales and Fulgencio Vilcanqui-Perez
Fibers 2025, 13(1), 2; https://doi.org/10.3390/fib13010002 - 28 Dec 2024
Cited by 1 | Viewed by 1369
Abstract
The objective of this research was to evaluate the effect of dye obtained from Buddleja coriacea and metallic mordants on the chromatic properties, textile characteristics, spectral profiles, and color stability in alpaca fibers. The dye extraction technique involved boiling in an aqueous solution, [...] Read more.
The objective of this research was to evaluate the effect of dye obtained from Buddleja coriacea and metallic mordants on the chromatic properties, textile characteristics, spectral profiles, and color stability in alpaca fibers. The dye extraction technique involved boiling in an aqueous solution, followed by filtration. Subsequently, alpaca yarns were dyed using the resulting extract following a standard protocol. The applied mordants included sodium sulfate (Na2SO4), aluminum sulfate and potassium dodecahydrate (KAl(SO4)2·12H2O), and oxalic acid (C2H2O4). Spectroscopy UV-Vis and FTIR spectrophotometry methods were used for the characterization of the dyed samples and analysis of the dye during the dyeing process. The findings revealed the formation of four distinct color tones. Additionally, it was determined that the mordants influenced the chromatic properties of the fibers dyed with Buddleja coriacea extract without modifying their textile characteristics. The identified spectral bands corresponded to keratin, the structural protein of the fibers. Changes in the intensity of these spectral bands were observed in the dyed samples, attributable to the presence of different mordants. Wet rub fastness was found to be inferior to dry rub fastness, which has implications for textile maintenance. In conclusion, Buddleja coriacea flowers provide an effective yellow dye, and when combined with various mordants, they allow for a variety of shades and hues in alpaca fiber yarns. Full article
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17 pages, 2713 KiB  
Article
Improving Cotton Fabric Dyeability by Oxygen Plasma Surface Activation
by Víctor M. Serrano-Martínez, Carlos Ruzafa-Silvestre, Carlota Hernández-Fernández, Elena Bañón-Gil, Francisca Arán-Ais and Elena Orgilés-Calpena
Surfaces 2024, 7(4), 1079-1095; https://doi.org/10.3390/surfaces7040071 - 20 Dec 2024
Cited by 1 | Viewed by 2058
Abstract
This paper focuses on investigating the use of low-pressure oxygen plasma as a surface treatment aimed at enhancing the wettability and dyeability of cotton fabrics for use in textiles and footwear materials. Plasma activation modified the cotton fabric surfaces, increasing their affinity for [...] Read more.
This paper focuses on investigating the use of low-pressure oxygen plasma as a surface treatment aimed at enhancing the wettability and dyeability of cotton fabrics for use in textiles and footwear materials. Plasma activation modified the cotton fabric surfaces, increasing their affinity for polar liquids. The research thoroughly characterised the treated fabrics through a combination of analytical methods and physical testing. Plasma treatment was performed using a 13.56 MHz RF generator at 90 W power, with an oxygen flow rate of 500 sccm and a pressure of 0.30 mbar, for treatment durations of 30, 60, and 120 s. Changes in surface chemistry were analysed with XPS, while SEM was used to observe morphological changes. Static water contact angle measurements confirmed a reduction from 128.5° in untreated cotton to 25.6° in samples treated for 30 s, indicating a significant increase in hydrophilicity. Water absorption tests showed a maximum absorption capacity of 119.6% after 60 min for plasma-treated samples, compared to 65.7% for untreated cotton. Contact angle measurements verified that surface hydrophilicity increased following the treatment. Furthermore, physical tests, such as rub fastness, colourimetry, and water absorption, were carried out to evaluate improvements in wettability, dyeability, and overall performance. The results showed notable enhancements in the wetting properties of cotton textiles, enabling better absorption of water and dyes, along with improved fixation. The comprehensive characterisations provided insights into the mechanisms behind these improvements. This research offers a sustainable approach for the textile industry, as plasma technology is a dry process that enhances dyeing efficiency while maintaining fabric performance and lowering environmental impact. Full article
(This article belongs to the Special Issue Surface Science: Polymer Thin Films, Coatings and Adhesives)
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10 pages, 2798 KiB  
Article
The Obtaining and Study of Composite Chromium-Containing Pigments from Technogenic Waste
by Bakyt Smailov, Bakhriddin Turakulov, Almagul Kadirbayeva, Nursulu Sarypbekova, Nurpeis Issabayev and Yerzhan Oralbay
J. Compos. Sci. 2024, 8(12), 520; https://doi.org/10.3390/jcs8120520 - 11 Dec 2024
Viewed by 1132
Abstract
This article provides information on the processing of chromium-containing waste from the Aktobe ferroalloy compounds plant using chemical reagents followed by high-temperature heat treatment for the synthesis of a composite chromite pigment used in the textile industry. This technology was developed for the [...] Read more.
This article provides information on the processing of chromium-containing waste from the Aktobe ferroalloy compounds plant using chemical reagents followed by high-temperature heat treatment for the synthesis of a composite chromite pigment used in the textile industry. This technology was developed for the first time for the purpose of recycling industrial waste and rational use of natural resources. The obtained pigments were analyzed by the X-ray phase of a D878-PC75-17.0 incident beam monochromator and the phase composition of the composite chromite pigment was studied. The thermogravimetric analysis of the composite chromite pigments was performed using a TGA/DSC 1HT/319 analyzer to determine the change in mass with time and temperature. According to the TGA results, the mass loss was determined to be 0.18% of the total mass. The elemental composition of the composite chromite pigment was determined using a JEOL JSM-6490 LV SEM device and the content of chromium oxide (Cr2O3) was determined, which reached up to 50%. The thermodynamic patterns of the processes occurring during the production of chromite pigments were studied using the integrated Chemistry software pack HSC-6. The results of testing printed and processed cotton and composite fabrics by the proposed method showed that the color fastness to washing and wet and dry friction is 4 points and the wear resistance assessment is 4860 and 6485 cycles, respectively. Composite chromite pigment based on technogenic wastes is recommended for use in various coloring compositions, including those used for printing on cotton and composite fabrics. Full article
(This article belongs to the Special Issue Composites: A Sustainable Material Solution)
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18 pages, 2514 KiB  
Article
Aloe Vera as a Printed Coating to Mitigate the Wear of Textiles
by Michail Karypidis, Amalia Stalika, Maria Zarkogianni, Apostolos Korlos and Eleftherios G. Andriotis
Coatings 2024, 14(11), 1467; https://doi.org/10.3390/coatings14111467 - 18 Nov 2024
Cited by 1 | Viewed by 1906
Abstract
Aloe vera is well known for its biological properties as a bioflavonoid anti-inflammatory and antibacterial agent. It has been used frequently in the food sector as a food coating due to its hygroscopic properties and as an ingredient in the lucrative cosmetic industry. [...] Read more.
Aloe vera is well known for its biological properties as a bioflavonoid anti-inflammatory and antibacterial agent. It has been used frequently in the food sector as a food coating due to its hygroscopic properties and as an ingredient in the lucrative cosmetic industry. Studies have also included aloe vera as an eco-friendly green solution based on these properties. The current research focuses on the use of aloe vera gel in printing pastes as an alternative sustainable solution to synthetic thickeners, evaluating its wet performance and ease of fabric stitching, and has been inspired by studies that similarly used this substance and measured its effect on the fabric’s coefficient of friction and antimicrobial action. In the current study, printing pastes with natural colourants, such as saffron, curcumin, and annatto, and aloe vera gel thickener derived from natural leaves from Crete increased the fabric’s mechanical resistance to abrasion compared to the untreated pastes. The measured performance did not differ substantially from prints with traditional synthetic pastes, hence tolerating the substitution with the non-contaminant variant. The enhanced resistance to abrasion and wear extends the fabric’s serviceable life and resulting garments, decreasing the need for high industry processing volumes and, as a result, reducing pollution. The resistance to wear was evaluated using the dominant method in textile testing of the Martindale apparatus, which measured the cycles to failure, weight loss, and general appearance deterioration using the official photographic standards. Full article
(This article belongs to the Special Issue Coatings for Antimicrobial Textiles)
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6 pages, 2098 KiB  
Correction
Correction: Hasanbeigi, A.; Zuberi, M.J.S. Electrified Process Heating in Textile Wet-Processing Industry: A Techno-Economic Analysis for China, Japan, and Taiwan. Energies 2022, 15, 8939
by Ali Hasanbeigi and M. Jibran S. Zuberi
Energies 2024, 17(22), 5698; https://doi.org/10.3390/en17225698 - 14 Nov 2024
Viewed by 528
Abstract
There was an error in the original publication [...] Full article
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15 pages, 2689 KiB  
Article
Mitigating Microfiber Pollution in Laundry Wastewater: Insights from a Filtration System Case Study in Galle, Sri Lanka
by Mahagama Gedara Yohan Lasantha Mahagamage, Sachith Gihan Gamage, Rathnayake Mudiyanselage Shehan Kaushalya Rathnayake, Premakumara Jagath Dickella Gamaralalage, Matthew Hengesbugh, Thejani Abeynayaka, Chathura Welivitiya, Lahiru Udumalagala, Chathura Rajitha and Supun Suranjith
Microplastics 2024, 3(4), 599-613; https://doi.org/10.3390/microplastics3040037 - 20 Oct 2024
Cited by 1 | Viewed by 2426
Abstract
Synthetic fibers are widely used in daily life due to their durability, elasticity, low cost, and ease of use. The textile industry is the primary source of synthetic microfibers, as these materials are mostly used in production processes. Globally, plastic pollution has been [...] Read more.
Synthetic fibers are widely used in daily life due to their durability, elasticity, low cost, and ease of use. The textile industry is the primary source of synthetic microfibers, as these materials are mostly used in production processes. Globally, plastic pollution has been identified as a major environmental threat in this era, since plastics are not degradable but break down into smaller particles such as mesoplastics, microplastics, and microfibers. Synthetic microfiber pollution is a significant issue in aquatic ecosystems, including oceans and rivers, with laundry wastewater being a major source. This problem is particularly pressing in cities like Galle, Sri Lanka, where numerous tourist hotels are located. Despite the urgency, there has been a lack of scientific and systematic analysis to fully understand the extent of the issue. This study addresses this gap by analyzing the generation of microfibers from laundry activities at a selected hotel and evaluating the efficiency of a laundry wastewater filtration system. This study focused on a fully automatic front-loading washing machine (23 kg capacity) with a load of 12 kg of polyester–cotton blend serviettes (black and red). Samples (1 L each) were taken from both treated and untreated wastewater during four wash cycles, with a total of 100 L of water used for the process. The samples were filtered through a 100 μm sieve and catalytic wet oxidation along with density separation were employed to extract the microfibers, which were then collected on a membrane filter paper (0.45 μm). Microfibers were observed and analyzed for shapes, colors and sizes under a stereo microscope. Results revealed that untreated laundry wastewater contained 10,028.7 ± 1420.8 microfibers per liter (n = 4), while treated wastewater samples recorded 191.5 ± 109.4 microfibers per liter (n = 4). Most of the microfibers observed were black and white/transparent colors. Further analysis revealed that 1 kg of polyester–cotton blend fabric can generate 336,833 microfibers per wash, which was reduced to 6367 microfibers after treatment. The filtration unit recorded an impressive efficiency of 98.09%, indicating a remarkably high capacity for removing microfibers from wastewater. These findings highlight the potential of such filtration techniques to significantly reduce microfiber emissions from laundry wastewater, presenting a promising approach to mitigating environmental pollution from microfibers. Full article
(This article belongs to the Collection Current Opinion in Microplastics)
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15 pages, 2735 KiB  
Review
Challenges Associated with the Production of Nanofibers
by Lebo Maduna and Asis Patnaik
Processes 2024, 12(10), 2100; https://doi.org/10.3390/pr12102100 - 27 Sep 2024
Cited by 16 | Viewed by 3464
Abstract
Nanofibers, with their high surface area-to-volume ratio and unique physical properties, hold significant promise for a wide range of applications, including medical devices, filtration systems, packaging, electronics, and advanced textiles. However, their development and commercialization are hindered by several key challenges and hazards. [...] Read more.
Nanofibers, with their high surface area-to-volume ratio and unique physical properties, hold significant promise for a wide range of applications, including medical devices, filtration systems, packaging, electronics, and advanced textiles. However, their development and commercialization are hindered by several key challenges and hazards. The main issues are production cost and yield, high voltage, clogging, and toxic materials driven by complex production techniques, which limit their adoption. Additionally, there are environmental and health concerns associated with nanofiber production and disposal, necessitating the development of safer and more sustainable processes and materials. Addressing these challenges requires continued innovation in materials science and industrial practices, as well as a concerted effort to balance production, material, and surrounding condition parameters. This study emphasizes the challenges and hazards associated with nanofiber materials and their production techniques, including electrospinning, centrifugal spinning, solution blow spinning, electro-blown spinning, wet spinning, and melt spinning. It also emphasizes biopolymers and recycling as sustainable and eco-friendly practices to avoid harming the environment and human beings. Full article
(This article belongs to the Section Materials Processes)
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11 pages, 3471 KiB  
Article
Cellulose Fiber with Enhanced Mechanical Properties: The Role of Co-Solvents in Gel-like NMMO System
by Suhnue Kim, Darae Lee and Hyungsup Kim
Gels 2024, 10(9), 607; https://doi.org/10.3390/gels10090607 - 23 Sep 2024
Cited by 2 | Viewed by 1635
Abstract
Cellulose has garnered attention in the textile industry, but it exhibits limitations in applications that require high strength and modulus. In this study, regenerated cellulose fiber with enhanced mechanical properties was fabricated from a gel-like N-methylmorpholine N-oxide (NMMO)–cellulose solution by modulating the intermolecular [...] Read more.
Cellulose has garnered attention in the textile industry, but it exhibits limitations in applications that require high strength and modulus. In this study, regenerated cellulose fiber with enhanced mechanical properties was fabricated from a gel-like N-methylmorpholine N-oxide (NMMO)–cellulose solution by modulating the intermolecular interaction and conformation of the cellulose chains. To control the interaction, two types of co-solvents (dimethyl acetamide (DMAc) and dimethyl formamide (DMF)) were added to the cellulose solutions at varying concentrations (10, 20, and 30 wt%). Rheological analysis showed that the co-solvents reduced the solution viscosity by weakening intermolecular interactions. The calculated distance parameter (Ra) in Hansen space confirmed that the co-solvent disrupted intermolecular hydrogen bonding within cellulose chains. The solutions were spun into fiber via a simple wet spinning process and were characterized by X-ray diffraction (XRD) and universal testing machine (UTM). The addition of co-solvent led to an increased crystallinity index (C.I.) owing to the extended cellulose chains. The modulus of the resulting fiber was increased when the co-solvent concentration was 10 wt%, regardless of the co-solvent type. This study demonstrates the potential for enhancing the mechanical properties of cellulose-based products by modulating the conformation and interaction of cellulose chains through the addition of co-solvent. Full article
(This article belongs to the Special Issue Rheological Properties and Applications of Gel-Based Materials)
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15 pages, 4057 KiB  
Article
Natural Dyeing and Antimicrobial Functionalization of Wool Fabrics Dyed with Chinese Dragon Fruit Extract to Enhance Sustainable Textiles
by Mohmadarslan Kutubuddin Sadannavar, Aravin Periyasamy, Syed Rashedul Islam, Faizan Shafiq, Xue Dong and Tao Zhao
Sustainability 2024, 16(16), 6832; https://doi.org/10.3390/su16166832 - 9 Aug 2024
Cited by 3 | Viewed by 3545
Abstract
Recently, the natural dyeing process has achieved great importance in the textile wet processing industry due to its clean dyeing, eco-friendliness, and nontoxicity in nature. In the above research project, a unique natural dye extracted from dragon fruit was applied to wool fabric [...] Read more.
Recently, the natural dyeing process has achieved great importance in the textile wet processing industry due to its clean dyeing, eco-friendliness, and nontoxicity in nature. In the above research project, a unique natural dye extracted from dragon fruit was applied to wool fabric using various mordanting agents to encourage the use of natural dyes and lessen the negative environmental effects caused by synthetic dyeing. The color characteristics (K/S), fastness properties, Fourier transform infrared spectroscopy (FTIR), absorption spectra, and thermal and ultraviolet (UV) resistance of the extracted dye and dyed wool samples were tested and characterized. The K/S values of the dyed wool fabrics were between 5.75 and 13.29. The color fastness ratings obtained from the dyed wool fabric were found to be between good and excellent. Hence, the overall results proved that the novel natural dye obtained from dragon fruit can be utilized for dyeing wool material for the production of eco-friendly and sustainable antimicrobial textiles. Full article
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23 pages, 1495 KiB  
Review
Diverse Approaches in Wet-Spun Alginate Filament Production from the Textile Industry Perspective: From Process Optimization to Composite Filament Production
by Cansu Var and Sema Palamutcu
Polymers 2024, 16(13), 1817; https://doi.org/10.3390/polym16131817 - 27 Jun 2024
Cited by 1 | Viewed by 1989
Abstract
Alginate, categorized as a natural-based biodegradable polymer, stands out for its inherently exclusive properties. Although this unique polymer is widely processed using film, coating, and membrane technologies for different usage areas, textile applications are still limited. This study aims to compile promising approaches [...] Read more.
Alginate, categorized as a natural-based biodegradable polymer, stands out for its inherently exclusive properties. Although this unique polymer is widely processed using film, coating, and membrane technologies for different usage areas, textile applications are still limited. This study aims to compile promising approaches that will pave the way for the use of wet-spun alginate filaments in textile applications. In this regard, this study provides information about the molecular structure of alginate, the gel formation mechanism, and cross-linking using different techniques. Our literature review categorizes parameters affecting the mechanical properties of wet-spun alginate filaments, such as the effect of ion source and spinning dope concentration, needle diameter, temperature, and coagulants. Following this, a detailed and comprehensive literature review of the various approaches, such as use of additives, preparation of blended filaments, and grafted nanocrystal addition, developed by researchers to produce composite alginate filaments is presented. Additionally, studies concerning the use of different cations in the coagulation phase are reported. Moreover, studies about the functionalism of wet-spun alginate filaments have been offered. Full article
(This article belongs to the Special Issue Natural-Based Biodegradable Polymeric Materials II)
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21 pages, 6866 KiB  
Article
Functionalization of Technical Textiles with Chitosan
by Kristina Klinkhammer, Hanna Hohenbild, Mohammad Toufiqul Hoque, Laura Elze, Helen Teshay and Boris Mahltig
Textiles 2024, 4(1), 70-90; https://doi.org/10.3390/textiles4010006 - 15 Feb 2024
Cited by 6 | Viewed by 4008
Abstract
Textiles are used for many different applications and require a variety of properties. Wet functionalization improve textiles’ properties, such as hydrophilicity or antimicrobial activity. Chitosan is a bio-based polymer widely investigated in the textile industry for this purpose. A weaving comprising a cotton/polyester [...] Read more.
Textiles are used for many different applications and require a variety of properties. Wet functionalization improve textiles’ properties, such as hydrophilicity or antimicrobial activity. Chitosan is a bio-based polymer widely investigated in the textile industry for this purpose. A weaving comprising a cotton/polyester mix and a pure-polyester weaving was functionalized with different concentrations of chitosan to determine the most robust method for chitosan detection in both cotton- and polyester-containing materials. Additionally, mixtures of chitosan with 3-glycidyloxypropyltriethoxy silane (GLYEO) or 3-aminopropyltriethoxy silane (AMEO) were applied in a one-step or two-step procedure on the same fabrics. Scanning electron microscopy (SEM) combined with energy-dispersive X-ray spectroscopy (EDS) and dyeing with Remazol Brilliant Red F3B demonstrated the presence of chitosan and silanes on the textiles’ surfaces. While non-functionalized textiles were not stained, the dependency of the dyeing depths on the chitosan concentrations enabled us to infer the efficacy of the very short processing time and a mild dyeing temperature. The one-step application of AMEO and chitosan resulted in the highest presence of silicon on the textile and the greatest color intensity. The functionalization with GLYEO reduced the water sink-in time of polyester, while chitosan-containing solutions increased the hydrophobicity of the material. Washing experiments demonstrated the increasing hydrophilicity of the cotton/polyester samples, independent of the type of functionalization. These experiments show that chitosan-containing recipes can be used as part of a useful method, and the type of functionalization can be used to adjust the hydrophilic properties of polyester and cotton/polyester textiles. Via this first step, in the future, new combinations of bio-based polymers with inorganic binder systems can be developed, ultimately leading to sustainable antimicrobial materials with modified hydrophilic properties. Full article
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