Search Results (8)

Herein we present a roadmap for tailoring the crystal growth conditions, near-infrared (NIR) laser emission, and self-frequency doubling (SFD) performances of newly developed Nd-doped La_xGd_ySc_4−x−y(BO₃)₄ (Nd:LGSB) crystals. Three different Nd³⁺ doping concentrations of 2.3 at.%, 3.5 at.%, and 4.6 at.% were investigated. Considering their incongruent melting, special conditions were employed for the growth using the Czochralski technique. Laser emission performances at 1062 nm in the CW regime were evaluated for uncoated crystal samples with different orientations (a-cut, c-cut, and SFD-cut). The highest slope efficiency η_sa = 0.68 was obtained for the 4.6 at.% c-cut Nd:LGSB crystal, with a randomly polarized emission. The a-cut 4.6 at.% Nd:LGSB crystal delivered a linearly polarized beam with a slope efficiency η_sa = 0.63. The SFD-cut 2.3 at.% and 3.5 at.% Nd:LGSB crystals achieved slightly lower efficiencies of ~ 0.56. The SFD capabilities of 2.3 at.% and 3.5 at.% Nd:LGSB crystals were also explored. Green laser emission at ~531 nm was achieved with a diode-to-green conversion efficiency increasing significantly from 0.17% to 1.44%, respectively. These results demonstrate that the Nd-doping concentration, crystal orientation, and sample length of Nd:LGSB crystals, must be carefully selected depending on the specific requirements of the intended application. Full article

Crystal coating is an important process in laser crystal applications. According to the crystal characteristics of neodymium-doped yttrium vanadate (Nd:YVO₄), its intrinsic parameters, and optical film design theory, Ta₂O₅ and SiO₂ were selected separately as high and low refractive index materials. The optical properties and surface roughness of the films were characterized by OptiLayer and Zygo interferometers, and the effects of ion source bias on refractive index and surface roughness were investigated so that the optimal ion source parameters were determined. Optical monitoring and quartz crystal control were combined to accurately control the thickness of each film layer and to reduce the monitoring error of film thickness. The prepared crystal device was successfully applied to the 1176 nm laser output system. Full article

This paper reviews the progress in developing the La_xY_ySc_4-x-y(BO₃)₄-LYSB and Yb-doped La_xY_ySc_4-x-y(BO₃)₄-LYSB:Yb huntite-type crystals grown by the Czochralski method as new candidates for the next generation of nonlinear optical (NLO) and/or laser crystals. Considering the incongruent melting of these crystals, the initial compositions of the melt and the pulling and rotation rates were optimized. Additionally, a special thermal setup was engineered to grow LYSB-type crystals by the Czochralski crystal growth method. The chemical compositions of the LYSB and LYSB:Yb grown crystals were found to be La_0.78Y_0.32Sc_2.90(BO₃)₄ and La_0.78Y_0.32Yb_0.04Sc_2.86(BO₃)₄, respectively. Therefore, for the LYSB:Yb crystal, the doping concentration of Yb³⁺ ions was considered to be 4 at.% with respect to the nonstoichiometric (La_1-xY_x)_1.25Sc_2.75(BO₃)₄ undoped compounds, i.e., LYSB:Yb (4 at.%). In terms of NLO properties, the obtained results demonstrate that LYSB and LYSB:Yb (4 at.%) crystals possess remarkable properties specific to huntite-type crystals. The main advantage of these crystals consists in the fact that they may be obtained with large dimensions and excellent optical quality by the Czochralski method, which recommends them as a new class of highly efficient crystals for different NLO applications, including second harmonic generation (SHG) of high-power or high-energy laser beams. The laser performances of the LYSB:Yb (4 at.%) crystal prove its favorable intrinsic properties to generate laser emissions in the 1 µm range with high efficiency. The efficient laser emission at ~1028 nm together with good NLO characteristics to convert its own emission into emission at ~514 nm via SHG make the LYSB:Yb (4 at.%) crystal a very promising active medium to be used in self-frequency doubling configuration. Full article

Point intrinsic and extrinsic defects, especially paramagnetic ions of transition metals and rare-earth elements, have essential influence on properties of lithium niobate, LN and tantalate, LT, and often determine their suitability for numerous applications. Discussions about structures of the defects in LN/LT have lasted for decades. Many experimental methods facilitate progress in determining the structures of impurity centers. This paper gives current bird’s eye view on contributions of Electron Paramagnetic Resonance (EPR), and Electron Nuclear Double Resonance (ENDOR) studies to the determination of impurity defect structures in LN and LT crystals for a broad audience of researchers and students. Symmetry and charge compensation considerations restrict a number of possible structures. Comparison of measured angular dependences of ENDOR frequencies with calculated ones for Li and Nb substitution using dipole–dipole approximation allows unambiguously to determine the exact location of paramagnetic impurities. Models with two lithium vacancies explain angular dependencies of EPR spectra for Me³⁺ ions substituting for Li⁺ like Cr, Er, Fe, Gd, Nd, and Yb. Self-compensation of excessive charges through equalization of concentrations of Me³⁺(Li⁺) and Me³⁺(Nb⁵⁺) and appearance of interstitial Li⁺ in the structural vacancy near Me³⁺(Nb⁵⁺) take place in stoichiometric LN/LT due to lack of intrinsic defects. Full article

In the past few decades, the multifunctional optical crystals for all-solid-state Raman lasers have been widely studied by many scholars due to their compactness, convenience and excellent performance. In this review, we briefly show two kinds of multifunctional Raman crystals: self-Raman (laser and Raman effects) crystals and self-frequency-doubled Raman (frequency-doubling and Raman effects) crystals. We firstly introduce the properties of the self-Raman laser crystals, including vanadate, tungstate, molybdate and silicate doped with rare earth ions, as well as self-frequency-doubled Raman crystals, including KTiOAsO₄ (KTA) and BaTeMo₂O₉ (BTM). Additionally, the domestic and international progress in research on multifunctional Raman crystals is summarized in the continuous wave, passively Q-switched, actively Q-switched and mode-locked regimes. Finally, we present the bottleneck in multifunctional Raman crystals and the outlook for future development. Through this review, we contribute to a general understanding of multifunctional Raman crystals. Full article

The influence of heat and droplet transfer into weld pool dynamic behavior and weld metal microstructure in double-pulsed gas metal arc welding (DP-GMAW) was investigated by the self-designed high-speed welding photography system. The heat input, the arc pressure, the droplet momentum and impingement pressure were measured and calculated. It was found that the arc pressure is far less than the droplet impingement pressure. The heat input and droplet impingement pressure per unit time acting on weld pool were proportional to the current pulse frequency, which fluctuated with thermal pulse. The size and oscillation amplitude of the weld pool had noticeable periodic changes synchronized with the process of heat input and droplet impingement. Compared to the microstructure of pulsed gas metal arc welding (P-GMAW) weld metal, that of DP-GMAW weld metal was significantly refined. High oscillation amplitude assisted the enhancement of weld pool convection, which leads to more constitutional supercooling. The heat input and shear force during the peak of thermal pulse causing dendrite fragmentation which provided sufficient crystal nucleus for the growth of equiaxed grains and the possibility of grain refinement. The effects of current parameters on welding behavior and weld metal grain size are investigated for further understanding of DP-GMAW. Full article

The structure and the maximal nonlinear optical (NLO) susceptibility χ⁽²⁾ are tabulated for more 700 acentric binary oxides, 220 crystals of simple, binary and complex borates and for the same set of 110 carbonates, tartrates, formates, oxalates, acetates and fluoride-carbonates used in ultraviolet and deep ultraviolet optoelectronics. According to the chemical formula, the structural symbols of these crystals have been plotted on the plane of two minimal oxide bond lengths (OBL). It is shown that acentric crystals are positioned on such plane inside the vertical, horizontal and slope intersected ellipses of “acentricity”. The oxide and borate crystals with moderate NLO susceptibility are found in the central parts of these ellipses intersection and, with low susceptibility, on top, at the bottom and border of the ellipses rosette. The nonpolar fluoride-carbonate crystals with high NLO susceptibility are found in the curve-side rhombic parts of the slope ellipse of “acentricity”. The unmonotonous fuzzy dependence “χ⁽²⁾” on the OBL of these crystals is observed, and their clear-cut taxonomy on compounds with π– or σ–oxide bonds is also established. It is shown that the correlations of χ⁽²⁾ with other acentric properties are nonlinear for the whole set of the oxide crystals having their clear maximum at a certain value of the piezoelectric or electro-optic coefficient. The correlation “hardness–thermoconductivity-fusibility” is plotted for oxide crystals, part of which is used at the creation of self-frequency-doubling solid state lasers. Full article

The efficient generation of second-harmonic light and squeezed light requires non-linear crystals that have low absorption at the fundamental and harmonic wavelengths. In this work the photo-thermal self-phase modulation technique is exploited to measure the absorption coefficient of periodically poled potassium titanyl phosphate (PPKTP) at 1,550 nm and 775 nm. Themeasurement results are (84±40) ppm/cmand (127±24) ppm/cm, respectively. We conclude that the performance of state-of-the-art frequency doubling and squeezed light generation in PPKTP is not limited by absorption. Full article