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Keywords = porphyrin synthon

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39 pages, 12036 KB  
Review
Meso-Formyl, Vinyl, and Ethynyl Porphyrins—Multipotent Synthons for Obtaining a Diverse Array of Functional Derivatives
by Vladimir S. Tyurin, Alena O. Shkirdova, Oscar I. Koifman and Ilya A. Zamilatskov
Molecules 2023, 28(15), 5782; https://doi.org/10.3390/molecules28155782 - 31 Jul 2023
Cited by 13 | Viewed by 4673
Abstract
This review presents a strategy for obtaining various functional derivatives of tetrapyrrole compounds based on transformations of unsaturated carbon-oxygen and carbon-carbon bonds of the substituents at the meso position (meso-formyl, vinyl, and ethynyl porphyrins). First, synthetic approaches to the preparation of [...] Read more.
This review presents a strategy for obtaining various functional derivatives of tetrapyrrole compounds based on transformations of unsaturated carbon-oxygen and carbon-carbon bonds of the substituents at the meso position (meso-formyl, vinyl, and ethynyl porphyrins). First, synthetic approaches to the preparation of these precursors are described. Then diverse pathways for the transformations of the multipotent synthons are discussed, revealing a variety of products of such reactions. The structures, electronic, and optical properties of the compounds obtained by the methods under consideration are analyzed. In addition, there is an overview of the applications of the products obtained. Biomedical use of the compounds is among the most important. Finally, the advantages of using the reviewed synthetic strategy to obtain dyes with targeted properties are highlighted. Full article
(This article belongs to the Special Issue Macrocyclic Compounds: Derivatives and Applications)
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