Search Results (28)

The concentration of intracellular adenosine triphosphate (ATP) is one of the most important characteristics of the metabolic state of the cells of microorganisms and their viability. This indicator, monitored by bioluminescent ATP-metry, and accumulation of the suspension biomass in the medium were used to assess the effect of particles of different synthetic microplastics (MPs) (non-biodegradable and biodegradable) on the cells of yeast, filamentous fungi, bacteria and phototrophic microorganisms (microalgae and cyanobacteria) co-exposed with polymer samples in different environments and concentrations. It was found that the effect of MPs on microorganisms depends on the concentration of MPs (1–5 g/L), as well as on the initial concentration of cells (10⁴ or 10⁷ cells/mL) in the exposure medium with polymers. It was shown that the lack of a sufficient number of nutrition sources in the medium with MPs is not fatal for the cells. The study of the effect of MPs on the photobacteria Photobacterium phosphoreum, widely used as a bioindicator for assessing the ecotoxicity of various environments, demonstrated a correlation between the residual bioluminescence of these cells and the level of their intracellular ATP in media with biodegradable polycaprolactone and polylactide, which had an inhibitory effect on these cells. Marine representatives of phototrophic microorganisms showed the greatest sensitivity to the presence of MPs, which was confirmed by both a decrease in the level of intracellular ATP and the concentration of their biomass. Among the eight microorganisms studied, bacteria of the genus Pseudomonas turned out to be not only the most tolerant to the presence of the seven MP samples used in the work, but also actively growing in their presence. Full article

This study evaluates the environmental impact of swimming goggles through a Life Cycle Assessment (LCA), comparing virgin and recycled polycarbonate models. It identifies key hotspots, assesses circular economy benefits, and examines barriers to sustainable disposal, aligning with European Union’s (EU) 2050 sustainability objectives. The LCA was modeled using SimaPro, with the Environmental Footprint (EF) 3.1 method to analyze 16 impact categories (e.g., climate change, human toxicity, resource depletion). Two scenarios were assessed: (1) virgin polycarbonate production and (2) a closed-loop system (80% recycled content, 30% reintegration). Primary data from a survey of 150 competitive swimmers quantified disposal behaviors. The lens production phase (bisphenol A processing) dominated impacts, contributing to 62% of climate change and 75% of human toxicity. The recycling scenario reduced total impact by 23.1% (119 → 91.5 mPt), with significant declines in freshwater ecotoxicity (−28.6%) and marine eutrophication (−25.1%). Survey data highlighted critical gaps: low consumer participation in recycling due to lack of awareness and inadequate disposal infrastructure. Recycled polycarbonate can substantially mitigate environmental impacts, but systemic barriers (consumer behavior, collection gaps) limit progress. Future work should explore bio-based polymers and policy incentives to accelerate circularity. Full article

Marine biofouling significantly impacts the performance and longevity of polymer-based marine structures, particularly those designed for hydrodynamic applications such as Vortex-Induced Vibration suppression systems. Traditional antifouling solutions rely on copper-based multilayer coatings, which present challenges including mechanical vulnerability (e.g., chipping and scratching), high material and labor demands, and environmental concerns such as volatile organic compound emissions and copper leaching. Recent developments in material science have introduced an alternative system involving the direct incorporation of copper oxide (Cu₂O) into high-density polyethylene (HDPE) during the molding process. This study conducts a comparative life cycle assessment (LCA) of two antifouling integration methods—System 1 (traditional coating-based) and System 2 (Cu₂O-impregnated HDPE)—evaluating their environmental impact across production, application, use, and end-of-life stages. The functional unit used for this study was 1 square meter for a time period of five years. Using ISO 14040-compliant methodology and data from Ecoinvent and OpenLCA, three impact categories were assessed: global warming potential (GWP), cumulative energy demand (CED), and marine aquatic ecotoxicity Potential (MAETP). The results indicate that System 2 outperforms System 1 in GWP (4.42 vs. 5.65 kg CO₂-eq), CED (75.3 vs. 91.0 MJ-eq), and MAETP (327,002 vs. 469,929 kg 1,4-DCB-eq) per functional unit over a five-year lifespan, indicating a 21.8%, 17.3%, and 30.4% reduction in the key impact factors, respectively. These results suggest that direct Cu₂O incorporation offers a more environmentally sustainable and mechanically resilient antifouling strategy, supporting the potential of embedded antifouling systems to shift industry practices toward more sustainable marine infrastructure. Full article

TiO₂ nanoparticles are found as pigments in coatings and paints and are, therefore, released into the environment through runoff. To assess their environmental impact, comprehensive fate and ecotoxicity studies necessitate particles closely resembling those released into the environment. In response, we developed a method designed to isolate TiO₂ particles from commercial paints. Using six contrasting paints alongside a pure TiO₂ pigment, we evaluated two extraction methods in terms of recovery, purification rate, and preservation of both inorganic and organic particle coatings. The paints and extracts were characterized using cryogenic-TEM, ICP-OES, thermogravimetry, and infrared spectroscopy. In contrast to the alkaline-based extraction method, the extraction with acetic acid facilitated the retention of both inorganic and organic coatings and ensured good removal of organic polymers. Recovery rates exceeded 70% for all paints and extraction methods, yet the complete removal of SiO₂, when present, was not achieved. CaCO₃ removal was effective with both extraction methods. Our developed extraction method enables the isolation of TiO₂-particles similar to those aged within paints. However, we recommend using silicate-free paints when SiO₂ interference is of concern for the study design. Furthermore, this method could be interesting for pigment recycling, offering a gentler alternative to existing techniques which compromise particle coatings. Full article

The increasing environmental concerns regarding plastic waste, especially in agriculture, have driven the search for sustainable alternatives. Agricultural plastics, such as mulching films and greenhouse covers, are heavily reliant on petrochemical-derived materials, which persist in the environment and contribute to long-term pollution. This study explores the use of biodegradable biocomposites made from steam explosion-treated chicken feathers and various polymer matrices to address these issues. Chicken feathers, a waste by-product of the poultry industry, present an excellent biodegradability as a result of the steam explosion treatment and contain nitrogen, potentially enhancing soil fertility. The biocomposites were characterized by thermal stability, mechanical properties, and biodegradability, and ecotoxicity assessments were carried out studying the incorporation of feathers into the soil. Results showed that the incorporation of treated chicken feathers increased the water absorption capacity of the composites, promoting faster disintegration and biodegradation. In particular, biocomposites made with polyhydroxyalkanoates and Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) exhibited a significant increase in degradation rates, from 3–10% in the first month for pure matrices to 40–50% when reinforced with treated feathers. Meanwhile, those made from polylactic acid showed slower degradation. Furthermore, the addition of feathers positively influenced crop growth at low concentrations, acting as a slow-release fertilizer. However, high concentrations of feathers negatively affect plant growth due to excess nitrogen. These findings highlight the potential of poultry feathers as a valuable, sustainable filler for agricultural bioplastics, contributing to waste valorization and environmentally friendly farming practices. Full article

Citric acid (CA), a naturally occurring compound in fruits, mainly citrus, has gained attention for its eco-friendly potential in wood modification. Through esterification, citric acid reacts with wood polymers to form bonds that improve adhesion, dimensional stability, and durability while reducing moisture absorption and susceptibility to decay. This study evaluated the efficacy of CA as an eco-friendly wood treatment. Wood samples were treated with solutions at varying concentrations (5%, 10%, and 15%) and assessed for dimensional stability, mechanical properties, biological resistance, and ecotoxicity. CA treatments significantly improved dimensional stability, with higher concentrations yielding greater weight percent gain (WPG) and anti-swelling efficiency (ASE). Biological tests demonstrated exceptional termite resistance, with no survival and minimal mass loss in treated samples at higher concentrations. Similarly, fungal resistance improved, as citric acid inhibited fungal growth. Ecotoxicity tests showed relatively low phytotoxicity, with some decrease in germination indices (GI) at higher CA concentrations. These findings highlight CA as a sustainable wood treatment for enhanced durability and biodegradation resistance in construction and outdoor applications. Full article

Starch has overtaken the bioplastic market in developing thermoplastic starch-based blends and composite systems owing to its biodegradability and sustainability. Thermoplastic starch (TPS) development is mostly a two-stage process involving plasticizing starch and blending plasticized starch with a polymer. Most of the research focuses on improving the properties of the blend system through different methodologies, including various plasticizers and co-plasticizers. However, limited studies have analyzed the environmental effects of plasticizers or co-plasticizers and their processing. Thus, in this research, the environmental impact of starch plasticization processes performed by co-plasticization (glycerol–urea, glycerol–citric acid, and glycerol–succinic anhydride) and by conventional glycerol-based plasticization is compared through life cycle assessment (LCA). The results showed that glycerol–citric acid- and glycerol–succinic anhydride-based co-plasticization had a comparable environmental impact to traditional glycerol-based plasticization. In contrast, the glycerol–urea-based co-plasticization process exhibited the highest effect on the environment. Furthermore, to reduce the environmental impact, a sensitivity analysis of the plasticization processes was conducted by changing the energy aspect of the processes through quantitative and qualitative approaches. The qualitative approach significantly reduced major impact categories such as global warming, carcinogens, ecotoxicity, and fossil fuel depletion. Full article

Microplastics (MPs) in aquatic environments can be associated with various substances, including persistent organic pollutants, which add to the problem of plastic ecotoxicity. The abundance of 1–5 mm microplastics and concentrations of particle-adsorbed organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in sandy sediments from three beaches in recreational areas along the upper Ob River in Western Siberia were assessed. MP pollution levels in the Ob River beach sands ranged from 24 ± 20.7 to 104 ± 46.2 items m⁻² or, in terms of mass concentration, from 0.26 ± 0.21 to 1.22 ± 0.39 mg m⁻². The average abundance of MP particles reached 0.67 ± 0.58 items kg⁻¹ or 8.22 ± 6.13 μg kg⁻¹ in the studied sediments. MP concentrations were significantly higher in number (p < 0.05) and mass (p < 0.01) at the riverbank site downstream of the Novosibirsk wastewater treatment plant (WWTP) outfall compared to these at the upstream and more distant beaches. Most MPs (70–100%) were represented by irregularly shaped fragments. The polymer composition of MPs varied between sites, with a general predominance of polyethylene (PE). The study revealed associations of MPs with PCBs and OCPs not previously detected in the riverbed and beach sediments, suggesting that these substances are circulating in the Ob River basin. Although MP concentrations were higher downstream of the WWTP, the maximum levels of particle-associated OCPs were observed in the beach sands of the site farthest from the urban agglomeration. The pesticides γ-HCH, 4,4-DDT, and 4,4-DDE were detected on MPs at relatively low concentrations. PCBs were more abundant in the studied samples, including 118 dioxin-like congener. The results obtained indicate that the Ob River is susceptible to plastic and persistent organic pollutant (POP) contamination and serve as a starting point for further studies and practical solutions to the problem. Full article

Background: Environmental concerns about petroleum-based plastic packaging materials and the growing demand for food have inspired researchers and the food industry to develop food packaging with better food preservation and biodegradability. Nanocomposites consisting of nanofillers, and synthetic/biopolymers can be applied to improve the physiochemical and antimicrobial properties and sustainability of food packaging. Scope and approach: This review summarized the recent advances in nanofiller and their applications in improved food packaging systems (e.g., nanoclay, carbon nanotubes), active food packaging (e.g., silver nanoparticles (Ag NPs), zinc oxide nanoparticles (ZnO NPs)), intelligent food packaging, and degradable packaging (e.g., titanium dioxide nanoparticles (e.g., TiO₂ NPs)). Additionally, the migration processes and related assessment methods for nanofillers were considered, as well as the use of nanofillers to reduce migration. The potential cytotoxicity and ecotoxicity of nanofillers were also reviewed. Key findings: The incorporation of nanofillers may increase Young’s modulus (YM) while decreasing the elongation at break (EAB) (y = −1.55x + 1.38, R² = 0.128, r = −0.358, p = 0.018) and decreasing the water vapor (WVP) and oxygen permeability (OP) (y = 0.30x − 0.57, R² = 0.039, r = 0.197, p = 0.065). Meanwhile, the addition of metal-based NPs could also extend the shelf-life of food products by lowering lipid oxidation by an average of approx. 350.74% and weight loss by approx. 28.39% during the longest storage period, and significantly increasing antibacterial efficacy against S. aureus compared to the neat polymer films (p = 0.034). Moreover, the migration process of nanofillers may be negligible but still requires further research. Additionally, the ecotoxicity of nanofillers is unclear, as the final distribution of nanocomposites in the environment is unknown. Conclusions: Nanotechnology helps to overcome the challenges associated with traditional packaging materials. Strong regulatory frameworks and safety standards are needed to ensure the appropriate use of nanocomposites. There is also a need to explore how to realize the economic and technical requirements for large-scale implementation of nanocomposite technologies. Full article

Given the widespread use of esters and polyesters in products like cosmetics, fishing nets, lubricants and adhesives, whose specific application(s) may cause their dispersion in open environments, there is a critical need for stringent eco-design criteria based on biodegradability and ecotoxicity evidence. Our approach integrates experimental and computational methods based on short oligomers, offering a screening tool for the rapid identification of sustainable monomers and oligomers, with a special focus on bio-based alternates. We provide insights into the relationships between the chemical structure and properties of bio-based oligomers in terms of biodegradability in marine environments and toxicity in benchmark organisms. The experimental results reveal that the considered aromatic monomers (terephthalic acid and 2,5-furandicarboxylic acid) accumulate under the tested conditions (OECD 306), although some slight biodegradation is observable when the inoculum derives from sites affected by industrial and urban pollution, which suggests that ecosystems adapt to non-natural chemical pollutants. While clean seas are more susceptible to toxic chemical buildup, biotic catalytic activities offer promise for plastic pollution mitigation. Without prejudice to the fact that biodegradability inherently signifies a desirable trait in plastic products, nor that it automatically grants them a sustainable “license”, this study is intended to facilitate the rational design of new polymers and materials on the basis of specific uses and applications. Full article

Water extracted from natural sources often requires treatment to meet the quality standards necessary for industrial use, involving physico-chemical processes such as coagulation, flocculation, and sedimentation. Inorganic coagulants, such as aluminum sulfate, are commonly used, although they generate a sludge with residual aluminum, classified as hazardous waste. Given this, biocoagulants, such as natural tannin-based polymers, have emerged as a promising alternative. Thus, the objective of this study was to evaluate the environmental performance of water treatment and sludge disposal at an industrial water treatment plant (WTP) of an oil refinery located in Brazil using aluminum sulfate and biocoagulant. The WTP of this study is located in the state of Bahia, Brazil, and is supplied by a surface water body, the Paraguaçu River—Lago de Pedra do Cavalo—which comes from a semi-arid region, and a lake called Catu Korea. The environmental analysis was carried out using the life cycle assessment (LCA) method, using the methodological framework recommended in ISO 14044, followed by economic analysis and circular economy analysis. The inventory used in the analyses contains field data, company records, related literature, and ecoinvent database version 3.3. The impact assessment considered the ILCD 2011 Midpoint+ method package, the AWARE method, and the cumulative energy demand (CED) method in SimaPro 8.4 software. The comparative results showed the greatest impacts in the Energy Demand, Water Footprint, Eutrophication, and Land Use categories for the biocoagulant scenario, in contrast to the Human Toxicity, Acidification, Ecotoxicity, Particulate Matter, Carbon Footprint, and Abiotic Depletion categories for aluminum sulfate. The economic analysis showed that 65% of the operational costs for material and energy inputs in water treatment are due to the use of electricity, and the water pumping stage is the biggest contributor to this consumption. Even though the price of the biocoagulant was identified as eight times that of aluminum sulfate, the water treatment cost with the biocoagulant was 21% higher compared to that with aluminum sulphate. In this regard, circular economy propositions for sludge valorization are discussed for use, recycling, or proper disposal. Thus, the environmental and economic analysis in this study offers insights into eco-efficiency promotion in water treatment and sludge management. Full article

In the subregion of La Paz Province in eastern Antioquia, Colombia, hydrangea floriculture has boosted economic and social development, generating high value in the territory; however, there are still environmental gaps to be resolved to make it a sustainable activity. This study analyzed some environmental aspects of cultivation based on life-cycle assessment under ISO 14040/14044 standards. The functional unit defined was 1 kg of hydrangea stems grown on a small farm of 0.45 ha, and the limits selected were gate-to-gate. The environmental impacts were evaluated using the CML methodology, Umberto LCA + 10.0.03 software, and the Ecoinvent 3.8 database. The most significant contributors to these impacts were ozone depletion, terrestrial ecotoxicity, and photochemical oxidant formation, which come from the application and pretreatment of chemical fertilizers and pesticides, plant residue generation, and fossil resource materials, such as polymers and fuels. In addition, two cleaner production initiatives were considered: composting plant residues for fertilizer (the use of 100% and 50% composting) and integrated pest management with biological control and natural agents to reduce pesticide use (30% and 50% of chemical pesticides). And the integration of both actions, with 50% composting and 30% substitution of chemical pesticides, was considered. The environmental impacts were reduced by 19.63% and 9.97%, respectively, for composting, 6.62% and 11.03%, respectively, for biological control, and 16.59% for the integration of actions. The two alternatives allowed for improving the crop, contributing to the minimization of environmental impacts, optimizing the use of inputs and fertilizers, and contributing to the sustainable development of floriculture. Full article

Blends of poly(lactic acid) (PLA) with poly(propylene carbonate) (PPC) are currently in the phase of intensive study due to their promising properties and environmentally friendly features. Intensive study and further commercialization of PPC-based polymers or their blends, as usual, will soon face the problem of their waste occurring in the environment, including soil. For this reason, it is worth comprehensively studying the degradation rate of these polymers over a long period of time in soil and, for comparison, in phosphate buffer to understand the difference in this process and evaluate the potential application of such materials toward agrochemical and agricultural purposes. The degradation rate of the samples was generally accompanied by weight loss and a decrease in molecular weight, which was facilitated by the presence of PPC. The incubation of the samples in the aqueous media yielded greater surface erosions compared to the degradation in soil, which was attributed to the leaching of the low molecular degradation species out of the foils. The phytotoxicity study confirmed the no toxic impact of the PPC on tested plants, indicating it as a “green” material, which is crucial information for further, more comprehensive study of this polymer toward any type of sustainable application. Full article

Micro(nano)plastics (MNPs) can be generated from a variety of sources, including the breakdown of larger plastic items, the abrasion of synthetic textiles, and the fragmentation of plastic waste. These particles can become airborne and be transported by wind, potentially leading to their presence in the atmosphere. Due to their widespread applications, ZnO particles at the nanometer range have attractive proprieties that make them appropriate for being combined with polymers, especially PET (polyethylene terephthalate), the most commonly used polymer in the packaging sector. Nevertheless, ZnO NPs have a potential ecotoxicity that could be reflected in PET-ZnO composites reaching the environment in the form of micro(nano)plastics. To assess the potential release of PET-ZnO, as well as the ecotoxicity of ZnO NPs, PET-ZnO and weathered composites were analyzed. The ecotoxicity of PET-ZnO was tested in organisms representing different food-chain levels and compared to ZnO NPs’ ecotoxicity. The composite form contained a stable dispersion of around 3.7% of NPs uniformly scattered in the polymeric matrix. ZnO NPs were toxic to Vibrio fischeri and Brachionus calyciflorus. PET-ZnO did not exhibited any toxicity to the organisms studied, while a moderate level of toxicity was observed for the weathered forms. Full article

Food spoilage is an ongoing global issue that contributes to rising carbon dioxide emissions and increased demand for food processing. This work developed anti-bacterial coatings utilising inkjet printing of silver nano-inks onto food-grade polymer packaging, with the potential to enhance food safety and reduce food spoilage. Silver nano-inks were synthesised via laser ablation synthesis in solution (LaSiS) and ultrasound pyrolysis (USP). The silver nanoparticles (AgNPs) produced using LaSiS and USP were characterised using transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, UV-Vis spectrophotometry and dynamic light scattering (DLS) analysis. The laser ablation technique, operated under recirculation mode, produced nanoparticles with a small size distribution with an average diameter ranging from 7–30 nm. Silver nano-ink was synthesised by blending isopropanol with nanoparticles dispersed in deionised water. The silver nano-inks were printed on plasma-cleaned cyclo-olefin polymer. Irrespective of the production methods, all silver nanoparticles exhibited strong antibacterial activity against E. coli with a zone of inhibition exceeding 6 mm. Furthermore, silver nano-inks printed cyclo-olefin polymer reduced the bacterial cell population from 1235 (±45) × 10⁶ cell/mL to 960 (±110) × 10⁶ cell/mL. The bactericidal performance of silver-coated polymer was comparable to that of the penicillin-coated polymer, wherein a reduction in bacterial population from 1235 (±45) × 10⁶ cell/mL to 830 (±70) × 10⁶ cell/mL was observed. Finally, the ecotoxicity of the silver nano-ink printed cyclo-olefin polymer was tested with daphniids, a species of water flea, to simulate the release of coated packaging into a freshwater environment. Full article