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Keywords = plastograph

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16 pages, 2088 KB  
Article
Predictive Modelling and Optimisation of Rubber Blend Mixing Using a General Regression Neural Network
by Ivan Kopal, Ivan Labaj, Juliána Vršková, Marta Harničárová, Jan Valíček, Alžbeta Bakošová, Hakan Tozan and Ashish Khanna
Polymers 2025, 17(13), 1868; https://doi.org/10.3390/polym17131868 - 3 Jul 2025
Cited by 3 | Viewed by 2197
Abstract
This paper presents an intelligent predictive system designed to support real-time decision making in the control of rubber blend mixing processes. The core of the system is a General Regression Neural Network (GRNN), which accurately predicts key process parameters, such as viscosity (expressed [...] Read more.
This paper presents an intelligent predictive system designed to support real-time decision making in the control of rubber blend mixing processes. The core of the system is a General Regression Neural Network (GRNN), which accurately predicts key process parameters, such as viscosity (expressed as torque), temperature, and energy consumption across varying masses of the processed material. The model can evaluate the mixing progress based on the initial 10% of input data, allowing early intervention and process optimisation. Experimental validation was conducted using a Brabender Plastograph EC Plus with a natural rubber-based blend in the mass range of 60–75 g. The GRNN kernel width parameter (σ) was optimised through a 10-fold cross-validation. High predictive accuracy was confirmed by values of the coefficient of determination (R2) approaching 1, and consistently low values of the root mean square error (RMSE). This system offers a robust and scalable solution for intelligent process control, productivity enhancement, and quality assurance across diverse industrial applications, beyond rubber blending. Full article
(This article belongs to the Special Issue Artificial Intelligence in Polymers)
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15 pages, 4526 KB  
Article
Dielectric Properties of Isotactic Polypropylene with Lignocellulose-Based Biomass Filler
by Dragana D. Cerovic, Ivan M. Petronijevic, Filip S. Marinkovic, Slavica B. Maletic and Dusan M. Popovic
Materials 2025, 18(7), 1657; https://doi.org/10.3390/ma18071657 - 4 Apr 2025
Cited by 1 | Viewed by 1040
Abstract
The ecological aspect of substituting synthetic materials with natural materials is of great interest nowadays. This paper examines the percentage of lignocellulose-based fillers that can be added to a synthetic polymer matrix to ensure the resulting biocomposite maintains its dielectric properties. Biocomposites were [...] Read more.
The ecological aspect of substituting synthetic materials with natural materials is of great interest nowadays. This paper examines the percentage of lignocellulose-based fillers that can be added to a synthetic polymer matrix to ensure the resulting biocomposite maintains its dielectric properties. Biocomposites were made from isotactic polypropylene (iPP) and various proportions (20%, 30%, and 40%) of oats, rye, wheat, and barley bran and granules from corn cobs using a Brabender plastograph and a hydraulic hot press. From a morphological analysis, it was noted that the particles were well incorporated into the polymer matrix. The frequency-dependent behavior of the dielectric properties was analyzed across a frequency range from 30 Hz to 60 kHz at a room temperature of 23 °C and 35% relative humidity. The obtained results showed that the incorporation of biomasses into the iPP matrix increased the values of the dielectric properties across the entire measured frequency range. The samples with wheat showed the most stable values of the dielectric parameters with frequency changes, for all three concentrations. A linear regression analysis showed a very high coefficient of determination (R2 = 0.997) between the effective dielectric permeability and filler concentration at 30 Hz for the samples with wheat. Furthermore, the biocomposite iPP/20% wheat showed a desirable balance of dielectric properties for electronic applications. The results showed that biocomposites obtained by adding cheap lignocellulose-based biomass, such as bran or granules from corn cobs, to a synthetic polymer matrix have a great potential for use as electrically insulating materials because their dielectric parameters are comparable to those of standard insulating materials. Full article
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25 pages, 8010 KB  
Article
Physical, Mechanical, and Morphological Properties of Treated Sugar Palm/Glass Reinforced Poly(Lactic Acid) Hybrid Composites
by S. F. K. Sherwani, E. S. Zainudin, S. M. Sapuan, Z. Leman and A. Khalina
Polymers 2021, 13(21), 3620; https://doi.org/10.3390/polym13213620 - 20 Oct 2021
Cited by 13 | Viewed by 2820
Abstract
This research was performed to evaluate the physical, mechanical, and morphological properties of treated sugar palm fiber (SPF)/glass fiber (GF) reinforced poly(lactic acid) (PLA) hybrid composites. Morphological investigations of tensile and flexural fractured samples of composites were conducted with the help of scanning [...] Read more.
This research was performed to evaluate the physical, mechanical, and morphological properties of treated sugar palm fiber (SPF)/glass fiber (GF) reinforced poly(lactic acid) (PLA) hybrid composites. Morphological investigations of tensile and flexural fractured samples of composites were conducted with the help of scanning electron microscopy (SEM). Alkaline and benzoyl chloride (BC) treatments of SPFs were performed. A constant weight fraction of 30% total fiber loading and 70% poly(lactic acid) were considered. The composites were initially prepared by a Brabender Plastograph, followed by a hot-pressing machine. The results reported that the best tensile and flexural strengths of 26.3 MPa and 27.3 MPa were recorded after alkaline treatment of SPF, while the highest values of tensile and flexural moduli of 607 MPa and 1847 MPa were recorded after BC treatment of SPF for SPF/GF/PLA hybrid composites. The novel SPF/GF/PLA hybrid composites could be suitable for fabricating automotive components. Full article
(This article belongs to the Special Issue Mechanical Performance of Sustainable Bio-Based Compounds)
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13 pages, 3782 KB  
Article
Thermo Compression of Thermoplastic Agar-Xanthan Gum-Carboxymethyl Cellulose Blend
by Smarak Bandyopadhyay, Tomáš Sáha, Daniel Sanétrník, Nabanita Saha and Petr Sáha
Polymers 2021, 13(20), 3472; https://doi.org/10.3390/polym13203472 - 10 Oct 2021
Cited by 14 | Viewed by 3547
Abstract
There is a gap in the literature for the preparation of agar-xanthan gum-carboxymethyl cellulose-based films by thermo compression methods. The present work aims to fill this gap by blending the polysaccharides in a plastograph and preparation of films under high pressure and temperature [...] Read more.
There is a gap in the literature for the preparation of agar-xanthan gum-carboxymethyl cellulose-based films by thermo compression methods. The present work aims to fill this gap by blending the polysaccharides in a plastograph and preparation of films under high pressure and temperature for a short duration of time. The pivotal aim of this work is also to know the effect of different mixing conditions on the physical, chemical, mechanical and thermal properties of the films. The films are assessed based on results from microscopic, infrared spectroscopic, permeability (WVTR), transmittance, mechanical, rheological and thermogravimetric analysis. The results revealed that the mixing volume and mixing duration had negative effects on the films’ transparency. WVTR was independent of the mixing conditions and ranged between 1078 and 1082 g/m2·d. The mixing RPM and mixing duration had a positive effect on the film tensile strength. The films from the blends mixed at higher RPM for a longer time gave elongation percentage up to 78%. Blending also altered the crystallinity and thermal behavior of the polysaccharides. The blend prepared at 80 RPM for 7 min and pressed at 140 °C showed better percent elongation and light barrier properties. Full article
(This article belongs to the Special Issue Stabilization of Bio-Based Polymeric Materials)
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21 pages, 14086 KB  
Article
Mechanical Properties of Sugar Palm (Arenga pinnata Wurmb. Merr)/Glass Fiber-Reinforced Poly(lactic acid) Hybrid Composites for Potential Use in Motorcycle Components
by S. F. K. Sherwani, E. S. Zainudin, S. M. Sapuan, Z. Leman and K. Abdan
Polymers 2021, 13(18), 3061; https://doi.org/10.3390/polym13183061 - 10 Sep 2021
Cited by 30 | Viewed by 4702
Abstract
This research aims to determine the mechanical properties of sugar palm fiber (Arenga pinnata Wurmb. Merr) (SPF)/glass fiber (GF)-reinforced poly(lactic acid) (PLA) hybrid composites for potential use in motorcycle components. The mechanical (hardness, compressive, impact, and creep) and flammability properties of SPF/GF/PLA [...] Read more.
This research aims to determine the mechanical properties of sugar palm fiber (Arenga pinnata Wurmb. Merr) (SPF)/glass fiber (GF)-reinforced poly(lactic acid) (PLA) hybrid composites for potential use in motorcycle components. The mechanical (hardness, compressive, impact, and creep) and flammability properties of SPF/GF/PLA hybrid composites were investigated and compared to commercially available motorcycle Acrylonitrile Butadiene Styrene (ABS) plastic components. The composites were initially prepared using a Brabender Plastograph, followed by a compression molding method. This study also illustrated the tensile and flexural stress–strain curves. The results revealed that alkaline-treated SPF/GF/PLA had the highest hardness and impact strength values of 88.6 HRS and 3.10 kJ/m2, respectively. According to the results, both alkaline and benzoyl chloride treatments may improve the mechanical properties of SPF/GF/PLA hybrid composites, and a short-term creep test revealed that the alkaline treated SPF/GF/PLA composite displayed the least creep deformation. The findings of the horizontal UL 94 testing indicated that the alkaline-treated SPF/GF/PLA hybrid composites had good flame resistance. However, alkaline-treated SPF/GF/PLA composites are more suitable materials for motorcycle components. Full article
(This article belongs to the Special Issue High-Performance Biocomposite Reinforced by Natural Fibers)
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13 pages, 8300 KB  
Article
Effects of Pulp Fiber and Epoxidized Tung Oil Content on the Properties of Biocomposites Based on Polylactic Acid
by Van Khoi Nguyen, Thanh Tung Nguyen, Thu Ha Pham Thi and Thu Trang Pham
J. Compos. Sci. 2020, 4(2), 56; https://doi.org/10.3390/jcs4020056 - 19 May 2020
Cited by 9 | Viewed by 3434
Abstract
Recently, various environmental-friendly materials have been investigated and developed, especially composites of polylactic acid (PLA) and plant fibers. This paper investigates the effects of pulp fiber (PF) and epoxidized Tung oil (ETO) content on the properties of biocomposites, based on polylactic acid. The [...] Read more.
Recently, various environmental-friendly materials have been investigated and developed, especially composites of polylactic acid (PLA) and plant fibers. This paper investigates the effects of pulp fiber (PF) and epoxidized Tung oil (ETO) content on the properties of biocomposites, based on polylactic acid. The bleached pulp fiber reinforced PLA (PLA/PF) composites with 10–50 wt% fiber contents and 0–15% epoxidized Tung oil contents (with a certain number of fiber) were prepared in an internal mixer (Plastograph® EC) at 150 °C. The mechanical properties of PLA/PF composites were improved significantly. The pulp fiber reinforced PLA composites, with the fiber content of 30 wt%, were found to have the highest mechanical properties. The tensile and flexural properties of PLA/Tung oil-soaked-pulp fiber composites were higher than those of PLA/Tung oil unsoaked pulp fiber composites. In addition, the degradation temperature of PLA-based composites decreased after adding more pulp fiber. The pulp fibers were well-dispersed in the PLA matrix with the content up to 30 wt%. The interaction between pulp fiber and PLA matrix improved by the addition of epoxidized Tung oil. Epoxidized Tung oil also improved tensile and flexural strength of composite materials when it was added with a number of below 10% of fiber. Full article
(This article belongs to the Special Issue Multifunctional Composites)
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