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Keywords = phebox ligand

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9 pages, 719 KB  
Communication
Chlorination of (Phebox)Ir(mesityl)(OAc) by Thionyl Chloride
by Meng Zhou and Alan S. Goldman
Molecules 2015, 20(6), 10122-10130; https://doi.org/10.3390/molecules200610122 - 1 Jun 2015
Cited by 3 | Viewed by 8566
Abstract
Pincer (Phebox)Ir(mesityl)(OAc) (2) (Phebox = 3,5-dimethylphenyl-2,6-bis(oxazolinyl)) complex, formed by benzylic C-H activation of mesitylene (1,3,5-trimethylbenzene) using (Phebox)Ir(OAc)2OH2 (1), was treated with thionyl chloride to rapidly form 1-(chloromethyl)-3,5-dimethylbenzene in 50% yield at 23 °C. A green species [...] Read more.
Pincer (Phebox)Ir(mesityl)(OAc) (2) (Phebox = 3,5-dimethylphenyl-2,6-bis(oxazolinyl)) complex, formed by benzylic C-H activation of mesitylene (1,3,5-trimethylbenzene) using (Phebox)Ir(OAc)2OH2 (1), was treated with thionyl chloride to rapidly form 1-(chloromethyl)-3,5-dimethylbenzene in 50% yield at 23 °C. A green species was obtained at the end of reaction, which decomposed during flash column chromatography to form (Phebox)IrCl2OH2 in 87% yield. Full article
(This article belongs to the Special Issue C-H Bond Activation and Functionalization)
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