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Keywords = nano-alkaline-surfactant-polymer

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24 pages, 6511 KB  
Article
Relation between Conventional and Starch-Assisted ASP Injection and Impact of Crystallinity on Flood Formation
by Hasanain A. Al-Jaber, Agus Arsad, Sulalit Bandyopadhyay, Mohd Zaidi Jaafar, Muhammad Tahir, Mustafa Jawad Nuhma, Abdulmunem R. Abdulmunem, Mohammad Yasin Abdulfatah and Hajar Alias
Molecules 2023, 28(18), 6685; https://doi.org/10.3390/molecules28186685 - 18 Sep 2023
Cited by 2 | Viewed by 2104
Abstract
Alkaline–surfactant–polymer (ASP) flooding, a recognized method for oil recovery, encounters limited use due to its expense. In addition, ASP’s best composition and injection sequence still remains uncertain today. This study explores conventional ASP flooding using PT SPR Langgak’s special surfactants, simulating Langgak oilfield [...] Read more.
Alkaline–surfactant–polymer (ASP) flooding, a recognized method for oil recovery, encounters limited use due to its expense. In addition, ASP’s best composition and injection sequence still remains uncertain today. This study explores conventional ASP flooding using PT SPR Langgak’s special surfactants, simulating Langgak oilfield conditions in Sumatra, Indonesia. By comparing the outcomes of this flooding technique with that of starch-assisted ASP performed in another study, the benefits of adding starch nanoparticles to flooding are evident. Nano-starch ASP increased oil recovery by 18.37%, 10.76%, and 10.37% for the three configurations investigated in this study. Water flooding preceded ASP flooding, and flooding operations were carried out at 60 °C. This study employed sodium hydroxide (NaOH), sodium carbonate (Na2CO3), and specialized surfactants from PT SPR. The adopted polymer is solely hydrolyzed polyacrylamide (HPAM) at 2000 ppm. Starch nanoparticles underwent comprehensive characterization and focused more on charge stability. Purple yam nanoparticles (PYNPs) exhibited remarkable stability at −36.33 mV, unlike cassava starch nanoparticles (CSNPs’) at −10.68 mV and HPAM’s at −27.13 mV. Surface properties affect interactions with fluids and rocks. Crystallinity, a crucial characterization, was assessed using Origin software 2019b. CSNPs showed 24.15% crystallinity, surpassing PYNPs’ 20.68%. Higher crystallinity benefits CSNPs’ thermal stability. The amorphous behavior found in PYNPs makes them less suitable if applied in harsh reservoirs. This research correlated with prior findings, reinforcing starch nanoparticles’ role in enhancing oil recovery. In summary, this study highlighted conventional ASP flooding using HPAM as the sole polymer and compared it with three formations that used two starch nanoparticles included with HPAM, assessing their impact on charge stability, crystallinity, and recovery rate to emphasize their importance in the oil recovery industry. Starch nanoparticles’ benefits and limitations guided further investigation in this study. Full article
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33 pages, 13851 KB  
Article
Enhancing ASP Flooding by Using Special Combinations of Surfactants and Starch Nanoparticles
by Hasanain A. Al-Jaber, Agus Arsad, Sulalit Bandyopadhyay, Muslim Abdurrahman, Mohammad Yasin Abdulfatah, Augustine Agi, Suriatie Mat Yusuf, Abdulmunem R. Abdulmunem, Muhammad Tahir and Mustafa Jawad Nuhma
Molecules 2023, 28(15), 5770; https://doi.org/10.3390/molecules28155770 - 31 Jul 2023
Cited by 17 | Viewed by 3747
Abstract
This study aimed to address the challenges faced by mature oilfields in extracting substantial oil quantities. It focused on improving the efficiency of alkaline–surfactant–polymer (ASP) flooding technique, which is a proven tertiary recovery technology, to overcome scaling issues and other hindrances in its [...] Read more.
This study aimed to address the challenges faced by mature oilfields in extracting substantial oil quantities. It focused on improving the efficiency of alkaline–surfactant–polymer (ASP) flooding technique, which is a proven tertiary recovery technology, to overcome scaling issues and other hindrances in its large-scale implementation. Appropriate materials and their suitable concentrations were selected to enhance the ASP flooding technique. Special surfactants from Indonesia were introduced to improve the interfacial tension reduction and wettability alteration. Reservoir rock model that resembling Langgak oilfield in Sumatra was utilized, and low-salinity water was employed to mimic the oilfield conditions. Starches derived from cassava nanoparticles (CSNPs) and purple yam nanoparticles (PYNPs) were combined separately with conventional hydrolyzed polyacrylamide (HPAM) polymer to enhance its performance. Sodium hydroxide and sodium carbonate were used as alkaline in final ASP formula. It was demonstrated from this research that only two combinations of ASP formulations have led to improved oil recovery. One combination utilizing PYNPs resulted in 39.17% progressive recovery, while the other combination incorporating CSNPs achieved 35% incremental oil recovery. The ASP combination that resulted in recovery rate of 39.17% was composed of sodium hydroxide (NaOH) at a concentration of 1.28 wt.%, PSC EOR 2.2 (0.98 wt.%), and a combined polymer consisting of HPAM (0.2 wt.%) and PYNPs nano-starch (0.6 wt.%). The second combination led to 35% recovery rate and involved NaOH also at concentration 1.28 wt.%, PSC HOMF (0.63 wt.%), and a combined polymer comprising from HPAM (0.2 wt.%) and CSNPs nano-starch (0.8 wt.%). These findings of this study highlighted the potential of this modified ASP flooding to enhance oil recovery in mature oilfields, thereby offering valuable insights for oil industry. Full article
(This article belongs to the Topic Advances in Chemistry and Chemical Engineering)
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29 pages, 3289 KB  
Review
A Critical Overview of ASP and Future Perspectives of NASP in EOR of Hydrocarbon Reservoirs: Potential Application, Prospects, Challenges and Governing Mechanisms
by Rasan Sarbast, Namam Salih and Alain Préat
Nanomaterials 2022, 12(22), 4007; https://doi.org/10.3390/nano12224007 - 14 Nov 2022
Cited by 20 | Viewed by 4252
Abstract
Oil production from depleted reservoirs in EOR (Enhanced Oil Recovery) techniques has significantly increased due to its huge demands in industrial energy sectors. Chemical EOR is one of the best approaches to extract the trapped oil. However, there are gaps to be addressed [...] Read more.
Oil production from depleted reservoirs in EOR (Enhanced Oil Recovery) techniques has significantly increased due to its huge demands in industrial energy sectors. Chemical EOR is one of the best approaches to extract the trapped oil. However, there are gaps to be addressed and studied well for quality and cost consideration in EOR techniques. Therefore, this paper addresses for the first time a systematic overview from alkaline surfactant polymer ((ASP)) and future perspectives of nano-alkaline surfactant polymer ((NASP)), its synergy effects on oil recovery improvement, and the main screening criteria for these chemicals. The previous findings have demonstrated that the optimum salinity, choosing the best concentration, using effective nano-surfactant, polymer and alkaline type, is guaranteed an ultra-low IFT (Interfacial Tension). Core flood results proved that the maximum oil is recovered by conjugating nanoparticles with conventional chemical EOR methods (surfactant, alkaline and polymer). This work adds a new insight and suggests new recommendation into the EOR application since, for the first time, it explores the role and effect of nanotechnology in a hybrid with ASP. The study illustrates detailed experimental design of using NASP and presents an optimum micro-model setup for future design of NASP flow distribution in the porous media. The presence of nano along with other chemicals increases the capillary number as well as the stability of chemicals in the solution and strengthens the effective mechanisms on the EOR. Full article
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