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Keywords = nabimusaite group

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14 pages, 4227 KB  
Article
New Mineral with Modular Structure Derived from Hatrurite from the Pyrometamorphic Rocks of the Hatrurim Complex: Ariegilatite, BaCa12(SiO4)4(PO4)2F2O, from Negev Desert, Israel
by Evgeny V. Galuskin, Biljana Krüger, Irina O. Galuskina, Hannes Krüger, Yevgeny Vapnik, Justyna A. Wojdyla and Mikhail Murashko
Minerals 2018, 8(3), 109; https://doi.org/10.3390/min8030109 - 8 Mar 2018
Cited by 21 | Viewed by 7194
Abstract
Ariegilatite, BaCa12(SiO4)4(PO4)2F2O (R 3 ¯ m, a = 7.1551(6) Å, c = 41.303(3) Å, V = 1831.2(3) Å3, Z = 3), is a new member of the [...] Read more.
Ariegilatite, BaCa12(SiO4)4(PO4)2F2O (R 3 ¯ m, a = 7.1551(6) Å, c = 41.303(3) Å, V = 1831.2(3) Å3, Z = 3), is a new member of the nabimusaite group exhibiting a modular intercalated antiperovskite structure derived from hatrurite. It was found in a few outcrops of pyrometamorphic rocks of the Hatrurim Complex located in the territories of Israel, Palestine and Jordan. The holotype specimen is an altered spurrite marble from the Negev Desert near Arad city, Israel. Ariegilatite is associated with spurrite, calcite, brownmillerite, shulamitite, CO3-bearing fluorapatite, fluormayenite-fluorkyuygenite and a potentially new mineral, Ba2Ca18(SiO4)6(PO4)3(CO3)F3O. Ariegilatite is overgrown and partially replaced by stracherite, BaCa6(SiO4)2[(PO4)(CO3)]F. The mineral forms flat disc-shaped crystals up to 0.5 mm in size. It is colorless, transparent, with white steaks and vitreous luster. Optically, ariegilatite is uniaxial, negative: ω = 1.650(2), ε = 1.647(2) (λ = 589 nm). The mean composition of the holotype ariegilatite, (Ba0.98K0.01Na0.01)Σ1(Ca11.77Na0.08Fe2+0.06Mn2+0.05Mg0.04)Σ12(Si3.95Al0.03Ti0.02)Σ4(P1.70C0.16Si0.10S6+0.03V0.01)Σ2F2.04O0.96, is close to the end-member formula. The structure of ariegilatite is described as a stacking of the two modules {F2OCa12(SiO4)4}4+ and {Ba(PO4)2}4− along (001). Ariegilatite, as well as associated stracherite, are high-temperature alteration products of minerals of an early clinker-like association. These alterations took place under the influence of pyrometamorphism by-products, such as gases and fluids generated by closely-spaced combustion foci. Full article
(This article belongs to the Special Issue New Mineral Species and Their Crystal Structures)
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