Search Results (123)

This paper explores the role of one-part alkali-activated cement, utilizing metakaolin as a precursor, in the long-term stabilization of mining tailings. Investigating three key factors (Si/Al and Na/Si ratios and curing period), this study reveals insights into the mechanical performance and microstructure of alkali-activated cemented iron ore tailings. Unconfined compressive strength test, statistical analysis, and Scanning Electron Microscopy analysis with Energy Dispersive Spectroscopy were performed. Findings indicate that the Si/Al ratio significantly influences strength, with an optimal ratio of 3.5. The Na/Si ratio introduces complexity, affecting alkali availability and reactivity, leading to nuanced strength variations. Extended curing periods consistently enhance the strength of alkali-activated cement, highlighting its dynamic nature. Notably, the 7-day specimens exhibit a less homogeneous distribution, weaker bonding, and decreased structural integrity compared to their 60-day counterparts. This research underscores the intricate nature of alkali-activated cement hydration, emphasizing the interdependence of Si/Al and Na/Si ratios. The observed strengthening effect with prolonged curing suggests the potential for tailoring these materials to specific applications. Addressing a research gap, especially in applying alkali-activation to mining tailings stabilization, this study highlights metakaolin’s role as a suitable precursor. Full article

This study introduces CO₂ laser surface vitrification as an innovative method for managing copper mining tailings, offering a sustainable solution to critical challenges in mineral processing. This technique transforms tailings into a stable and impermeable layer, immobilizing hazardous metals contained within them. By achieving vitrification at the surface level and operating at temperatures around 1200 °C, the process significantly reduces energy consumption compared to traditional vitrification methods, making it suitable for large-scale applications in remote mining sites. Detailed geochemical and mechanical analyses confirmed the formation of a dense vitreous matrix with high hardness (7.19–7.48 GPa) and reduced permeability, ensuring compliance with stringent environmental regulations. However, the brittle nature of the vitrified layer underscores the need for further research to enhance mechanical resilience. This work positions CO₂ laser vitrification as a transformative approach for integrating energy-efficient technologies into mineral processing, addressing key environmental concerns while advancing the sustainable management of mining waste. Full article

Resource depletion and environmental degradation have resulted from the substantial increase in the use of natural aggregates and construction materials brought on by the growing demand for infrastructure development. Road building using mining waste has become a viable substitute that reduces the buildup of industrial waste while providing ecological and economic advantages. In order to assess the appropriateness of several mining waste materials for use in road building, this study investigates their engineering characteristics. These materials include slag, fly ash, tailings, waste rock, and overburden. To ensure long-term performance in pavement applications, this study evaluates their tensile and compressive strength, resistance to abrasion, durability under freeze–thaw cycles, and chemical stability. This review highlights the potential of mining waste materials as sustainable alternatives in road construction. Waste rock and slag exhibit excellent mechanical strength and durability, making them suitable for high-traffic pavements. Although fly ash and tailings require stabilization, their pozzolanic properties enhance subgrade reinforcement and soil stabilization. Properly processed overburden materials are viable for subbase and embankment applications. By promoting the reuse of mining waste, this study supports landfill reduction, carbon emission mitigation, and circular economy principles. Overall, mining byproducts present a cost-effective and environmentally responsible alternative to conventional construction materials. To support broader implementation, further efforts are needed to improve stabilization techniques, monitor long-term field performance, and establish effective policy frameworks. Full article

The swift advancement of China’s mining sector has led to the generation of substantial amounts of industrial solid waste, which poses significant risks to the ecological environment. This study aims to investigate effective methods for utilizing industrial solid waste in the production of mine filling materials, thereby facilitating green mine construction and the efficient use of resources. The study employs the PRISMA methodology to conduct a systematic review of the pertinent literature, analyzing the current status, challenges, and developmental trends associated with the use of coal-based solid waste, smelting waste, industrial by-product gypsum, and tailings in filling materials. The findings indicate that, while the use of individual coal-based solid waste in filling materials shows promise, there is a need to optimize the ratios and activation technologies. Furthermore, the synergistic application of multi-source coal-based solid waste can enhance the overall utilization rate; however, further investigation into the reaction mechanisms and ratio optimization is required. Smelting slag can serve as a cementing agent or aggregate post-treatment, yet further research is necessary to improve its strength and durability. Industrial by-product gypsum can function as an auxiliary cementing material or activator, although its large-scale application faces significant challenges. Tailings present advantages as aggregates, but concerns regarding their long-term stability and environmental impacts must be addressed. Future research should prioritize the synergistic utilization of multi-source solid waste, performance customization, low-carbon activation technologies, and enhancements in environmental safety. Additionally, the establishment of a comprehensive lifecycle evaluation and standardization system is essential to transition the application of industrial solid-waste-based filling materials from empirical ratios to mechanism-driven approaches, ultimately achieving the dual objectives of green mining and the resource utilization of solid waste in mining operations. Full article

An alternative to conventional methods for mine tailings disposal is stabilization with alkali-activated binders (AABs), developed from agro-industrial waste. Despite increasing interest in this topic, there is still a lack of studies focusing on the stabilization of iron ore tailings (IOTs) using AABs, particularly those that combine the characterization of cementitious gels with an evaluation of leaching behavior. This study assessed the strength, mineralogy, and leaching performance of IOTs stabilized with AABs formulated from rice husk ash (RHA) and hydrated eggshell lime (HEL), using sodium hydroxide as the alkaline activator. Tests included unconfined compressive strength (UCS), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and metal leaching analyses. The IOT–AAB mixture with the highest AAB content and dry unit weight achieved an average UCS of 2.14 MPa after 28 days of curing. UCS increased with AAB content, followed by dry unit weight and curing time, the latter showing a non-linear influence. The formation of C–S–H gel was confirmed after 28 days, while N–A–S–H gel was detected as early as 7 days of curing. The cemented IOT–AAB mixtures showed no metal toxicity and effectively encapsulated barium originating from the RHA. Full article

The characterisation of shear modulus degradation is essential for understanding the dynamic response of geomaterials. This article presents a modified hyperbolic model that evaluates the shear modulus for various angular strains and effective confining stresses. The model has been calibrated and validated using data from 108 resonant-column tests conducted on three different types of tailings from the Riotinto mines in Huelva, Spain. These tests were conducted on saturated samples that were consolidated at effective stresses of 50, 100, 150, 200, 250, and 300 kPa, accompanied by various combinations of torsional excitations to induce distinct angular strains. The results show that the hyperbolic model effectively predicts the shear modulus degradation in unconventional geomaterials, characterising the shear modulus under the testing conditions for the three types of Riotinto tailings. Additionally, the model can identify and confirm both the initial (or maximum) shear modulus and the reference angular strain as functions of the effective confining stress. The findings and model presented in this article contribute to enhancing the stability and resilience of geotechnical structures, including tailings storage facilities, that are subjected to dynamic loading, leading to safer designs and improved infrastructure performance. Full article

This study evaluated the phytoremediation of mine tailing-contaminated soils in Quiulacocha, Peru, using the combined application of biochar and compost, with Zea mays L. (maize) serving as the phytoremediator due to its high biomass production and stress tolerance. A factorial experimental design was implemented, varying two main factors: the mining tailings dose (30% and 60% w/w) and the biochar pyrolysis temperature (300 °C and 500 °C). The mine tailings were characterized by high concentrations of heavy metals and unfavourable physico-chemical properties (pH, low organic matter), whereas the biochar, produced from pine forest residues, and the compost, derived from urban organic waste, exhibited attributes that enhance soil quality. During the pot experiment, response variables including the Bioconcentration Factor (BCF) and Translocation Factor (TF) for various metals were evaluated to assess the capacity for contaminant immobilization and their distribution between plant roots and aerial tissues. The results demonstrated that the incorporation of biochar and compost significantly improved soil quality by increasing pH, cation exchange capacity, and nutrient retention, while simultaneously reducing the bioavailability of heavy metals and limiting their translocation to the aerial parts of maize. Factorial analysis further indicated that both the tailings dose and biochar pyrolysis temperature significantly influenced the efficacy of the phytoremediation process. In conclusion, the combined application of biochar and compost presents an effective and sustainable strategy for rehabilitating mine tailing-contaminated soils by stabilizing heavy metals and promoting the safe growth of Zea mays L. Full article

Acid mine drainage (AMD) has serious impacts on the environment. To inhibit the generation of AMD from copper sulfide tailings at the source, in this paper, a strategy is developed for promoting the biopassivation of copper sulfide tailings using algal biochar, and the effects of the pyrolysis temperature and concentration of algal biochar on the passivation efficiency and stability are investigated. The results reveal that the introduction of algal biochar during the biopassivation of copper sulfide tailings significantly enhances the tailings passivation effect of the tested Acidithiobacillus ferrooxidans strain and greatly stabilizes the formed passivation layer. Algal biochar prepared with a pyrolysis temperature of 300 °C and applied at a concentration of 6 g/L not only optimizes biopassivation but also significantly improves the stability of the passivation layer. The complex mechanisms of algal biochar in this system include regulating the pH and oxidation‒reduction potential of the reaction system, effectively adsorbing microbial cells, efficiently aggregating metal cations in solution, stimulating the synthesis of extracellular polymeric substances, and accelerating electron transfer. This research offers a novel method for the benign treatment of copper sulfide tailings and resource utilization of algae. Full article

The increasing global demand for metals, driven by technological progress and the energy transition, has led to an acceleration in the expansion of the mining and metallurgical industry, resulting in an increase in the generation of mine tailings. This waste, which is of heterogeneous composition and has high contaminant potential, represents significant environmental and social challenges, affecting soils, water, and the geotechnical stability of tailings. The accumulation of these mine tailings poses a problem not only in terms of quantity, but also in terms of physicochemical composition, which exacerbates their environmental impact due to the release of heavy metals, affecting ecosystems and nearby communities. This article reviews the potential of geopolymerization and 3D printing as a technological solution for the management of tailings, offering an effective alternative for their reuse as sustainable building materials. Alkaline activation of aluminosilicates facilitates the formation of N–A–S–H and C–A–S–H cementitious structures, thereby providing enhanced mechanical strength and chemical stability. Conversely, 3D printing optimizes structural design and minimizes material consumption, thereby aligning with the principles of a circular eco-economy and facilitating carbon footprint mitigation. The present study sets out to compare different types of tailings and their influence on geopolymer reactivity, workability, and mechanical performance. In order to achieve this, the study analyses factors such as the Si/Al ratio, rheology, and setting. In addition, the impact of alkaline activators, additives, and nanoparticles on the extrusion and interlaminar cohesion of 3D printed geopolymers is evaluated. These are key aspects of their industrial application. A bibliometric analysis was conducted, which revealed the growth of research in this field, highlighting advances in optimized formulations, encapsulation of hazardous waste, CO₂ capture, and self-healing geopolymers. The analysis also identified technical and regulatory challenges to scalability, emphasizing the necessity to standardize methodologies and assess the life cycle of materials. The findings indicated that 3D printing with tailings-derived geopolymers is a viable alternative for sustainable construction, with applications in pavements, prefabricated elements, and materials resistant to extreme environments. This technology not only reduces mining waste but also promotes the circular economy and decarbonization in the construction industry. Full article

Cemented tailings backfill (CTB) plays an important role in mine filling operations. In order to study the long-term stability of CTB under the dynamic disturbance of deep wells, ultrafine cemented tailings backfill was taken as the research object, and the true triaxial hydraulic fracturing antireflection-wetting dynamic experimental system of coal and rock was used to carry out a static true triaxial compression test, a true triaxial compression test under unidirectional disturbance, and a true triaxial compression test under bidirectional disturbance. At the same time, the acoustic emission monitoring and positioning tests of the CTB were carried out during the compression test. The evolution law of the mechanical parameters and deformation and failure characteristics of CTB under different confining pressures is analyzed, and the damage constitutive model of the filling body is established using stochastic statistical theory. The results show that the compressive strength of CTB increases with an increase in intermediate principal stress. According to the change process of the acoustic emission ringing count over time, the triaxial compression test can be divided into four stages: the initial active stage, initial calm stage, pre-peak active stage, and post-peak calm stage. When the intermediate principal stress is small, the specimen is dominated by shear failure. With an increase in the intermediate principal stress, the specimen changes from brittle failure to plastic failure. The deformation and failure strength of CTB are closely related to its loading and unloading methods. Under a certain stress intensity, compared with unidirectional unloading, bidirectional unloading produces a greater deformation of the rock mass, and the failure strength of the rock mass is higher. This study only considers the confining pressure within the compressive limit of the specimen. Future research can be directed at a wider range of stresses to improve the applicability and reliability of the research results. Full article

A comprehensive understanding of the mechanical behavior of backfill under compression is crucial for optimizing its design, improving stope stability and enhancing resource recovery. Laboratory testing and numerical simulation were conducted to study the mechanical properties and damage mechanism of cemented tailings backfill (CTB) with different cement-to-tailings (c/t) ratios under uniaxial compression. Laboratory testing was used to investigate the strength and deformation characteristics, macroscopic failure modes, and energy evolution patterns of CTB, while simulation with Particle Flow Code (PFC) was employed to explore the distribution of microcracks and mesoscopic damage mechanisms. A constitutive model accounting for the initial compaction stage was proposed, validated, and applied to practical engineering. The results show that as the c/t ratio decreases, the failure mode of CTB transforms from shear failure to combined tensile–shear failure, and tensile failure. Mesoscopically, a higher c/t ratio leads to more bond contacts, which increases the bearing capacity and consequently causes more cracks to damage CTB. From an energy standpoint, the damage mechanism of CTB is further analyzed and the development of energy is characterized by four stages. Moreover, to explore the failure mechanism of CTB, an innovative constitutive model was proposed and verified through experiments. The matching coefficients, based on the novel constitutive model, indicate that CTB with a c/t ratio of 1:6 is qualified for all current mining depths, and a c/t ratio of 1:10 is sufficient to depths below 300 m. Full article

This study analyzed the influence of the mechanical properties of two-step backfill on the stability of mining sites. The study focused on the one-step adhesive backfill of segmented backfill mining in a mine in Shandong Province, where the front wall was exposed and the back wall was compressed. A three-dimensional mechanical model of the front wall exposed, back wall compressed cemented filling material considering the mechanical properties of the two-step weakly cemented filling material was established through theoretical analysis. On this basis, considering the influence of different mechanical properties (elastic modulus, internal friction angle, cohesion, and Poisson’s ratio) of two-step weakly cemented filling on one-step cemented filling, FLAC 3D 6.00.60 numerical simulation software was used to study the influence of various factors on the horizontal displacement distribution of cemented filling under single-sided exposure conditions using numerical simulation methods. The results show that the adhesive filling material exposed on one side is subjected to lateral pressure from adjacent weak adhesive filling materials, and its stability is affected by the contact area and mechanical properties of the weak adhesive filling material. Increasing the elastic modulus of the two-step weak adhesive filling material from 100 MPa to 500 MPa can reduce the maximum horizontal displacement of the one-step adhesive filling material from 116 mm to 32 mm, a decrease of about 72%. Similarly, increasing the cohesive force from 0.09 MPa to 0.21 MPa can reduce displacement from 96 mm to 33 mm, a decrease of 66%. Improving the mechanical properties of the two-step weakly cemented filling material can reduce the tendency of tailings to slide and collapse, and can reduce the lateral pressure applied by the cemented filling material. The horizontal displacement law of the two-step cemented filling material with front wall exposure and rear wall compression is basically similar under different mechanical properties of the one-step weakly cemented filling material. In the vertical direction, as the height of the filling material increases, the horizontal displacement first slowly increases to the maximum value and then slowly decreases. As the mechanical properties of the two-step weakly cemented filling increase, the horizontal displacement of the one-step cemented filling decreases. Full article

The substantial volumes of tailings produced during ore beneficiation present significant challenges for sustainable management due to potential public health hazards, particularly from metal leaching. The risk associated with tailings varies greatly depending on their mineralogical composition and climatic conditions. If tailings are classified as a non-hazardous by-product, they may serve as secondary raw materials, offering a sustainable alternative to the reliance on non-renewable primary resources. In this study, the recycling feasibility of tailings from an active copper mine was assessed through mineralogical characterization, environmental tests (e.g., static, kinetic, and leaching tests), and geochemical modeling. This multi-faceted approach aimed to predict the geochemical behavior and reactivity of tailings under varying conditions. Results from the static tests indicated that the tailings were non-acid generating. Weathering cell tests revealed circumneutral pH conditions (6.5–7.8), low sulfide oxidation rates, and low instantaneous metal concentrations (<1 mg/L), except for copper (0.6–3.5 mg/L) and iron (0.4–1.4 mg/L). These conditions are attributed to the low abundance of sulfide minerals, such as pyrite, chalcopyrite, bornite, covellite (<0.1 wt.%), and chalcocite (0.2 wt.%), which are effectively encapsulated within gangue minerals. Additionally, the presence of neutralizing minerals, specifically dolomite (27.4 wt.%) and calcite (2.4 wt.%), further stabilizes pH and promotes metal sequestration in secondary mineral forms. The Toxicity Characteristic Leaching Procedure (TCLP) test confirmed low leachability, classifying the tailings as non-hazardous. Full article

This article presents a comprehensive scientometric analysis of mining waste valorization, focusing on tailings utilization in construction materials from 2010 to 2024. Through examination of 1096 Web of Science publications and utilizing CiteSpace mapping and network analyses, we analyze the intellectual structure of this field. Subject category analysis reveals materials science, construction technology, and environmental engineering as the dominant disciplines, interconnected through 168 links across 64 thematic nodes. Our co-citation analysis identifies 12 major research clusters, with materials science and environmental engineering serving as primary disciplinary pillars. Keyword co-occurrence analysis of 532 nodes connected by 1181 links highlights the field’s emphasis on fly ash, concrete applications, and mechanical properties. Recent citation bursts indicate growing research focus on thermal stability, heavy metal treatment, and innovative processing methods. Through synthesizing these scientometric indicators, this review provides strategic insights for advancing sustainable construction practices through mining waste utilization. Research gaps identified include long-term durability assessment, standardization needs, and scalability challenges. By synthesizing these diverse scientometric indicators, this review provides strategic insights for researchers, industry practitioners, and policymakers, contributing to the advancement of sustainable construction practices through mining waste utilization. Full article

Yellow phosphorus slag has been considered as a potential cement substitute for mine filling material due to its cementing activity; however, its slow setting and low early strength have limited broader use. This study investigates the grading, compactness, and strength of yellow phosphorus slag combined with tailing sand. Using yellow phosphorus slag as an aggregate, cement as a binder, and mixing tailing sand in different ratios, this study evaluates its feasibility as a coarse aggregate in mine backfill. The key findings are as follows. (1) The grading index of tailing sand was 0.5, aligning with Fuller grading, but it required mixing with coarse aggregates to enhance strength and reduce cement consumption. Yellow phosphorus slag, with a grading index of 0.97, does not match Fuller’s curve and thus benefits from mixing with tailing sand. (2) For mixtures of waste rock and tailings, the 5:5 ratio aligned closely with Fuller’s theory, showing optimal packing density and strength. Mixtures of yellow phosphorus slag and tailings at ratios of 3:7, 4:6, and 5:5 had R² values of 0.73, 0.80, and 0.85, respectively, confirming reliable fit. The 5:5 mixture provided the best packing density and strength. (3) A new strength prediction model, accounting for aggregate, cement, and water effects, suggests that a 5:5 ratio with a 71% mass concentration and 1/7 ash–sand ratio meets industrial strength requirements. FLAC3D simulations indicated that cemented backfill reduces stress concentrations caused by excavation and supports stability during mining while also absorbing energy through compaction, creating favorable conditions for safe mining operations. Full article