Search Results (7)

In this study, the wear behavior of AA7075/silicon carbide/fly ash hybrid surface composites processed with a clean and green friction stir processing technique was investigated. The microstructure of the composites was investigated to determine the particle dispersion. Wear tests using a pin-on-disc tribometer were conducted, and wear tracks and debris analyses were conducted using scanning electron microscopic imaging, EDX, and mapping. The wear rate of the composites was higher in the case of the composites with agglomerated zones, which led to the loose SiC/fly ash particles pulling out during the action of dry sliding. However, on the other hand, the wear resistance was improved in the composites with uniformly distributed SiC/fly ash particles. The hard SiC/fly ash particles acted as optimized load-bearing asperities and induced more wear resistance during the action of dry sliding against the mating plate, which was made of mild steel. In the case of the well-dispersed composites, the wear mechanisms shifted from fretting fatigue and adhesion to abrasion. The presence of a high Fe content in the wear debris was confirmed in the most wear-resistant composite sample, S-20, which was produced with the following parameters: tool rotation (w) of 1000 rpm, tool traverse (v) of 40 mm/min, hybrid ratio (HR) of 75:25, and a volume percentage of reinforcements (vol.%) of 8. Full article

In industrial applications, welding of dissimilar metals such as aluminum (Al) and titanium (Ti) is a prerequisite for the development of hybrid components with improved mechanical and corrosion properties. However, dissimilar welding of the Al/Ti system is highly challenging due to differences in the physical and thermal properties of the two materials. In the present investigation, an attempt has been made to fabricate a dissimilar friction stir weld (FSW) of commercially pure Al and Ti and to elucidate the mechanism associated with superior joint formation. The process parameters, such as tool rotation speed, traverse speed and tool offset position have been optimized using Taguchi’s optimization technique. A detailed investigation of the weld with optimum process parameters has been carried out to reveal the mechanism of joint formation. The superior mechanical properties (24% higher ultimate tensile strength and 10% higher ductility than that of base Al) of the weld are attributed to the fabrication of a defect-free joint, formation of intercalated particles and an Al/Ti interlocking interface, homogeneous distribution of fine second-phase (Ti and/or intermetallics) particles in the weld nugget, reduction in the evolution of brittle Al₃Ti intermetallic compounds (IMCs) and recrystallization and grain refinement of Al in the weld nugget. The potentio-dynamic polarization test indicated that the optimized Al/Ti weld has ~47% higher corrosion resistance than Al; it had a very mild corrosion attack due to the homogeneous dispersion of fine particles. The method and mechanism could have an immense influence on any dissimilar weld and metal matrix composites, improving their mechanical properties and corrosion resistance. Full article

Good dispersion of nanosilica particles in waterborne polyurethane was obtained by mild mechanical stirring when 0.1–0.5 wt.% nanosilica in aqueous dispersion was added. The addition of small amounts of nanosilica produced more negative Z-potential values, increased the surface tension and decreased the Brookfield viscosity, as well as the extent of shear thinning of the waterborne polyurethane. Depending on the amount of nanosilica, the particle-size distributions of the waterborne polyurethanes changed differently and the addition of only 0.1 wt.% nanosilica noticeably increased the percentage of the particles of 298 nm in diameter. The DSC curves showed two melting peaks at 46 °C and 52 °C, as well as an increase in the melting enthalpy. In addition, when nanosilica was added, the crystallization peak of the waterborne polyurethane was displaced to a higher temperature and showed higher enthalpy. Furthermore, the addition of 0.1–0.5 wt.% nanosilica displaced the temperature of decomposition of the soft domains to higher temperatures due to the intercalation of the particles among the soft segments; this led to a change in the degree of phase separation of the waterborne polyurethanes. As a consequence, improved thermal stability and viscoelastic and mechanical properties of the waterborne polyurethanes were obtained. However, the addition of small amounts of nanosilica was detrimental for the wettability and adhesion of the waterborne polyurethanes due to the existence of acrylic moieties on the nanosilica particles, which seemed to migrate to the interface once the polyurethane was cross-linked. In fact, the final T-peel strength values of the joints made with the waterborne polyurethanes containing nanosilica were significantly lower than the one obtained with the waterborne polyurethane without nanosilica; the higher the nanosilica content, the lower the final adhesion. The better the nanosilica dispersion in the waterborne polyurethane+nanosilica, the higher the final T-peel strength value. Full article

In the current work, mild steel used in shipbuilding applications was friction-stir-welded (FSWed) with the aim of investigating the microstructure and mechanical properties of the FSWed joints. Mild steel of 5 mm thickness was friction-stir-welded at a constant tool rotation rate of 500 rpm and two different welding speeds of 20 mm/min and 50 mm/min and 3° tool tilt angle. The microstructure of the joints was investigated using optical and scanning electron microscopes. Additionally, the grain structure and crystallographic texture of the nugget (NG) zone of the FSWed joints was investigated using electron backscattering diffraction (EBSD). Furthermore, the mechanical properties were investigated using both tensile testing and hardness testing. The microstructure of the low-welding-speed joint was found to consist of fine-grain ferrite and bainite (acicular ferrite) with an average grain size of 3 µm, which indicates that the temperature experienced above A1, where a ferrite and austenite mixture is formed, and upon cooling, the austenite transformed into bainite. The joint produced using high welding speed resulted in a microstructure consisting mainly of polygonal ferrite and pearlite. This could be due to the temperature far below A1 experienced during FSW. In terms of joint efficiency expressed in terms of relative ultimate tensile, the stress of the joint to the base material was found to be around 92% for the low-speed joint and 83% for the high-welding-speed joint. A reduction in welding was attributed to the microstructure, as well as the microtunnel defect formed near the advancing side of the joint. The tensile strain was preserved at 18% for low welding speed and increased to 24% for the high welding speed. This can be attributed to the NG zone microstructural constituents. In terms of crystallographic texture, it is dominated by a simple shear texture, with increased intensity achieved by increasing the welding speed. In both joints, the hardness was found to be significantly increased in the NG zone of the joints, with a greater increase in the case of the low-welding-speed joint. This hardness increase is mainly attributed to the fine-grained structure formed after FSW. Full article

Nanostructured nickel-based catalysts were produced by solution combustion synthesis and it was found that their properties and structure depended on the pretreatment of the precursor solution. X-ray diffraction, N₂ adsorption, and an infrared high-speed camera were used to follow the various synthesis steps and to characterize the obtained catalysts, while their catalytic activity was determined in the hydrogenation of maleic acid. It was determined that the amount of water used and the heating of the precursor solution under mild stirring up to 70 °C influenced the nickel nitrate–glycine–water complexes that were formed in the precursor solution in the form of dendrites. These play a key role in the solution combustion synthesis (SCS) reaction mechanism and in particular in the formation of nickel-based catalysts. Understanding the interrelationships between the processing parameters and the ensuing powder properties allowed an efficient optimization of the catalytic performance. Full article

In the field of energy production, cogeneration systems based on micro gas turbine cycles appear particularly suitable to reach the goals of improving efficiency and reducing pollutants. Moderate and Intense Low-Oxygen Dilution (MILD) combustion represents a promising technology to increase efficiency and to further reduce the emissions of those systems. The present work aims at describing the behavior of a combustion chamber for a micro gas turbine operating in MILD regime. The performances of the combustion chamber are discussed for two cases: methane and biogas combustion. The combustor performed very well in terms of emissions, especially CO and NO ${}_{\mathrm{x}}$ , for various air inlet temperatures and air-to-fuel ratios, proving the benefits of MILD combustion. The chamber proved to be fuel flexible, since both ignition and stable combustion could be achieved by also burning biogas. Finally, the numerical model used to design the combustor was validated against the experimental data collected. The model performs quite well both for methane and biogas. In particular, for methane the Partially Stirred Reactor (PaSR) combustion model proved to be the best choice to predict both minor species, such as CO, more accurately and cases with lower reactivity that were not possible to model using the Eddy Dissipation Concept (EDC). For the biogas, the most appropriate kinetic mechanism to properly model the behavior of the chamber was selected. Full article

Dysregulated iron metabolism is associated with altered body composition and nonalcoholic fatty liver disease (NAFLD); however, mechanisms underlying this association remain undefined. We investigated this association in 117 women. Middle-aged women (≥45 years old (y)) were heavier and had lower serum iron, higher serum hepcidin, ferritin, and severe NAFLD incidence than young adult women (<45 y). Age-adjusted linear regression analysis revealed that young adult women with the highest serum iron:ferritin ratio (Tertile 3) had a 5.08-unit increased percentage of muscle mass [β = 5.08 (1.48–8.68), p < 0.001] and a 1.21-unit decreased percentage visceral fat mass [β = −1.21 (−2.03 to −0.39), p < 0.001] compared with those with the lowest serum iron:ferritin ratio (Tertile 1; reference). The iron:ferritin dietary pattern, characterized by high consumption of beef, lamb, dairy products, fruits, and whole grains, and low consumption of refined carbohydrates (rice, noodles, and bread and pastries), and deep- and stir-fried foods, predicted a 90% [odds ratio: 0.10, 95% confidence interval: 0.02–0.47, p < 0.001] reduced risk of mild vs. moderate and severe NAFLD in young adult women. Our findings suggest that the serum iron:ferritin ratio more accurately predicts body composition and reduced risk of severe fatty liver progression in young adult women compared to middle-aged women. Full article