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Keywords = hyaloclastite

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22 pages, 12371 KiB  
Article
The Fate of “Immobile” Ti in Hyaloclastites: An Evidence from Silica–Iron-Rich Sedimentary Rocks of the Urals Paleozoic Massive Sulfide Deposits
by Nuriya R. Ayupova, Valery V. Maslennikov, Irina Yu. Melekestseva, Dmitry A. Artemyev and Elena V. Belogub
Minerals 2024, 14(9), 939; https://doi.org/10.3390/min14090939 - 13 Sep 2024
Cited by 1 | Viewed by 1300
Abstract
The formation of Paleozoic silica–iron-rich sedimentary rocks in the Urals volcanic-hosted massive sulfide (VHMS) deposits is considered a result of seafloor alteration of hyaloclastites mixed with calcareous/organic or sulfide material. These rocks host various Ti mineral phases pointing to the transformation of precursor [...] Read more.
The formation of Paleozoic silica–iron-rich sedimentary rocks in the Urals volcanic-hosted massive sulfide (VHMS) deposits is considered a result of seafloor alteration of hyaloclastites mixed with calcareous/organic or sulfide material. These rocks host various Ti mineral phases pointing to the transformation of precursor metacolloidal TiO2 phases to disordered anatase during seafloor alteration of hyaloclastites, which was later converted to globules and clusters and further to diagenetic rutile. The LA-ICP-MS analysis showed that the Ti content of hyaloclasts partly replaced by finely dispersed Si–Fe aggregates increases to 540–2950 ppm and decreases (<5 ppm) in full Si–Fe pseudomorphs after hyaloclasts. LA-ICP-MS element mapping reveals the enrichment in V, U, Cr, W, Nb, Pb, and Th of the anatase globules and the local accumulation of Zr, Y, and REE on their periphery. Corrosive biogenic textures in the outer zones of some hyaloclasts and biomorphic aggregates in rocks contain anatase particles in assemblage with apatite indicating the biophilic properties of Ti. This work fills the knowledge gaps about Ti mobilization during low-temperature seafloor alteration of hyaloclastites in VHMS deposits. Full article
(This article belongs to the Special Issue Mineralization and Geochemistry of VMS Deposits)
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32 pages, 11917 KiB  
Article
Miocene Volcanism in the Slovenský Raj Mountains: Magmatic, Space, and Time Relationships in the Western Carpathians
by Rastislav Demko, Marián Putiš, Qiu-Li Li, David Chew, Lukáš Ackerman and Ondrej Nemec
Minerals 2024, 14(1), 9; https://doi.org/10.3390/min14010009 - 19 Dec 2023
Viewed by 2164
Abstract
The Miocene volcanic-intrusive complex in the Slovenský Raj Mountains, middle Slovakia, comprises a swarm of subalkaline basalts and basaltic andesites with alkaline basalts, trachybasalts and basaltic trachyandesites. Basaltic to doleritic feeder dykes and sporadic hyaloclastite lavas are exposed in contact with the Triassic [...] Read more.
The Miocene volcanic-intrusive complex in the Slovenský Raj Mountains, middle Slovakia, comprises a swarm of subalkaline basalts and basaltic andesites with alkaline basalts, trachybasalts and basaltic trachyandesites. Basaltic to doleritic feeder dykes and sporadic hyaloclastite lavas are exposed in contact with the Triassic Bódvaszilas Formation of the Silica Nappe. The primary clinopyroxene, plagioclase, and Fe-Ti oxide assemblage also contains calcite spheroids inferred to represent carbonatitic melt. These spheroids are associated with subsolidus chlorite, actinolite, magnetite, titanite, calcite, and epidote. Micropoikilitic clinopyroxene, albite, and Ti-magnetite formed due to rapid quenching. There was an incorporation of host rock carbonate during the eruption. The erupted products are the result of magmatic differentiation of the parental basaltic tholeiitic magma with a redox of ∆QFM = +1 to +3, affected by varying degrees of 0%–50% fractionation and the assimilation of carbonate material in a shallow magmatic reservoir. REE geochemistry shows N-MORB-like type patterns with both LaN/YbN and LaN/SmN < 1 at near constant Eu/Eu* (~0.9). This is supported by εNd(t=13 Ma) values of +8.0 to +7.4 determined from the basaltic rocks. The REE values can be modeled by 1% fractional melting of garnet peridotite mixed with 7% melting of spinel peridotite of PM composition (1:9 proportions). SIMS and LA-ICP-MS U/Pb analysis of zircons yields a concordant age of 12.69 ± 0.24 Ma and a 13.3 ± 0.16 Ma intercept (Serravallian) age. The Middle Miocene volcanic activity was related to subduction-collision processes along the boundary of the Cenozoic ALCAPA (Alps–Carpathians–Pannonia) microplate and the southern margin of the European plate. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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30 pages, 5423 KiB  
Article
The Secondary Minerals from the Pillow Basalt of Salsette-Mumbai, Deccan Volcanic Province, India
by Berthold Ottens, Ralf Schuster and Zsolt Benkó
Minerals 2022, 12(4), 444; https://doi.org/10.3390/min12040444 - 4 Apr 2022
Cited by 5 | Viewed by 7983
Abstract
Secondary minerals occur within the tholeiitic basalts of Salsette Island in the greater Mumbai region, as well as in other localities in the Deccan Volcanic Province (DVP). However, the secondary minerals of Salsette Island show remarkable differences with respect to their mineral speciation [...] Read more.
Secondary minerals occur within the tholeiitic basalts of Salsette Island in the greater Mumbai region, as well as in other localities in the Deccan Volcanic Province (DVP). However, the secondary minerals of Salsette Island show remarkable differences with respect to their mineral speciation and precipitation sequence, which are both due to their unique geological environment. The greater Mumbai region is built up by the Salsette subgroup, which represents the youngest sequence of the DVP. It formed subsequently to the main phase of DVP activity in Danian time (62.5 to 61.5 Ma), in the course of the India–Laxmi Ridge–Seychelles breakup. The main part of the Salsette subgroup consists of tholeiitic basaltic flows with pillows, pillow breccia, and hyaloclastite, which formed in contact with brackish and fresh water in a lagoonal environment. In some places, intertrappeans are represented by fossiliferous shallow water sediments. On the top, trachytic and rhyolitic subaqueous volcaniclastics occur, and some dioritic bodies have intruded nearby. Due to differing fluid rock interactions, several distinctly different secondary minerals developed in the void spaces of the hyaloclastite breccia of the interpillow matrix and in the pillow cavities. The highly permeable hyaloclastite breccia formed an open system, where pronounced precipitation occurred in the early phase and at higher temperatures. In contrast, the pillow cavities were a temporally closed system and contained, for example, more low-temperature zeolites. The genesis of the secondary minerals can be summarized as follows: During initial cooling of the volcanic rocks at about 62 Ma, the first mineralization sequence developed with chlorite, laumontite I, quartz, and calcite I. Ongoing magmatic activity caused reheating and the main phase of precipitation at prehnite–pumpellyite facies conditions. During generally decreasing temperatures, in the range of 270–180 °C, babingtonite, laumontite II, prehnite, julgoldite, yugawaralite, calcite II, ilvaite, pumpellyite, and gryolite developed. The fluid contained SiO2 + Al2O3 + FeO + MgO + CaO, and minor MnO and Na2O, and was predominately mineralized by the decomposition of basaltic glass. Further temperature decreases caused zeolite facies conditions and precipitation of okenite I, scolecite, heulandite, stilbite, and finally chabazite I, in the temperature range of 180 °C to less than 100 °C. As FeO, MgO, and MnO were then absent, an interaction of the fluid with plagioclase is indicated. According to Rb-Sr and K-Ar ages on apophyllite-K, a third phase of precipitation with apophyllite-K, okenite II, and chabazite II occurred in the late Eocene to early Oligocene (30–40 Ma). The new hydrothermal fluid additionally contained K2O, and temperatures of 50–100 °C can be expected. Full article
(This article belongs to the Special Issue Zeolites: Occurrence, Properties, and Utilization)
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35 pages, 12276 KiB  
Article
Lithogeochemical and Hyperspectral Halos to Ag-Zn-Au Mineralization at Nimbus in the Eastern Goldfields Superterrane, Western Australia
by Steven P. Hollis, Sabri Foury, Stefano Caruso, Sean Johnson, Vitor Barrote and Andrew Pumphrey
Minerals 2021, 11(3), 254; https://doi.org/10.3390/min11030254 - 28 Feb 2021
Cited by 6 | Viewed by 4729
Abstract
With new advances in rapid-acquisition geochemical and hyperspectral techniques, exploration companies are now able to detect subtle halos surrounding orebodies at minimal expense. The Nimbus Ag-Zn-(Au) deposit is unique in the Archean Yilgarn Craton of Western Australia. Due to its mineralogy, alteration assemblages, [...] Read more.
With new advances in rapid-acquisition geochemical and hyperspectral techniques, exploration companies are now able to detect subtle halos surrounding orebodies at minimal expense. The Nimbus Ag-Zn-(Au) deposit is unique in the Archean Yilgarn Craton of Western Australia. Due to its mineralogy, alteration assemblages, geochemical affinity, and tectonic setting, it is interpreted to represent a shallow water (~650 mbsl) and low-temperature (<250 °C) volcanogenic massive sulfide (VMS) deposit with epithermal characteristics (i.e., a hybrid bimodal felsic deposit). We present a detailed paragenetic account of the Nimbus deposit, and establish lithogeochemical and hyperspectral halos to mineralization to aid exploration. Mineralization at Nimbus is characterized by early units of barren massive pyrite that replace glassy dacitic lavas, and underlying zones of polymetallic sulfides that replace autoclastic monomict dacite breccias. The latter are dominated by pyrite-sphalerite-galena, a diverse suite of Ag-Sb ± Pb ± As ± (Cu)-bearing sulfosalts, minor pyrrhotite, arsenopyrite, and rare chalcopyrite. The main sulfosalt suite is characterized by pyrargyrite, and Ag-rich varieties of boulangerite, tetrahedrite, and bournonite. Zones of sulfide mineralization in quartz-sericite(±carbonate)-altered dacite are marked by significant mass gains in Fe, S, Zn, Pb, Sb, Ag, As, Cd, Ni, Cu, Ba, Co, Cr, Tl, Bi, and Au. Basaltic rocks show reduced mass gains in most elements, with zones of intense quartz-chlorite-carbonate±fuchsite alteration restricted to thick sequences of hyaloclastite, and near contacts with dacitic rocks. Broad zones of intense silica-sericite alteration surround mineralization in dacite, and are marked by high Alteration Index and Chlorite-Carbonate-Pyrite Index (CCPI) values, strong Na-Ca depletion, and an absence of feldspar (albite) in thermal infrared (TIR) data. White mica compositions are predominantly muscovitic in weakly altered sections of the dacitic footwall sequence. More paragonitic compositions are associated with zones of increased sericitization and high-grade polymetallic sulfide mineralization. Chlorite in dacitic rocks often occurs adjacent to zones of sulfide mineralization and is restricted to narrow intervals. Carbonate abundance is sporadic in dacite, but is most abundant outside the main zones of Na-Ca depletion. Basaltic rocks are characterized by strongly paragonitic white mica compositions, and abundant chlorite and carbonate. Shifts from Ca carbonates and Fe-rich chlorites to more Mg-rich compositions of both minerals occur in more intensely hydrothermally altered basaltic hyaloclastite, and near contacts with dacitic rocks. Hanging-wall polymict conglomerates are characterized by minor amounts of muscovitic to phengitic white mica (2205–2220 nm), and an absence of chlorite and carbonate alteration. Full article
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23 pages, 5251 KiB  
Article
Late Pleistocene Boulder Slumps Eroded from a Basalt Shoreline at El Confital Beach on Gran Canaria (Canary Islands, Spain)
by Inés Galindo, Markes E. Johnson, Esther Martín-González, Carmen Romero, Juana Vegas, Carlos S. Melo, Sérgio P. Ávila and Nieves Sánchez
J. Mar. Sci. Eng. 2021, 9(2), 138; https://doi.org/10.3390/jmse9020138 - 29 Jan 2021
Cited by 5 | Viewed by 3457
Abstract
This study examines the role of North Atlantic storms degrading a Late Pleistocene rocky shoreline formed by basaltic rocks overlying hyaloclastite rocks on a small volcanic peninsula connected to Gran Canaria in the central region of the Canary Archipelago. A conglomerate dominated by [...] Read more.
This study examines the role of North Atlantic storms degrading a Late Pleistocene rocky shoreline formed by basaltic rocks overlying hyaloclastite rocks on a small volcanic peninsula connected to Gran Canaria in the central region of the Canary Archipelago. A conglomerate dominated by large, ellipsoidal to angular boulders eroded from an adjacent basalt flow was canvassed at six stations distributed along 800 m of the modern shore at El Confital, on the outskirts of Las Palmas de Gran Canaria. A total of 166 individual basalt cobbles and boulders were systematically measured in three dimensions, providing the database for analyses of variations in clast shape and size. The goal of this study was to apply mathematical equations elaborated after Nott (2003) and subsequent refinements in order to estimate individual wave heights necessary to lift basalt blocks from the layered and joint-bound sea cliffs at El Confital. On average, wave heights in the order of 4.2 to 4.5 m are calculated as having impacted the Late Pleistocene rocky coastline at El Confital, although the largest boulders in excess of 2 m in diameter would have required larger waves for extraction. A review of the fossil marine biota associated with the boulder beds confirms a littoral to very shallow water setting correlated in time with Marine Isotope Stage 5e (Eemian Stage) approximately 125,000 years ago. The historical record of major storms in the regions of the Canary and Azorean islands indicates that events of hurricane strength were likely to have struck El Confital in earlier times. Due to its high scientific value, the outcrop area featured in this study is included in the Spanish Inventory of Geosites and must be properly protected and managed to ensure conservation against the impact of climate change foreseen in coming years. Full article
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24 pages, 10071 KiB  
Article
Reconstruction of Late Pleistocene-Holocene Deformation through Massive Data Collection at Krafla Rift (NE Iceland) Owing to Drone-Based Structure-from-Motion Photogrammetry
by Fabio Luca Bonali, Alessandro Tibaldi, Noemi Corti, Luca Fallati and Elena Russo
Appl. Sci. 2020, 10(19), 6759; https://doi.org/10.3390/app10196759 - 27 Sep 2020
Cited by 9 | Viewed by 3625
Abstract
In the present work, we demonstrate how drone surveys coupled with structure-from-motion (SfM) photogrammetry can help to collect huge amounts of very detailed data even in rough terrains where logistics can affect classical field surveys. The area of study is located in the [...] Read more.
In the present work, we demonstrate how drone surveys coupled with structure-from-motion (SfM) photogrammetry can help to collect huge amounts of very detailed data even in rough terrains where logistics can affect classical field surveys. The area of study is located in the NW part of the Krafla Fissure Swarm (NE Iceland), a volcanotectonic rift composed of eruptive centres, extension fractures, and normal faults. The surveyed sector is characterized by the presence of a hyaloclastite ridge composed of deposits dated, on a stratigraphic basis, to the Weichselian High Glacial (29.1–12.1 ka BP), and a series of lava flows mostly dating back to 11–12 ka BP. The integration of remotely sensed surveys and field inspections enabled us to recognize that this segment of the Krafla rift is made of grabens arranged en-échelon with a left-stepping geometry. A major graben increases in width in correspondence of the hyaloclastite cone; we interpret this geometry as resulting from the mechanical contrast between the stiffer lava succession and the softer hyaloclastites, which favours the development of concentric faults. We also measured a total extension of 16.6 m and 11.2 m along the fractures affecting the lava units, and a total extension in the hyaloclastites of 29.3 m. This produces an extension rate of 1.4 mm/yr in the Holocene lavas and 1.7 ± 0.7 mm/yr in the Weichselian hyaloclastite deposits. The spreading direction we obtained for this area is N97.7° E, resulting from the av. of 568 opening direction values. Full article
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29 pages, 38822 KiB  
Article
Authigenesis at the Urals Massive Sulfide Deposits: Insight from Pyrite Nodules Hosted in Ore Diagenites
by Nataliya P. Safina, Irina Yu. Melekestseva, Nuriya R. Ayupova, Valeriy V. Maslennikov, Svetlana P. Maslennikova, Dmitry A. Artemyev and Ivan A. Blinov
Minerals 2020, 10(2), 193; https://doi.org/10.3390/min10020193 - 20 Feb 2020
Cited by 9 | Viewed by 3977
Abstract
The pyrite nodules from ore diagenites of the Urals massive sulfide deposits associated with various background sedimentary rocks are studied using optical and electron microscopy and LA-ICP-MS analysis. The nodules are found in sulfide–black shale, sulfide–carbonate–hyaloclastite, and sulfide–serpentinite diagenites of the Saf’yanovskoe, Talgan, [...] Read more.
The pyrite nodules from ore diagenites of the Urals massive sulfide deposits associated with various background sedimentary rocks are studied using optical and electron microscopy and LA-ICP-MS analysis. The nodules are found in sulfide–black shale, sulfide–carbonate–hyaloclastite, and sulfide–serpentinite diagenites of the Saf’yanovskoe, Talgan, and Dergamysh deposits, respectively. The nodules consist of the core made up of early diagenetic fine-crystalline (grained) pyrite and the rim (±intermediate zone) composed of late diagenetic coarse-crystalline pyrite. The nodules are replaced by authigenic sphalerite, chalcopyrite, galena, and fahlores (Saf’yanovskoe), sphalerite, chalcopyrite and galena (Talgan), and pyrrhotite and chalcopyrite (Dergamysh). They exhibit specific accessory mineral assemblages with dominant galena and fahlores, various tellurides and Co–Ni sulfoarsenides in sulfide-black shale, sulfide–hyaloclastite–carbonate, and sulfide-serpentinite diagenites, respectively. The core of nodules is enriched in trace elements in contrast to the rim. The nodules from sulfide–black shale diagenites are enriched in most trace elements due to their effective sorption by associated organic-rich sediments. The nodules from sulfide–carbonate–hyaloclastite diagenites are rich in elements sourced from seawater, hyaloclastites and copper–zinc ore clasts. The nodules from sulfide–serpentinite diagenites are rich in Co and Ni, which are typical trace elements of ultramafic rocks and primary ores from the deposit. Full article
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20 pages, 6217 KiB  
Article
Rhyolite Domes and Subsequent Offlap of Pliocene Carbonates on Volcanic Islets at San Basilio (Baja California Sur, Mexico)
by Markes E. Johnson, David H. Backus, Ana Luisa Carreño and Jorge Ledesma-Vázquez
Geosciences 2019, 9(2), 87; https://doi.org/10.3390/geosciences9020087 - 14 Feb 2019
Cited by 2 | Viewed by 4976
Abstract
San Basilio basin in Baja California Sur (Mexico) exhibits distinct styles of volcanism that interrupted phases of normal sedimentation correlated with the Zanclean Stage (Lower Pliocene). Sea cliffs around a 4-km2 bay opening onto the Gulf of California are dominated by rhyolite, [...] Read more.
San Basilio basin in Baja California Sur (Mexico) exhibits distinct styles of volcanism that interrupted phases of normal sedimentation correlated with the Zanclean Stage (Lower Pliocene). Sea cliffs around a 4-km2 bay opening onto the Gulf of California are dominated by rhyolite, mudstone, sandstone, and limestone. Volcanism associated with re-sedimented hyaloclastite is regionally uncommon and the goal was to investigate interactions between volcanic events and intervals of stability represented by fossil-rich strata. Methods of study involved a combination of microfossil and macrofossil analyses. Relating the basin’s faults to Pliocene development in the greater Gulf of California was a secondary goal. Microfossils Bolivina bicostata and B. interjuncta recovered from mudstone indicate an initial water column of 150 m. An abrupt hydromagmatic explosion ruptured the mudstone cover, followed by banded rhyolite flows inter-bedded with sandstone. Outlying limestone beds with the index fossil Clypeaster bowersi are separated from rhyolite by conglomerate eroded under intertidal conditions. A renewed phase of activity saw eruption of smaller volcanoes in the basin center semi-contemporaneous with pecten limestone deposited on unstable slopes. Normal faults conform to a pattern of extensional rifting in the proto-gulf, followed by cross-cutting faults indicating the onset of transtensional tectonics beginning about 3.5 Ma. Full article
(This article belongs to the Section Biogeosciences)
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