Search Results (5)

This study focuses on investigating the strength recovery of fire-damaged fly ash concrete (FAC) with a low substitution rate of 10% through post-fire curing. The chemical and microstructural changes were analyzed using X-ray diffraction (XRD), derivative thermogravimetry (DTG), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), and nitrogen adsorption. The findings indicate that the incorporation of fly ash slightly enhanced the strength after exposure to 400 °C; this was attributed to improved pozzolanic reactions, which were not observed at higher temperatures of 600 °C and 800 °C. Moreover, a positive effect on the recovery of compressive strength was observed due to the pozzolanic reaction. However, due to the relatively low fly ash content, depletion occurred at a later age, resulting in the inability to inhibit microstructural damage caused by the production of portlandite, thereby weakening the compressive strength. Interestingly, fly ash influenced the morphology of calcium carbonate and calcium silicate hydrate crystals, which is potentially ascribed to the role of high aluminum content acting as a crystallization-guiding agent. Full article

A cellular concrete with a fine porous structure was experimentally made using the corrosion technique for aluminum powder as an expanding agent in an aqueous solution of Ca(OH)₂. The originality of this paper was the use of our own production method for the fine aluminum powder through atomizing the recycled molten waste of this metal using concentrated jets of nitrogen. Additionally, the waste melting technique involved our own microwave heating method. A high weight proportion of calcined gypsum (maximum 82.3%) represented the main concrete binder. Using moderate contents of coal fly ash (3.6–11.1%) together with perlite (4.6–6.4%) to reduce the pore size and silica fume (0.3–1.2%) with pozzolanic properties, the aim was to obtain a macrostructure characterized by a very low pore size and to increase the compressive strength (by up to 4.1 MPa), despite the relatively low density (below 641 kg/m³). An industrial method of increasing the mechanical strength by steam curing fresh concrete was applied. Full article

The secondary aluminum ash is the black slag left after the primary aluminum ash is extracted from the metal aluminum. To address the environmental pollution and resource waste caused by the accumulation and landfill of aluminum ash, this study fabricated non-fired bricks by using secondary aluminum ash as the principal raw material, which was supplemented by cement, slaked lime, gypsum and engineering sand. The effects of mix proportions of various admixtures on the mechanical properties of non-fired bricks were investigated, and on this basis, the hydration mechanism was analyzed. The results showed that the mix proportions were 68.3% aluminum ash, 11.4% cement, 6.4% slaked lime, 4.2% gypsum and 9.7% engineering sand. The compressive strength of the fabricated bricks reached 22.19 MPa, and their quality indicators were in line with the MU20 requirements for Non-fired Rubbish Gangue Bricks. Evident hydration reaction occurred inside the non-fired bricks, with main products being calcium silicate hydrate (CSH), calcium aluminate hydrate (CAH) and ettringite (AFt). Besides, a dense structure was formed, which enhanced the brick strength. Full article

Small-scale wood pellet producers often use a trial-and-error approach for determining adequate blending of available wood processing residues and pelletizing parameters. Developing general guidelines for optimizing wood pellet quality and meeting market standards would facilitate their market entry and profitability. Four types of hardwood residues, including green wood chips, dry shavings, and solid and engineered wood sawdust, were investigated to determine the optimum blends of feedstocks and pelletizing conditions to produce pellets with low friction force, high density and high mechanical strength. The feedstock properties reported in this study included particle size distribution, wood moisture content, bulk density, ash content, calorific values, hemicelluloses, lignin, cellulose, extractives, ash major and minor elements, and carbon, nitrogen, and sulfur. All residues tested could potentially be used for wood pellet production. However, high concentrations of metals, such as aluminum, could restrict their use for accessing markets for high-quality pellets. Feedstock moisture content and composition (controlled by the proportions of the various residue sources within blends) were the most important parameters that determined pellet quality, with pelletizing process parameters having less overall influence. Residue blends with a moisture content of 9%–13.5% (dry basis), composed of 25%–50% of sawdust generated by sawing of wood pieces and a portion of green chips generated by trimming of green wood, when combined with a compressive force of 2000 N or more during pelletizing, provided optimum results in terms of minimizing friction and increasing pellet density and mechanical strength. Developing formal relationships between the type of process that generates residues, the properties of residues hence generated, and the quality of wood pellets can contribute to optimize pellet production methods. Full article

Agricultural producers are interested in using biomass available on farms to substitute fossil fuels for heat production. However, energy crops like reed canary grass contain high nitrogen (N), sulfur (S), potassium (K) and other ash-forming elements which lead to increased emissions of gases and particulate matter (PM) and ash-related operational problems (e.g., melting) during combustion. To address these problematic behaviors, reed canary grass was blended with wood (50 wt%) and fuel additives (3 wt%) such as aluminum silicates (sewage sludge), calcium (limestone) and sulfur (lignosulfonate) based additives. When burned in a top-feed pellet boiler (29 kW), the four blends resulted in a 17%–29% decrease of PM concentrations compared to pure reed canary grass probably because of a reduction of K release to flue gas. Nitrogen oxides (NO_x) and sulfur dioxide (SO₂) emissions varied according to fuel N and S contents. This explains the lower NO_x and SO₂ levels obtained with wood based products and the higher SO₂ generation with the grass/lignosulfonate blend. The proportion of clinkers found in combustion ash was greatly lessened (27%–98%) with the use of additives, except for lignosulfonate. The positive effects of some additives may allow agricultural fuels to become viable alternatives. Full article