Search Results (6)

In the aerospace industry, low-density quartz fiber/phenolic resin composites offer advantages such as low cost, low density, high thermal insulation, and excellent thermal resistance, making them a promising candidate when exposed to a long-term low–medium heat flow environment. However, there is currently a lack of understanding regarding the ablation evolution and mechanisms of these materials under this environment, which hampers the enhancement of material performance. Additionally, there is insufficient quantification of their pyrolysis processes, which is detrimental to the development of subsequent mathematical models for ablation thermal response. Therefore, this work focuses on the study of the ablation process of low-density needled quartz felt/phenolic resin (PR/NQF) under long-term low–medium heat flow. Ablation samples of PR/NQF with varying densities were obtained by treating them with a quartz lamp at different temperatures. The differences in the carbonization of the PR/NQF ablation surface were analyzed through SEM, microCT, FTIR, XRD, and XPS experiments, revealing the influence of ablation temperature and composite density. Subsequently, the pyrolysis mechanism of PR/NQF was analyzed using Py-GC-MS, resulting in insights into the evolution and component ratio of pyrolysis gases and their temperature correlations. To further describe the pyrolysis process of low-density PR/NQF, a pyrolysis kinetics model was developed based on the TGA experimental results, and the consistency between the fitted results and theoretical values was validated. The conclusions of this study provide support for analyzing the ablation mechanisms and evolution processes of low-density PR/NQF under long-term low–medium heat flow. Furthermore, the conclusions offered a certain degree of basic data support of mathematical models for ablation processes and the development of new thermal protection materials. Full article

This research used end-of-use cotton apparel to develop mulch mats, a type of agrotextiles. The researchers collected and sorted end-of-use garments to obtain cotton textile waste. These end-of-use garments were deconstructed to obtain shredded textiles and big pieces of textiles. Using the textiles from deconstructed end-of-use garments, together with a small amount of new cotton fibers, the researchers used a Feltloom to develop needle-punched nonwoven fabrics that can be used as mulch mats. The researchers tested textile properties of these mulch mats and conducted agricultural field tests for weed control and pot tests for biodegradation. The researchers also tested the mulch mats’ soil moisture infiltration, and impact on water evaporation. The nonwoven mulch mats made from end-of-use garments have excellent weed inhibition capability and biodegradability. Compared to plastic mulch sheet, the nonwoven mulch mats are better for water utilization in rainfall watering and sprinkle irrigation but poorer in water conservation in drip irrigation. Considering durability, biodegradability, and soil temperature regulation, it is recommended to use 100% cotton and felt four times to produce mulch mats from end-of-use garments. Full article

Lightweight and high-strength insulation materials have important application prospects in the aerospace, metallurgical, and nuclear industries. In this study, a highly porous silica fiber reinforced phenolic resin matrix composite was prepared by vacuum impregnation and atmospheric drying using quartz fiber needled felt as reinforcement and anhydrous ethanol as a pore-making agent. The effects of curing agent content on the structure, composition, density, and thermal conductivity of the composite were studied. The mechanical properties of the composite in the xy direction and z direction were analyzed. The results showed that this process can also produce porous phenolic resin (PR) with a density as low as 0.291 g/cm³, where spherical phenolic resin particles are interconnected to form a porous network structure with a particle size of about 5.43 μm. The fiber-reinforced porous PR had low density (0.372~0.397 g/cm³) and low thermal conductivity (0.085~0.095 W/m·K). The spherical phenolic resin particles inside the composite were well combined with the fiber at the interface and uniformly distributed in the fiber lap network. The composite possessed enhanced mechanical properties with compressive strength of 3.5–5.1 MPa in the xy direction and appeared as gradual compaction rather than destruction as the strain reached 30% in the z direction. This research provides a lightweight and high-strength insulation material with a simple preparation process and excellent performance. Full article

In this work, a novel P/N flame-retardant monomer (PDHAA) was synthesized through reacting phenyl dichlorophosphate (PDCP) with N-hydroxyethyl acrylamide (HEAA). The structure of PDHAA was confirmed using Fourier transform infrared (FTIR) spectroscopy and proton nuclear magnetic resonance (NMR) spectroscopy. PDHAA monomer and 2-hydroxyethyl methacrylate phosphate (PM-2) monomer were mixed at different mass ratios, to prepare UV-curable coatings, and then applied to the surface of fiber needled felts (FNFs), to improve their flame retardancy. PM-2 was introduced to reduce the curing time of the flame-retardant coatings and improve the adhesion between the coating and the fiber needled felts (FNFs). The research results indicated that the surface flame-retardant FNFs had a high limiting oxygen index (LOI) and rapidly self-extinguished in a horizontal combustion test and passed a UL-94 V-0 test. At the same time, the CO and CO₂ emissions were greatly reduced, and the carbon residue rate was increased. In addition, the introduction of the coating improved the mechanical properties of the FNFs. Therefore, this simple and efficient UV-curable surface flame-retardant strategy has broad application prospects in the field of fire protection. Full article

In this study, the safe critical temperature that can be tolerated by CFRP tendons under normal working conditions was derived through tensile tests at room and high temperatures. Next, the times required to reach a safe critical temperature for CFRP cables protected with different types of fire-retardant materials of various thicknesses were determined through fire resistance tests, Finally, fitting the surface of the finite element simulation results allowed the establishment of the temperature rise calculation model of CFRP tendons under the protection of fire-retardant materials. The results showed that 300 °C can be regarded as the safe critical temperature. Both high-silica needled felt and ceramic fiber felt exhibited high fireproof performance. With an increase in the thickness of the fire-retardant material, the time for the CFRP tendon to reach the inflection point of the heating rate increased, and the safe fire resistance time increased exponentially. According to the HC temperature rise curve, the fire resistance time of CFRP tendons protected by 24 mm thick high-silica needled felt was 45 min, and that for CFRP tendons protected by 24 mm thick ceramic fiber felt was 39.5 min. Under the action of fire corresponding to the hydrocarbon temperature rise model, the safe fire resistance time of CFRP tendons protected by 45 mm high-silica needled felt or 50 mm ceramic fiber felt was more than 2 h, sufficient to meet the specification. The proposed model of fire resistance performance enables the determination of the thickness of the fire resistance material required to obtain different degrees of fire resistance for CFRP cables for structural use. Full article

The heat generated by a high-power device will seriously affect the operating efficiency and service life of electronic devices, which greatly limits the development of the microelectronic industry. Carbon fiber (CF) materials with excellent thermal conductivity have been favored by scientific researchers. In this paper, CF/carbon felt (CF/C felt) was fabricated by CF and phenolic resin using the “airflow network method”, “needle-punching method” and “graphitization process method”. Then, the CF/C/Epoxy composites (CF/C/EP) were prepared by the CF/C felt and epoxy resin using the “liquid phase impregnation method” and “compression molding method”. The results show that the CF/C felt has a 3D network structure, which is very conducive to improving the thermal conductivity of the CF/C/EP composite. The thermal conductivity of the CF/C/EP composite reaches 3.39 W/mK with 31.2 wt% CF/C, which is about 17 times of that of pure epoxy. Full article