Search Results (3)

This study examines the environmental challenges posed by azo-dye pollutants and aluminum industrial waste. Aluminum oxide nanoparticles (P/Al₂O₃-NPs) were produced using a green method that utilized pharmaceutical packaging waste as an aluminum source and marine algae extract (Padina pavonica) as reducing and stabilizing agents and that was characterized by XRD, EDX, SEM, TEM, and zeta potential. Batch biosorption studies were performed to assess the effectiveness of P/Al₂O₃-NPs in removing CR dye from aqueous solutions. The results demonstrate that the particle sizes range from 58.63 to 86.70 nm and morphologies vary from spherical to elliptical. FTIR analysis revealed Al–O lattice vibrations at 988 and 570 cm⁻¹. The nanoparticles displayed a negative surface charge (−13 mV) and a pH_zpc of 4.8. Adsorption experiments optimized parameters for CR dye removal, achieving 97.81% efficiency under native pH (6.95), with a dye concentration of 30 mg/L, an adsorbent dosage of 0.1 g/L, and a contact time of 30 min. Thermodynamic studies confirmed that the process is exothermic and spontaneous. Kinetic data fit well with the pseudo-second-order model, while equilibrium data aligned with the Langmuir isotherm. The adsorption mechanism involved van der Waals forces, hydrogen bonding, and π–π interactions, as supported by the influence of pH, isotherm data, and FTIR spectra. Overall, the study demonstrates the potential of eco-friendly P/Al₂O₃-NPs to efficiently remove CR dye from aqueous solutions. Full article

Articulated slab bridges have been widely used by transportation administration for short-to-medium span bridges because of their good economy, convenient construction, and environmental advantages, while the presence of shear keys increases the complexity of structural behavior. Developing more reasonable analysis approaches of quick assessment, pre-design, and hand calculations for the articulated slab bridges is a challenge because of the peculiar shear key mechanism. This paper is devoted to presenting a recursive algorithm, based on the force equilibrium conditions of each individual slab, thus resulting in simultaneous equations of the transfer matrix method (TMM). In this procedure, the state vector is an array composed of vertical displacement, shear force, unit constant; and the transfer matrix contains the bending and torsional stiffness parameters of simply supported slabs. Then, the influence line of transverse load distribution (TLD) is calculated for each slab by introducing boundary conditions. To validate and verify the efficiency of the TMM algorithm, a transversely prefabricated void slab bridge with a span of 20 m is considered as a case study. The traditional force (FM) and finite element (FEM) methods are used for comparison and validation. It is demonstrated that the TMM can provide good results with higher algorithm efficiency by exempting the modeling tasks in FM and FEM and capture variations in TLD along the bridge’s span. In addition, the influence of the span length and relative stiffness coefficient of slabs on the TLD of articulated slab bridges are analyzed from the parametric analysis. Full article

The morphological change of a headland bay beach—Tenby, West Wales, UK—was analysed over a 73-year period (1941–2014). Geo-referenced aerial photographs were used to extract shoreline positions which were subsequently compared with wave models based on storm event data. From the 1941 baseline, results showed shoreline change rates reduced over time with regression models enabling a prediction of shoreline equilibrium circa 2061. Further temporal analyses showed southern and central sector erosion and northern accretion, while models identified long-term plan-form rotation, i.e., a negative phase relationship between beach extremities and a change from negative to positive correlation within the more stable central sector. Models were then used in conjunction with an empirical 2nd order polynomial equation to predict the 2061 longshore equilibrium shoreline position under current environmental conditions. Results agreed with previous regional research which showed that dominant south and southwesterly wave regimes influence south to north longshore drift with counter drift generated by less dominant easterly regimes. The equilibrium shoreline was also used to underpin flood and inundation assessments, identifying areas at risk and strategies to increase resilience. UK shoreline management plans evaluate coastal vulnerability based upon temporal epochs of 20, 50 and 100 years. Therefore, this research evaluating datasets spanning 73 years has demonstrated the effectiveness of linear regression in integrating temporal and spatial consequences of sea level rise and storms. The developed models can be used to predict future shoreline positions aligned with shoreline management plan epochs and inform embayed beach shoreline assessments at local, regional and international scales, by identifying locations of vulnerability and enabling the development of management strategies to improve resilience under scenarios of sea level rise and climate change. Full article