Search Results (5)

Electrochemical-based processes have shown great promise in removing organic pollutants such as non-steroidal anti-inflammatory drugs (NSAIDs) from wastewater due to their effectiveness in addressing environmental pollution. This study conducts a bibliometric analysis of the most-cited articles in the field to systematically evaluate the progress and current state of electrochemical methods for NSAID removal from wastewater. Additionally, it highlights the potential of combining electrochemical techniques with other treatment methods to enhance the overall efficiency of NSAID removal. Research in this field has mainly focused on three technologies: electro-peroxone process (E-peroxone), electro-Fenton (EF), and electrochemical oxidation (EO). Early studies prioritized EO-based treatments, but interest has gradually shifted toward EF and E-peroxone. Future research is expected to focus on the development of cost-effective electrode materials, improving energy efficiency, and exploring hybrid systems for more effective treatment of wastewater contaminated with NSAIDs. An integrated bibliometric and systematic review framework presented in this study provides the first comprehensive assessment of electrochemical strategies for NSAIDs removal, highlighting the evolution of research focus and the potential of hybrid approaches. Full article

The treatment of medical wastewater by the peroxone (AOP) and electro-peroxone (E-peroxone) processes was analyzed. The E-peroxone process is based on the production of hydrogen peroxide electrochemically from an O₂ and O₃ gas mixture produced in sparged ozone generator effluent using graphite-polytetrafluorethylene cathodes. The electrogenerated H₂O₂ reacts with sparged ozone to produce hydroxyl radicals. All advanced oxidation processes presented in this study effectively removed chemical oxygen demand (COD) by up to 87%. The use of E-peroxone showed 15% better results in COD reduction than conventional peroxone. The research suggests that E-peroxone is more sufficient at removing pollutants in wastewater than peroxone. Hence, E-peroxone was found to be more cost-effective than AOP in this case. Full article

A novel material of self-shaped ZnO-embedded biomass carbon foam pellets (ZnO@BCFPs) was successfully synthesized and used as fluidized particle electrodes in three-dimensional (3D) electro-peroxone systems for metronidazole degradation. Compared with 3D and 2D + O₃ systems, the energy consumption was greatly reduced and the removal efficiencies of metronidazole were improved in the 3D + O₃ system. The degradation rate constants increased from 0.0369 min⁻¹ and 0.0337 min⁻¹ to 0.0553 min⁻¹, respectively. The removal efficiencies of metronidazole and total organic carbon reached 100% and 50.5% within 60 min under optimal conditions. It indicated that adding ZnO@BCFPs particle electrodes was beneficial to simultaneous adsorption and degradation of metronidazole due to improving mass transfer of metronidazole and forming numerous tiny electrolytic cells. In addition, the process of metronidazole degradation in 3D electro-peroxone systems involved hydroxyethyl cleavage, hydroxylation, nitro-reduction, N-denitrification and ring-opening. The active species of ·OH and ·O₂⁻ played an important role. Furthermore, the acute toxicity LD₅₀ and the bioconcentration factor of intermediate products decreased with the increasing reaction time. Full article

The presence of emerging contaminant para-aminobenzoic acid (PABA) in the aquatic environment or drinking water has the potential to harm the aquatic ecosystem and human health. In this work, the removal of aqueous PABA by a compartmental electro-peroxone (E-peroxone) process was systematically investigated from the kinetic and mechanism viewpoints. The results suggest that single electrolysis or ozonation was inefficient in PABA elimination, and the combined E-peroxone yielded synergistic target pollutant degradation. Compared to the conventional E-peroxone oxidation, the sequential cathodic reactions, followed by anodic oxidations, improved the PABA removal efficiency from ~63.6% to ~89.5% at a 10-min treatment, and the corresponding pseudo first-order kinetic reaction rate constant increased from ~1.6 × 10⁻³ to ~3.6 × 10⁻³ s⁻¹. Moreover, the response surface methodology (RSM) analysis indicated that the appropriate increase of inlet ozone concentration, applied current density, initial solution pH value, and solution temperature could accelerate the PABA degradation, while the excess of these operational parameters would have a negative effect on the treatment efficiency. The comparation tests revealed that the coupling of electrolysis and ozonation could synergistically produce hydroxyl radicals (HO•) and the separation of cathodic reactions and anodic oxidations further promoted the HO• generation, which was responsible for the enhancement of PABA elimination in the compartmental E-peroxone process. These observations imply that the compartmental E-peroxone process has the potential for aqueous micropollutants elimination, and the reaction conditions that favor the reactive oxygen species generation are critical for the treatment efficiency. Full article

The electro-peroxone (E-peroxone) process is an emerging electrocatalytic ozonation process that is enabled by in situ producing hydrogen peroxide (H₂O₂) from cathodic oxygen reduction during ozonation. The in situ-generated H₂O₂ can then promote ozone (O₃) transformation to hydroxyl radicals (•OH), and thus enhance the abatement of ozone-refractory pollutants compared to conventional ozonation. In this study, a chemical kinetic model was employed to simulate micropollutant abatement during the E-peroxone treatment of various water matrices (surface water, secondary wastewater effluent, and groundwater). Results show that by following the O₃ and •OH exposures during the E-peroxone process, the abatement kinetics of a variety of model micropollutants could be well predicted using the model. In addition, the effect of specific ozone doses on micropollutant abatement efficiencies could be quantitatively evaluated using the model. Therefore, the chemical kinetic model can be used to reveal important information for the design and optimization of the treatment time and ozone doses of the E-peroxone process for cost-effective micropollutant abatement in water and wastewater treatment. Full article