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Keywords = demolding deformation

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13 pages, 12964 KiB  
Article
A Soft Variable Stiffness Actuator with a Chain Mail Structure as a Particle Jamming Interface
by John E. Bermeo, Eduardo Castillo-Castañeda and Med Amine Laribi
Actuators 2025, 14(5), 247; https://doi.org/10.3390/act14050247 - 14 May 2025
Viewed by 734
Abstract
Variable stiffness actuators (VSAs) have attracted considerable attention in wearable robotics and soft exoskeletons due to their ability to adapt to various load conditions. This study presents a modular design for VSAs that incorporates a chain mail structure with various link topologies, allowing [...] Read more.
Variable stiffness actuators (VSAs) have attracted considerable attention in wearable robotics and soft exoskeletons due to their ability to adapt to various load conditions. This study presents a modular design for VSAs that incorporates a chain mail structure with various link topologies, allowing for a reconfiguration of stiffness. The proposed VSA consists of three main parts: the vacuum chamber, the VSA actuator, and the chain mail structure. The VSA fabrication process was carried out in five stages: (1) mold fabrication by 3D FDM printing, incorporating a film of oil to facilitate easy demolding; (2) mold preparation using silicone, with a precise ratio of 1:1 weight-based mixture to optimize material utilization; (3) silicone pouring into molds while applying vibration to eliminate air bubbles; (4) curing for four hours to achieve optimal mechanical properties; and (5) careful demolding to prevent damage. Experimental tests were conducted to characterize the stiffness of actuators with different chain mail fabric configurations, using an experimental setup designed to securely fix the actuator and accurately measure the pneumatic pressure and the angle of deformation after applying weights at its end. The European 6-in-1 and rounded square configurations were shown to be the most effective, increasing stiffness up to 382% compared to the chain mail-free configuration, highlighting the positive impact of these structural designs. Full article
(This article belongs to the Special Issue Advanced Technologies in Soft Actuators)
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20 pages, 9094 KiB  
Article
Finite Element Simulation of Injection Mold Design Integrating Different Structures of Conformal Cooling Channels
by Meiyun Zhao and Zhengcheng Tang
Processes 2025, 13(1), 234; https://doi.org/10.3390/pr13010234 - 15 Jan 2025
Viewed by 1751
Abstract
Injection molding (IM) is a process in which completely melted plastic material is injected into the mold cavity under high pressure at a specific temperature, and the molded product is obtained after pressure holding, cooling, and demolding. During the mold cooling process, the [...] Read more.
Injection molding (IM) is a process in which completely melted plastic material is injected into the mold cavity under high pressure at a specific temperature, and the molded product is obtained after pressure holding, cooling, and demolding. During the mold cooling process, the conformal cooling channel system can improve the uniformity of mold temperature, reduce warping deformation, and significantly improve product accuracy. However, the cost consumption of conformal cooling channels for the cavity and core of injection molds is significant, which is a distinct disadvantage. This paper proposes an innovative conformal cooling channel. Compared with conventional cooling channels, the warpage of plastic parts has been reduced by 0.3401 mm. Moreover, the cooling time difference between C2 and C4 is relatively small, about 7.9 s. Among them, C4 takes the shortest time, C1 takes the longest, and C4 is 4.371 s shorter than C1. Compared with C1, the cooling efficiency of C4 has increased by 35.48%. In addition, from a commercial value perspective, many mold manufacturing companies’ real production applications are better suited for using conformal cooling channels alone on the injection mold core. This paper establishes injection molding models under different working conditions, simulates the cooling of dynamic mold temperature molds, and analyzes the effects of fluid media and various fluid rates on mold temperature changes. The results indicate that the cooling effect of cooling water is significantly better than that of cooling oil at the same fluid rate. When the fluid rate increases from 0.75 L/min to 6 L/min, the effect of cooling oil on the temperature change in the mold is significantly higher than that of cooling water. The influence of mold temperature on the cooling medium’s fluid rate tends to stabilize once the cooling medium’s flow rate reaches a specific value. Full article
(This article belongs to the Special Issue Modeling and Simulation in Polymer Reaction Engineering)
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16 pages, 10339 KiB  
Article
Exploring the Application Method of Bamboo Powder in Promoting the Development of Sustainable Outdoor Furniture
by Yafei Fan, Ziqian Zhu, Jiacheng Luan and Yi Liu
Sustainability 2024, 16(24), 11282; https://doi.org/10.3390/su162411282 - 23 Dec 2024
Cited by 2 | Viewed by 1429
Abstract
With the depletion of fossil fuels, more and more green products are appearing in daily necessities. Bamboo is a common sustainable biomaterial with the characteristics of fast growth, easy bending, low cost, and easy processing, and it is widely used in furniture design. [...] Read more.
With the depletion of fossil fuels, more and more green products are appearing in daily necessities. Bamboo is a common sustainable biomaterial with the characteristics of fast growth, easy bending, low cost, and easy processing, and it is widely used in furniture design. However, the poor aging resistance and UV resistance of natural bamboo materials limit their application in outdoor furniture. In order to improve the service life of outdoor bamboo furniture, this study prepared bamboo boards from bamboo powder and utilized them in the design of outdoor furniture. The research was conducted in two stages. In the first stage, functional modification was carried out on the surface of bamboo fibers (BF). Epoxy resin and UV absorber ZnO were introduced into the bamboo powder matrix, and a three-dimensional network structure of bamboo powder-based polymer material was formed by adjusting the material ratio and reaction conditions. With the increase of ZnO content, the absorption of moisture by the bamboo powder-based polymer materials decreased. The compressive strength of 1.5%ZnO-Board reached 36.8 MPa, exceeding the compressive strength of C30 concrete. In the second stage, 1.5% ZnO-Board was selected for solidification and demolding, and used as the seat surface for outdoor chairs. Through the car crushing experiment, the chair panel did not undergo significant deformation during the car crushing process. The anti-aging experiment showed that the structure and morphology of the panel would not be damaged by long-term UV irradiation. The panel did not show any weight changes in the anti-water-absorption experiment. By using low-contrast color combinations, the seats can be organically integrated into the environmental background, effectively enhancing the coordination and unity of the overall aesthetic harmony of the space. Compared with the commonly used plastic outdoor seats, the outdoor seats prepared in this study showed a 144% increase in carbon reduction effect. This study highlights the potential of modified bamboo powder for the design of outdoor furniture, which is of great significance to reducing outdoor plastic products and promoting sustainable life. Full article
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11 pages, 4644 KiB  
Article
Effects of Thermoforming Parameters on Woven Carbon Fiber Thermoplastic Composites
by Shun-Fa Hwang, Cheng-Yi Yang and Shao-Hao Huang
Materials 2024, 17(16), 3932; https://doi.org/10.3390/ma17163932 - 7 Aug 2024
Cited by 2 | Viewed by 1467
Abstract
The quality of woven carbon fiber fabric/polycarbonate thermoplastic composites after thermoforming and demolding was investigated using finite element simulation and the Taguchi orthogonal array. The simulation utilized a discrete approach with a micro-mechanical model to describe the deformation of woven carbon fabric, combined [...] Read more.
The quality of woven carbon fiber fabric/polycarbonate thermoplastic composites after thermoforming and demolding was investigated using finite element simulation and the Taguchi orthogonal array. The simulation utilized a discrete approach with a micro-mechanical model to describe the deformation of woven carbon fabric, combined with a resin model. This simulation was validated with bias extension tests at five temperatures. The thermoforming process parameters considered were blank temperature, mold temperature, and blank holding pressure, with three levels for each factor. Optimal values for the fiber-enclosed angle, spring-back angle, mold shape fitness, and the strain of the U-shaped workpiece were desired. The results indicated that the comparison of the stress-displacement curve of bias extension tests verified the application of the discrete finite element method. Results from the Taguchi array indicated that blank holding pressure was the dominant parameter, with the optimal value being 1.18 kPa. Blank temperature was the second most significant factor, effective in the range of 160 °C to 230 °C, while mold temperature had a minor effect. Furthermore, the four quality values are dependent and have a similar trend. The best combination was identified as a blank holding press of 1.18 kPa, a blank temperature of 230 °C, and a mold temperature of 190 °C. Full article
(This article belongs to the Special Issue Structural Design and Analysis of Fiber Composites)
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22 pages, 15592 KiB  
Article
Enhancing the Forming Accuracy of CFRP through a Global Compensation Method by Introducing an Optimal Profile
by Yongming Zhang, Luling An and Cong Zhao
Polymers 2024, 16(13), 1792; https://doi.org/10.3390/polym16131792 - 25 Jun 2024
Cited by 1 | Viewed by 1217
Abstract
Irreversible curing distortion represents a significant limiting factor in the application of high-performance composite structures. Curing distortion is the deviation of a component’s profile from the theoretical profile after demolding. Introducing the optimal compensation profile into the traditional compensation algorithm represents an effective [...] Read more.
Irreversible curing distortion represents a significant limiting factor in the application of high-performance composite structures. Curing distortion is the deviation of a component’s profile from the theoretical profile after demolding. Introducing the optimal compensation profile into the traditional compensation algorithm represents an effective method to enhance CFRPs’ forming accuracy. For this method, it is necessary to obtain the optimal compensating profile by establishing the coordinate model of the curing process parameter and mold profile compensation. The coordinated control model consists of four parameters: the mean value (Dav), root mean square value (Dmsr), minimum (Dmin), and maximum (Dmax) of curing distortion. Two sizes of composite structural parts are manufactured using the global compensation method. We investigate the influence mechanisms of heating, holding, and cooling times on curing distortion and residual stresses and develop a multi-field coupled finite element model. Strong agreement between the numerical and experimental findings serves as evidence for the effectiveness of the numerical model. The middle layer of the fabricated parts exhibit a reduction in residual stresses as the heating and holding times increase, while an opposite trend is noted with an increase in cooling time. Refining the design of curing process parameters can yield the minimum value of curing deformation within the specified resin system interval. Comparisons indicate that the distortion of the composite wall panel structure is reduced by 86.2% through the use of the global compensation method, demonstrating the validity of this approach for composite structures. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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23 pages, 5182 KiB  
Review
Variable Shape Tooling for Composite Manufacturing: A Systematic Review
by Fabian Neumann
J. Compos. Sci. 2024, 8(4), 131; https://doi.org/10.3390/jcs8040131 - 3 Apr 2024
Cited by 2 | Viewed by 2904
Abstract
The choice of material, manufacturing process, and molding tool significantly affects the quality, environmental impact, and cost efficiency of composite components. Producing one-piece hollow profiles with smooth inner surfaces and undercuts presents major challenges for conventional mold concepts. There is yet no thorough [...] Read more.
The choice of material, manufacturing process, and molding tool significantly affects the quality, environmental impact, and cost efficiency of composite components. Producing one-piece hollow profiles with smooth inner surfaces and undercuts presents major challenges for conventional mold concepts. There is yet no thorough review of shape-variable mandrels in composite manufacturing to be found in the literature. This paper provides an overview of research on shape memory polymers and other shape-variable materials used in tooling applications for composite manufacturing. This work covers shape memory, heat shrink, and other deformable tooling concepts that enable the production of one-piece Type V pressure vessels, air intake ducts, or curved struts and tubes. A systematic literature review in combination with a state-of-the-art open-source active learning tool ASReview is conducted. Fifteen relevant studies were identified. Research on shape-variable tooling is mainly conducted by three research groups in the USA and the PRC. The tooling is mostly made of unreinforced thermosets, especially styrene-based ones. Thermoplastic resins are less common, and reinforcements limit the usable elongation in the temporary shape. The shape variability is either a shape memory and/or a softening process, which, in all studies, is activated by heating. Release agents are widely used to ease demolding. No ecological or economical assessment of the manufacturing methods was conducted in the reviewed studies. Three fields for further research that could be identified are as follows: (1) thorough ecological end economical assessment of shape-variable mandrels in comparison with conventional tooling; (2) thermoplastic shape memory polymer mandrels; and (3) further investigation of simulation capabilities for shape memory mandrels. Full article
(This article belongs to the Section Composites Manufacturing and Processing)
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13 pages, 3765 KiB  
Article
A Glass–Ultra-Thin PDMS Film–Glass Microfluidic Device for Digital PCR Application Based on Flexible Mold Peel-Off Process
by Yanming Xia, Xianglong Chu, Caiming Zhao, Nanxin Wang, Juan Yu, Yufeng Jin, Lijun Sun and Shenglin Ma
Micromachines 2022, 13(10), 1667; https://doi.org/10.3390/mi13101667 - 4 Oct 2022
Cited by 5 | Viewed by 4253
Abstract
The microfluidic device (MFD) with a glass–PDMS–glass (G-P-G) structure is of interest for a wide range of applications. However, G-P-G MFD fabrication with an ultra-thin PDMS film (especially thickness less than 200 μm) is still a big challenge because the ultra-thin PDMS film [...] Read more.
The microfluidic device (MFD) with a glass–PDMS–glass (G-P-G) structure is of interest for a wide range of applications. However, G-P-G MFD fabrication with an ultra-thin PDMS film (especially thickness less than 200 μm) is still a big challenge because the ultra-thin PDMS film is easily deformed, curled, and damaged during demolding and transferring. This study aimed to report a thickness-controllable and low-cost fabrication process of the G-P-G MFD with an ultra-thin PDMS film based on a flexible mold peel-off process. A patterned photoresist layer was deposited on a polyethylene terephthalate (PET) film to fabricate a flexible mold that could be demolded softly to achieve a rigid structure of the glass–PDMS film. The thickness of ultra-thin patterned PDMS could reach less than 50 μm without damage to the PDMS film. The MFD showcased the excellent property of water evaporation inhibition (water loss < 10%) during PCR thermal cycling because of the ultra-thin PDMS film. Its low-cost fabrication process and excellent water evaporation inhibition present extremely high prospects for digital PCR application. Full article
(This article belongs to the Topic Advances in Microfluidics and Lab on a Chip Technology)
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16 pages, 6367 KiB  
Article
Effect of Interfacial Interaction on the Demolding Deformation of Injection Molded Microfluidic Chips
by Yilei Wang, Can Weng, Huijie Sun, Zijian Deng and Bingyan Jiang
Nanomaterials 2022, 12(19), 3416; https://doi.org/10.3390/nano12193416 - 29 Sep 2022
Cited by 4 | Viewed by 2027
Abstract
During the demolding process, the interfacial interaction between the polymer and the metal mold insert will lead to the deformation of the micro-structure, which will directly affect the molding quality and performance of injection molded microfluidic chips. In this study, the demolding quality [...] Read more.
During the demolding process, the interfacial interaction between the polymer and the metal mold insert will lead to the deformation of the micro-structure, which will directly affect the molding quality and performance of injection molded microfluidic chips. In this study, the demolding quality of micro-channels and micro-mixing structures of polycarbonate (PC), polymethyl methacrylate (PMMA), cyclic olefin copolymer (COC), and polystyrene (PS) microfluidic chips for heavy metal detection were investigated by molding experiments. The experimental results showed that the structures of microfluidic chips could be completely replicated. However, tensile deformation and fracture defects were observed at the edges of the micro-structures after demolding. Compared to the Ni mold insert, the calculation of the relative deviation percentages showed that the width of the micro-channel became larger and the depth became smaller, while the dimensions of the micro-mixing structure changes in the opposite direction. Subsequently, a molecular dynamics (MD) simulation model of polymer/nickel (Ni) mold insert for injection molding was established. The changes of adhesion work, demolding resistance and potential energy during demolding were analyzed. The simulation results showed that the polymer structures had some deformations such as necking, molecular chain stretching and voids under the action of adhesion work and demolding resistance. The difference in the contact area with the mold insert directly brought different interfacial interactions. In addition, the potential energy change of the polymer system could be used to quantitatively characterize the demolding deformation of the structure. Overall, the MD method is able to effectively explain the internal mechanisms of interfacial interactions, leading to the demolding deformation of polymer structures from the molecular/atomic scale. Full article
(This article belongs to the Special Issue Micro/Nano-Machining: Fundamentals and Recent Advances)
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12 pages, 3397 KiB  
Article
Thermoplastic Mandrel for Manufacturing Composite Components with Complex Structure
by Xishuang Jing, Siyu Chen, Jiuzhi An, Chengyang Zhang and Fubao Xie
Aerospace 2021, 8(12), 399; https://doi.org/10.3390/aerospace8120399 - 16 Dec 2021
Cited by 2 | Viewed by 5001
Abstract
This study was to solve the mandrel demolding problem after curing the composite component with complex structure. In this paper, a reusable thermoplastic mandrel with heating softening characteristics was developed by resin transfer molding (RTM). The glass transition temperature (Tg), surface roughness, and [...] Read more.
This study was to solve the mandrel demolding problem after curing the composite component with complex structure. In this paper, a reusable thermoplastic mandrel with heating softening characteristics was developed by resin transfer molding (RTM). The glass transition temperature (Tg), surface roughness, and reusability of the mandrel, as well as the shape, surface roughness, thickness uniformity, and internal quality of the formed structure, were tested. The result showed that the Tg of the mandrel was between 80 and 90 °C and the surface roughness was less than Ra 0.5 μm. Additionally, the mandrel can be recycled and can still maintain a good shape after 20 times of deformation. By using this method, the demolding process can be realized by heating and softening the mandrel. The profile error of the formed structure was within 0.5 mm, the surface roughness was less than Ra 0.5 μm, the thickness error was within 0.2 mm, and the average porosity of the upper and lower halves of composite parts was 0.72% and 0.61%. All those data showed that the formed part was in good shape and of good quality. The thermoplastic mandrel can solve the demolding problem of composite materials with complex shapes. Full article
(This article belongs to the Special Issue Advanced Aerospace Composite Materials)
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14 pages, 4947 KiB  
Article
Experimental Investigation and Molecular Dynamics Simulation on the Anti-Adhesion Behavior of Alkanethiols on Nickel Insert in Micro Injection Molding
by Can Weng, Jiachen Chen, Jin Yang, Mingyong Zhou and Bingyan Jiang
Nanomaterials 2021, 11(7), 1834; https://doi.org/10.3390/nano11071834 - 14 Jul 2021
Cited by 2 | Viewed by 2296
Abstract
Due to the adhesion between the polymer melt and nickel (Ni) mold insert in the micro injection molding process, deformation defects frequently occur when the microstructures are demolded from the insert. In this study, self-assembled alkanethiols were applied to modify the surface of [...] Read more.
Due to the adhesion between the polymer melt and nickel (Ni) mold insert in the micro injection molding process, deformation defects frequently occur when the microstructures are demolded from the insert. In this study, self-assembled alkanethiols were applied to modify the surface of Ni mold insert to reduce its surface energy. Experimental trials were undertaken to explore the effect of alkanethiols coating on the replication quality. After that, molecular dynamics (MD) simulation was then used to investigate the adhesion behavior between the self-assembled coating and polypropylene (PP) by establishing three different types of alkanethiol material. The interaction energy, the potential energy change and radial distribution function were calculated to study the anti-adhesion mechanism. Experimental results show that all the three coatings can effectively decrease the adhesion and therefore promote the replication fidelity. It is demonstrated in MD simulation that the adhesion mainly comes from the van der Waals (vdW) force at the interface. The arrangement of sulfur atom on the Ni surface results in different absorbing behaviors. Compared with that of the PP–Ni interface, the interfacial energy and adhesion work after surface treatment is significantly reduced. Full article
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13 pages, 6030 KiB  
Article
Self-Assembled Monolayers of Alkanethiols on Nickel Insert: Characterization of Friction and Analysis on Demolding Quality in Microinjection Molding
by Jiachen Chen, Jin Yang, Mingyong Zhou and Can Weng
Micromachines 2021, 12(6), 636; https://doi.org/10.3390/mi12060636 - 29 May 2021
Cited by 7 | Viewed by 2766
Abstract
When the part geometry scaling down from macro to microscale level, the size-induced surface effect becomes significant in the injection molding process. The adhesion between polymer and nickel (Ni) mold insert during the process can lead to defects in necking, warping and deformation [...] Read more.
When the part geometry scaling down from macro to microscale level, the size-induced surface effect becomes significant in the injection molding process. The adhesion between polymer and nickel (Ni) mold insert during the process can lead to defects in necking, warping and deformation of microstructure. In this study, the self-assembled monolayers (SAMs) with low surface energy were deposited on the Ni surface to reduce the adhesion and further improve the demolding quality of the microstructure. Results show that the alkyl mercaptan SAMs with chemical bonds and close alignment can be successfully deposited on the surface of Ni by the solution deposition method. The contact angle, surface free energy, and friction coefficient before and after anti-adhesion treatment on the surface of mold insert were measured. In addition, the anti-adhesion properties of different alkyl mercaptan materials and the correspondingly replication quality of microstructure parts after injection molding were analyzed. It is found that the Ni mold insert treated by the perfluorodecanethiol has the best wear resistance and still shows good reproducibility at the 100th demolding cycle. Full article
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14 pages, 42938 KiB  
Article
Influence of Diamond-Like Carbon Coating on the Channel Deformation of Injection-Molded Microfluidic Chips during the Demolding Process
by Yilei Wang, Bingyan Jiang, Mingyong Zhou, Jiachen Chen and Can Weng
Polymers 2020, 12(12), 2914; https://doi.org/10.3390/polym12122914 - 4 Dec 2020
Cited by 8 | Viewed by 2245
Abstract
Injection molding is one of the main techniques for manufacturing microfluidic chips. As an important stage, the demolding process in injection molding will directly affect the quality of the functional unit of microfluidic chips (polymer microchannels), thus limiting the realization of its functions. [...] Read more.
Injection molding is one of the main techniques for manufacturing microfluidic chips. As an important stage, the demolding process in injection molding will directly affect the quality of the functional unit of microfluidic chips (polymer microchannels), thus limiting the realization of its functions. In this study, molecular dynamics (MD) simulations on the demolding process were carried out to investigate the influence of diamond-like carbon (DLC) coating on the channel deformation. The channel qualities of polystyrene (PS), polymethyl methacrylate (PMMA), cyclic olefin copolymer (COC) and polycarbonate (PC) were analyzed after demolding with nickel (Ni) and DLC-coated mold inserts, respectively. In particular, the non-bonded interfacial interaction energy, elastic recovery and gyration radius of polymer molecular chains were further studied. The results showed that the non-bonded interfacial interaction energies could be significantly reduced by DLC-coating treatment on the mold insert. Moreover, common channel defects such as molecular chain separation, surface burrs and necking did not occur. The treatment of DLC coating could also significantly reduce the change in the gyration radius of polymer molecular chains, so the morphology of the polymer channel could be maintained well. However, the change in the elastic recovery of the polymer channel was increased, and the opening width became larger. In a word, DLC-coating treatment on the mold insert has great application potential for improving the demolding quality of injection-molded microfluidic chips. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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14 pages, 7162 KiB  
Article
Formation Mechanism of Residual Stresses in Micro-Injection Molding of PMMA: A Molecular Dynamics Simulation
by Can Weng, Tao Ding, Mingyong Zhou, Jiezhen Liu and Hao Wang
Polymers 2020, 12(6), 1368; https://doi.org/10.3390/polym12061368 - 17 Jun 2020
Cited by 16 | Viewed by 3936
Abstract
Injection molding is an economical and effective method for manufacturing polymer parts with nanostructures and residual stress in the parts is an important factor affecting the quality of molding. In this paper, taking the injection molding of polymethyl methacrylate (PMMA) polymer in a [...] Read more.
Injection molding is an economical and effective method for manufacturing polymer parts with nanostructures and residual stress in the parts is an important factor affecting the quality of molding. In this paper, taking the injection molding of polymethyl methacrylate (PMMA) polymer in a nano-cavity with an aspect ratio of 2.0 as an example, the formation mechanism of residual stresses in the injection molding process was studied, using a molecular dynamics simulation. The changes in dynamic stress in the process were compared and analyzed, and the morphological and structural evolution of molecular chains in the process of flow were observed and explained. The effects of different aspect ratios of nano-cavities on the stress distribution and deformation in the nanostructures were studied. The potential energy, radius of gyration and elastic recovery percentage of the polymer was calculated. The results showed that the essence of stress formation was that the molecular chains compressed and entangled under the flow pressure and the restriction of the cavity wall. In addition, the orientation of molecular chains changed from isotropic to anisotropic, resulting in the stress concentration. At the same time, with the increase in aspect ratio, the overall stress and deformation of the nanostructures after demolding also increased. Full article
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16 pages, 45659 KiB  
Article
Molecular Dynamics Simulation on the Influences of Nanostructure Shape, Interfacial Adhesion Energy, and Mold Insert Material on the Demolding Process of Micro-Injection Molding
by Jin Yang, Can Weng, Jun Lai, Tao Ding and Hao Wang
Polymers 2019, 11(10), 1573; https://doi.org/10.3390/polym11101573 - 27 Sep 2019
Cited by 19 | Viewed by 3915
Abstract
In micro-injection molding, the interaction between the polymer and the mold insert has an important effect on demolding quality of nanostructure. An all-atom molecular dynamics simulation method was performed to study the effect of nanostructure shape, interfacial adhesion energy, and mold insert material [...] Read more.
In micro-injection molding, the interaction between the polymer and the mold insert has an important effect on demolding quality of nanostructure. An all-atom molecular dynamics simulation method was performed to study the effect of nanostructure shape, interfacial adhesion energy, and mold insert material on demolding quality of nanostructures. The deformation behaviors of nanostructures were analyzed by calculating the non-bonded interaction energies, the density distributions, the radii of gyration, the potential energies, and the snapshots of the demolding stage. The nanostructure shape had a direct impact on demolding quality. When the contact areas were the same, the nanostructure shape did not affect the non-bonded interaction energy at PP-Ni interface. During the demolding process, the radii of gyration of molecular chains were greatly increased, and the overall density was decreased significantly. After assuming that the mold insert surface was coated with an anti-stick coating, the surface burrs, the necking, and the stretching of nanostructures were significantly reduced after demolding. The deformation of nanostructures in the Ni and Cu mold inserts were more serious than that of the Al2O3 and Si mold inserts. In general, this study would provide theoretical guidance for the design of nanostructure shape and the selection of mold insert material. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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13 pages, 5132 KiB  
Article
Molecular Dynamics Simulations on the Demolding Process for Nanostructures with Different Aspect Ratios in Injection Molding
by Can Weng, Dongjiao Yang and Mingyong Zhou
Micromachines 2019, 10(10), 636; https://doi.org/10.3390/mi10100636 - 23 Sep 2019
Cited by 11 | Viewed by 3298
Abstract
Injection molding is one of the most potential techniques for fabricating polymeric products in large numbers. The filling process, but also the demolding process, influence the quality of injection-molded nanostructures. In this study, nano-cavities with different depth-to-width ratios (D/W) were built and molecular [...] Read more.
Injection molding is one of the most potential techniques for fabricating polymeric products in large numbers. The filling process, but also the demolding process, influence the quality of injection-molded nanostructures. In this study, nano-cavities with different depth-to-width ratios (D/W) were built and molecular dynamics simulations on the demolding process were conducted. Conformation change and density distribution were analyzed. Interfacial adhesion was utilized to investigate the interaction mechanism between polypropylene (PP) and nickel mold insert. The results show that the separation would first happen at the shoulder of the nanostructures. Nanostructures and the whole PP layer are both stretched, resulting in a sharp decrease in average density after demolding. The largest increase in the radius of gyration and lowest velocity can be observed in 3:1 nanostructure during the separation. Deformation on nanostructure occurs, but nevertheless the whole structure is still in good shape. The adhesion energy gets higher with the increase of D/W. The demolding force increases quickly to the peak point and then gradually decreases to zero. The majority of the force comes from the adhesion and friction on the nanostructure due to the interfacial interaction. Full article
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