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Keywords = compatible camouflage

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21 pages, 5415 KiB  
Article
Hierarchical 3D FeCoNi Alloy/CNT @ Carbon Nanofiber Sponges as High-Performance Microwave Absorbers with Infrared Camouflage
by Yifan Fei, Junya Yao, Wei Cheng and Wenling Jiao
Materials 2025, 18(1), 113; https://doi.org/10.3390/ma18010113 - 30 Dec 2024
Cited by 1 | Viewed by 1023
Abstract
Microwave absorbers with infrared camouflage are highly desirable in military fields. Self-supporting 3D architectures with tailorable shapes, composed of FeCoNi alloy/carbon nanotubes (CNTs) @ carbon nanofibers (CNFs), were fabricated in this study. On the one hand, multiple loss mechanisms were introduced into the [...] Read more.
Microwave absorbers with infrared camouflage are highly desirable in military fields. Self-supporting 3D architectures with tailorable shapes, composed of FeCoNi alloy/carbon nanotubes (CNTs) @ carbon nanofibers (CNFs), were fabricated in this study. On the one hand, multiple loss mechanisms were introduced into the high-elastic sponges. Controllable space conductive networks caused by the in situ growth of CNTs on the CNFs contributed to the effective dielectric and resistance loss. Moreover, the uniformly distributed magnetic alloy nanoparticles (NPs) with dense magnetic coupling resulted in magnetic loss. On the other hand, heterogeneous interfaces were constructed by multicomponent engineering, causing interfacial polarization and polarization loss. Furthermore, the internal structures of sponges were optimized by regulating the alloy NPs sizes and the growth state of CNTs, then tuning the impedance matching and microwave absorption. Therefore, the high-elastic sponges with ultra-low density (7.6 mg·cm−3) were found to have excellent radar and infrared-compatible stealth properties, displaying a minimum refection loss (RLmin) of −50.5 dB and a maximum effective absorption bandwidth (EABmax) of 5.36 GHz. Moreover, the radar stealth effect of the sponges was evaluated by radar cross-section (RCS) simulation, revealing that the multifunctional sponges have a promising prospect in military applications. Full article
(This article belongs to the Special Issue Advances in Electrostatic Spinning Micro and Nano Fibers)
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23 pages, 5774 KiB  
Review
Recent Advances in Graphene Adaptive Thermal Camouflage Devices
by Lucia Sansone, Fausta Loffredo, Fabrizia Cilento, Riccardo Miscioscia, Alfonso Martone, Nicola Barrella, Bruno Paulillo, Alessio Bassano, Fulvia Villani and Michele Giordano
Nanomaterials 2024, 14(17), 1394; https://doi.org/10.3390/nano14171394 - 26 Aug 2024
Cited by 1 | Viewed by 3626
Abstract
Thermal camouflage is a highly coveted technology aimed at enhancing the survivability of military equipment against infrared (IR) detectors. Recently, two-dimensional (2D) nanomaterials have shown low IR emissivity, widely tunable opto-electronic properties, and compatibility with stealth applications. Among these, graphene and graphene-like materials [...] Read more.
Thermal camouflage is a highly coveted technology aimed at enhancing the survivability of military equipment against infrared (IR) detectors. Recently, two-dimensional (2D) nanomaterials have shown low IR emissivity, widely tunable opto-electronic properties, and compatibility with stealth applications. Among these, graphene and graphene-like materials are the most appealing 2D materials for thermal camouflage applications. In multilayer graphene (MLG), charge density can be effectively tuned through sufficiently intense electric fields or through electrolytic gating. Therefore, MLG’s optical properties, like infrared emissivity and absorbance, can be controlled in a wide range by voltage bias. The large emissivity modulation achievable with this material makes it suitable in the design of thermal dynamic camouflage devices. Generally, the emissivity modulation in the multilayered graphene medium is governed by an intercalation process of non-volatile ionic liquids under a voltage bias. The electrically driven reduction of emissivity lowers the apparent temperature of a surface, aligning it with the background temperature to achieve thermal camouflage. This characteristic is shared by other graphene-based materials. In this review, we focus on recent advancements in the thermal camouflage properties of graphene in composite films and aerogel structures. We provide a summary of the current understanding of how thermal camouflage materials work, their present limitations, and future opportunities for development. Full article
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27 pages, 16898 KiB  
Article
αvβ3 Integrin and Folate-Targeted pH-Sensitive Liposomes with Dual Ligand Modification for Metastatic Breast Cancer Treatment
by Prashant Pandey, Dilip Kumar Arya, Payal Deepak, Daoud Ali, Saud Alarifi, Saurabh Srivastava, Afsaneh Lavasanifar and Paruvathanahalli Siddalingam Rajinikanth
Bioengineering 2024, 11(8), 800; https://doi.org/10.3390/bioengineering11080800 - 7 Aug 2024
Cited by 13 | Viewed by 2969
Abstract
The advent of pH-sensitive liposomes (pHLips) has opened new opportunities for the improved and targeted delivery of antitumor drugs as well as gene therapeutics. Comprising fusogenic dioleylphosphatidylethanolamine (DOPE) and cholesteryl hemisuccinate (CHEMS), these nanosystems harness the acidification in the tumor microenvironment and endosomes [...] Read more.
The advent of pH-sensitive liposomes (pHLips) has opened new opportunities for the improved and targeted delivery of antitumor drugs as well as gene therapeutics. Comprising fusogenic dioleylphosphatidylethanolamine (DOPE) and cholesteryl hemisuccinate (CHEMS), these nanosystems harness the acidification in the tumor microenvironment and endosomes to deliver drugs effectively. pH-responsive liposomes that are internalized through endocytosis encounter mildly acidic pH in the endosomes and thereafter fuse or destabilize the endosomal membrane, leading to subsequent cargo release into the cytoplasm. The extracellular tumor matrix also presents a slightly acidic environment that can lead to the enhanced drug release and improved targeting capabilities of the nano-delivery system. Recent studies have shown that folic acid (FA) and iRGD-coated nanocarriers, including pH-sensitive liposomes, can preferentially accumulate and deliver drugs to breast tumors that overexpress folate receptors and αvβ3 and αvβ5 integrins. This study focuses on the development and characterization of 5-Fluorouracil (5-FU)-loaded FA and iRGD surface-modified pHLips (FA-iRGD-5-FU-pHLips). The novelty of this research lies in the dual targeting mechanism utilizing FA and iRGD peptides, combined with the pH-sensitive properties of the liposomes, to enhance selective targeting and uptake by cancer cells and effective drug release in the acidic tumor environment. The prepared liposomes were small, with an average diameter of 152 ± 3.27 nm, uniform, and unilamellar, demonstrating efficient 5-FU encapsulation (93.1 ± 2.58%). Despite surface functionalization, the liposomes maintained their pH sensitivity and a neutral zeta potential, which also conferred stability and reduced aggregation. Effective pH responsiveness was demonstrated by the observation of enhanced drug release at pH 5.5 compared to physiological pH 7.4. (84.47% versus 46.41% release at pH 5.5 versus pH 7.4, respectively, in 72 h). The formulations exhibited stability for six months and were stable when subjected to simulated biological settings. Blood compatibility and cytotoxicity studies on MDA-MB-231 and SK-BR3 breast cancer cell lines revealed an enhanced cytotoxicity of the liposomal formulation that was modified with FA and iRGD compared to free 5-FU and minimal hemolysis. Collectively, these findings support the potential of FA and iRGD surface-camouflaged, pH-sensitive liposomes as a promising drug delivery strategy for breast cancer treatment. Full article
(This article belongs to the Special Issue Natural Peptides/Proteins and Their Applications in Bioengineering)
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13 pages, 4305 KiB  
Article
Three-Layered Thin Films for Simultaneous Infrared Camouflage and Radiative Cooling
by Luyu Zhang, Wenjie Zhang, Yuanbin Liu and Linhua Liu
Materials 2023, 16(11), 4188; https://doi.org/10.3390/ma16114188 - 5 Jun 2023
Cited by 10 | Viewed by 2999
Abstract
With the rapid advancements in aerospace technology and infrared detection technology, there are increasing needs for materials with simultaneous infrared camouflage and radiative cooling capabilities. In this study, a three-layered Ge/Ag/Si thin film structure on a titanium alloy TC4 substrate (a widely used [...] Read more.
With the rapid advancements in aerospace technology and infrared detection technology, there are increasing needs for materials with simultaneous infrared camouflage and radiative cooling capabilities. In this study, a three-layered Ge/Ag/Si thin film structure on a titanium alloy TC4 substrate (a widely used skin material for spacecraft) is designed and optimized to achieve such spectral compatibility by combining the transfer matrix method and the genetic algorithm. The structure exhibits a low average emissivity of 0.11 in the atmospheric windows of 3–5 μm and 8–14 μm for infrared camouflage and a high average emissivity of 0.69 in 5–8 μm for radiative cooling. Furthermore, the designed metasurface shows a high degree of robustness regarding the polarization and incidence angle of the incoming electromagnetic wave. The underlying mechanisms allowing for the spectral compatibility of the metasurface can be elucidated as follows: the top Ge layer selectively transmits electromagnetic waves ranging from 5–8 μm while it reflects those in the ranges of 3–5 μm and 8–14 μm. The transmitted electromagnetic waves from the Ge layer are first absorbed by the Ag layer and then localized in the Fabry-Perot resonance cavity formed by Ag layer, Si layer and TC4 substrate. Ag and TC4 make further intrinsic absorptions during the multiple reflections of the localized electromagnetic waves. Full article
(This article belongs to the Section Thin Films and Interfaces)
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19 pages, 5936 KiB  
Article
Tunable Infrared Detection, Radiative Cooling and Infrared-Laser Compatible Camouflage Based on a Multifunctional Nanostructure with Phase-Change Material
by Mingyu Luo, Xin Li, Zhaojian Zhang, Hansi Ma, Te Du, Xinpeng Jiang, Zhenrong Zhang and Junbo Yang
Nanomaterials 2022, 12(13), 2261; https://doi.org/10.3390/nano12132261 - 30 Jun 2022
Cited by 17 | Viewed by 3925
Abstract
The nanostructure composed of nanomaterials and subwavelength units offers flexible design freedom and outstanding advantages over conventional devices. In this paper, a multifunctional nanostructure with phase-change material (PCM) is proposed to achieve tunable infrared detection, radiation cooling and infrared (IR)-laser compatible camouflage. The [...] Read more.
The nanostructure composed of nanomaterials and subwavelength units offers flexible design freedom and outstanding advantages over conventional devices. In this paper, a multifunctional nanostructure with phase-change material (PCM) is proposed to achieve tunable infrared detection, radiation cooling and infrared (IR)-laser compatible camouflage. The structure is very simple and is modified from the classic metal–dielectric–metal (MIM) multilayer film structure. We innovatively composed the top layer of metals with slits, and introduced a non-volatile PCM Ge2Sb2Te5 (GST) for selective absorption/radiation regulation. According to the simulation results, wide-angle and polarization-insensitive dual-band infrared detection is realized in the four-layer structure. The transformation from infrared detection to infrared stealth is realized in the five-layer structure, and laser stealth is realized in the atmospheric window by electromagnetic absorption. Moreover, better radiation cooling is realized in the non-atmospheric window. The proposed device can achieve more than a 50% laser absorption rate at 10.6 μm while ensuring an average infrared emissivity below 20%. Compared with previous works, our proposed multifunctional nanostructures can realize multiple applications with a compact structure only by changing the temperature. Such ultra-thin, integratable and multifunctional nanostructures have great application prospects extending to various fields such as electromagnetic shielding, optical communication and sensing. Full article
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18 pages, 16396 KiB  
Article
Extended Spatially Localized Perturbation GAN (eSLP-GAN) for Robust Adversarial Camouflage Patches
by Yongsu Kim, Hyoeun Kang, Naufal Suryanto, Harashta Tatimma Larasati, Afifatul Mukaroh and Howon Kim
Sensors 2021, 21(16), 5323; https://doi.org/10.3390/s21165323 - 6 Aug 2021
Cited by 3 | Viewed by 3775
Abstract
Deep neural networks (DNNs), especially those used in computer vision, are highly vulnerable to adversarial attacks, such as adversarial perturbations and adversarial patches. Adversarial patches, often considered more appropriate for a real-world attack, are attached to the target object or its surroundings to [...] Read more.
Deep neural networks (DNNs), especially those used in computer vision, are highly vulnerable to adversarial attacks, such as adversarial perturbations and adversarial patches. Adversarial patches, often considered more appropriate for a real-world attack, are attached to the target object or its surroundings to deceive the target system. However, most previous research employed adversarial patches that are conspicuous to human vision, making them easy to identify and counter. Previously, the spatially localized perturbation GAN (SLP-GAN) was proposed, in which the perturbation was only added to the most representative area of the input images, creating a spatially localized adversarial camouflage patch that excels in terms of visual fidelity and is, therefore, difficult to detect by human vision. In this study, the use of the method called eSLP-GAN was extended to deceive classifiers and object detection systems. Specifically, the loss function was modified for greater compatibility with an object-detection model attack and to increase robustness in the real world. Furthermore, the applicability of the proposed method was tested on the CARLA simulator for a more authentic real-world attack scenario. Full article
(This article belongs to the Special Issue Selected Papers from WISA 2020)
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29 pages, 5813 KiB  
Review
Smart Textiles for Visible and IR Camouflage Application: State-of-the-Art and Microfabrication Path Forward
by Lauren M. Degenstein, Dan Sameoto, James D. Hogan, Asad Asad and Patricia I. Dolez
Micromachines 2021, 12(7), 773; https://doi.org/10.3390/mi12070773 - 30 Jun 2021
Cited by 52 | Viewed by 11629
Abstract
Protective textiles used for military applications must fulfill a variety of functional requirements, including durability, resistance to environmental conditions and ballistic threats, all while being comfortable and lightweight. In addition, these textiles must provide camouflage and concealment under various environmental conditions and, thus, [...] Read more.
Protective textiles used for military applications must fulfill a variety of functional requirements, including durability, resistance to environmental conditions and ballistic threats, all while being comfortable and lightweight. In addition, these textiles must provide camouflage and concealment under various environmental conditions and, thus, a range of wavelengths on the electromagnetic spectrum. Similar requirements may exist for other applications, for instance hunting. With improvements in infrared sensing technology, the focus of protective textile research and development has shifted solely from providing visible camouflage to providing camouflage in the infrared (IR) region. Smart textiles, which can monitor and react to the textile wearer or environmental stimuli, have been applied to protective textiles to improve camouflage in the IR spectral range. This study presents a review of current smart textile technologies for visible and IR signature control of protective textiles, including coloration techniques, chromic materials, conductive polymers, and phase change materials. We propose novel fabrication technology combinations using various microfabrication techniques (e.g., three-dimensional (3D) printing; microfluidics; machine learning) to improve the visible and IR signature management of protective textiles and discuss possible challenges in terms of compatibility with the different textile performance requirements. Full article
(This article belongs to the Special Issue Polymer Based MEMS and Microfabrication II)
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7 pages, 1647 KiB  
Article
Metal-Based Graphical SiO2/Ag/ZnS/Ag Hetero-Structure for Visible-Infrared Compatible Camouflage
by Dong Qi, Xian Wang, Fu Chen, Yongzhi Cheng and Rongzhou Gong
Materials 2018, 11(9), 1594; https://doi.org/10.3390/ma11091594 - 3 Sep 2018
Cited by 17 | Viewed by 4341
Abstract
A brand-new approach to realizing visible-infrared compatible camouflage is proposed based on a metal-based graphical hetero-structure (MGHS) SiO2/Ag/ZnS/Ag. For different thicknesses (20, 40, and 60 nm) of color-controlling sub-layer, high-contract and large-span structure colors (yellow, navy, and cyan) were observed due [...] Read more.
A brand-new approach to realizing visible-infrared compatible camouflage is proposed based on a metal-based graphical hetero-structure (MGHS) SiO2/Ag/ZnS/Ag. For different thicknesses (20, 40, and 60 nm) of color-controlling sub-layer, high-contract and large-span structure colors (yellow, navy, and cyan) were observed due to reintroducing constructive interference with a matching intensity of reflected waves. Ultra-low infrared emissivity values of 0.04, 0.05, and 0.04 (with high average reflectance values of 95.46%, 95.31%, and 95.09%) were obtained at 3–14 μm. In addition, the well-performing trisecting-circle structure further indicates that it is feasible to design on-demand compatible camouflage patterns using the easily-prepared MGHS. Full article
(This article belongs to the Special Issue Thin Film Fabrication and Surface Techniques)
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