Search Results (7)

The influence of the centerline segregation region (CSR) on the hydrogen embrittlement (HE) of two different API 5L X80 pipeline steel plates was investigated. The novelty of this work was to establish relationships between the CSR, microstructure, and distribution of localized fragile particles on HE susceptibility and on fracture morphology. This work intended to establish a relationship between centerline segregation and HE susceptibility in high-strength low-alloy steels submitted to inhomogeneous transformations. Microscopy, hydrogen permeation, and slow strain rate (SSR) tests were used to investigate hydrogen-related degradation. The solution used on the charging cell of the permeation tests—and on the SSR test cell—was 0.5 mol L⁻¹ H₂SO₄ + 10 mg L⁻¹ As₂O₃, and in the oxidation cell, 0.1 M NaOH was used as a solution. The CSR led the thicker plate to present the highest HE index (0.612) in analyses carried out in the mid-thickness; however, the same plate showed the lowest HE index in near-surface tests. The presence of hydrogen changed the fracture morphology from ductile to a brittle and ductile feature; this occurred due to the interaction with localized fragile particles and the significant reduction of the shear stress necessary for the dislocation movement. Full article

Industrial experiments of mechanical soft reduction in continuous casting were conducted in the present study aiming to improve the internal quality of the bearing steel blooms. Two methods were developed to verify the solidification model for a reliable crater end in the caster, which is provided by SMS CONCAST. The verified solidification model was applied to determine the solidification status of the bloom and provides theoretical reduction region. Several trials were conducted to study the optimization of the reduction rate regarding the V-shaped and centerline segregation of the bloom. The results show an obvious improvement of internal quality in the bearing steel bloom by applying appropriate reduction during casting. Full article

Medium-high carbon steels having a high quality are widely used in China. It is advantageous to produce high value-added hot-rolled plates with the crystal refined and chemical composition homogenized in the casting slabs. However, element segregation occurs easily during high-medium carbon steels’ production. Generally, the centerline segregation is improved by enlarging the equiaxed zone with low-superheat casting and electromagnetic stirring (EMS). Studies were conducted on centerline segregation of S50C steel slabs with a thickness of 52 mm produced by the compact strip production (CSP) process in China without EMS equipped. By sampling along the width at different position, the secondary dendrite arm spacing (SDAS) was measured after etching and picture processing, based on which the cooling rate was calculated. It was found that the cooling rate increased from the center to the surfaces of the slabs ranging in 1~20 K/s, 10 times faster than that of a conventional process. The faster cooling rate led to a refined solidifying structure and columnar dendrite through the center of the slabs. The SDAS tended to increase from surfaces to the center, ranging only 32~120 μm smaller than that of a conventional process in 100~300 μm, indicating a finer solidifying structure by the CSP process. Results by EPMA indicated that elements C, Si, and Mn distribute in dispersed spots, increasing towards the center, and the centerline segregation changed in a narrow range: for C mainly in 1.0~1.1, Si in 0.98~1.08, Mn in 0.96~1.02, respectively, meaning a more chemical homogenization than that of thick slabs. Elements’ segregation originated from solute redistribution between solid and liquid. According to thermodynamic calculation, δ region of S50C is so narrow that the solute redistribution mainly occurred between γ-Fe and liquid during solidification. As the equilibrium partition coefficient of element C was the smallest, it was easy for C to be rejected to the residual liquid in the inter-dendritic space, leading to obvious segregation, relatively. Besides, as a result of high-cooling intensity, the solidifying structure became so fine that the Fourier number increased and the volume of the residual liquid decreased, making centerline segregation alleviated effectively both in volume and degree. Although bulging was observed during the industrial experiment, the centerline segregation was still inhibited obviously as the refining solidifying structure with permeability ranged only in 0.1~2.3 μm² from the surfaces to centerline, which showed a good resistance on the residual flow towards the centerline. Full article

Sedimentation of free-floating grains is the main origin of the negative centerline segregation in direct-chill casting of aluminum alloys. This study examines the motion and distribution of the floating grains during casting using experimental measurements and numerical modeling. The typical floating grains consisting of interior solute-lean coarse dendrites and periphery fine dendrites were experimentally observed only in the central region of the billet along with the negative segregation. The billet exhibits the strongest segregation at the center where the most floating grains are found. In simulations, under the action of the convection and the underlying forces, the grains floating in the transition region exhibit different motion behaviors, i.e., settling to the mushy zone, floating in the slurry zone, and moving upward to the liquid zone. However, most grains were transported to the central region of the billet and then were captured by the mushy zone and settled. Therefore, the floating grains comprise the largest share of the grain structure at the center of the billet, in agreement with the experimental results. Moreover, the simulation results indicate that the increased size of the grains promotes the sedimentation of the floating grains. These results are important for the future alleviation of negative centerline segregation in direct-chill casting of aluminum alloys. Full article

Low variability in mechanical properties is required for pipeline project designs to meet a strain-based design, which is used in regions of large ground movements. The objective of this study is to elucidate the influence of centerline segregation in continuously cast slab on variability in the mechanical property of pipeline steel, and controlling centerline segregation can meet the requirements of a strain-based design. Mannesmann rating method was used to evaluate the degree of segregation of two slabs and its effect on variability in mechanical properties of corresponding plates. Microstructural characterization indicated that bainite/martensite was formed in a segregated area where the content of C and Mn enriched. The mechanical property results indicated that controlling the degree of centerline segregation can reduce tensile strength variability and improve ductile-brittle transition temperature (DBTT). Full article

Grain structure and macrosegregation are two important aspects to assess the quality of direct chill (DC) cast billets, and the phenomena responsible for their formation are strongly interacted. Transient modeling of grain structure and macrosegregation during DC casting is achieved with a cellular automaton (CA)–finite element (FE) model, by which the macroscopic transport is coupled with microscopic relations for grain growth. In the CAFE model, a two-dimensional (2D) axisymmetric description is used for cylindrical geometry, and a Lagrangian representation is employed for both FE and CA calculations. This model is applied to the DC casting of two industrial scale Al-6.0 wt % Cu round billets with and without grain refiner. The grain structure and macrosegregation under thermal and solutal convection are studied. It is shown that the grain structure is fully equiaxed in the grain-refined billet, while a fine columnar grain region and a coarse columnar grain region are formed in the non-grain-refined billet. With the increasing casting speed, grains become finer and grow in a direction more perpendicular to the axis, and the positive segregation near the centerline becomes more pronounced. The increasing casting temperature makes grains coarser and the negative segregation near the surface more pronounced. Full article

Macrosegregation, serving as a major defect in billets, can severely degrade material homogeneity. Better understanding of the physical characteristics of macrosegregation through numerical simulation could significantly contribute to the segregation control. The main purpose of this study was to predict macrosegregation in continuously cast billets with a newly developed three-dimensional macrosegregation model. The fluid flow, solidification, and solute transport in the entire billet region were solved and analyzed. Flow patterns, revealing a typical melt recirculation at the upper region of mold and thermosolutal convection at the secondary cooling zone, significantly affect the solidification and solute distribution. The solute redistribution occurring with thermosolutal convection at the solidification front contributes significantly to continued macrosegregation as solidification proceeds. The results of this study show that the equilibrium partition coefficient is mostly responsible for the magnitude of macrosegregation, while comparison between solute P and S indicated that diffusion coefficients also have some amount of influence. Typical macrosegregation patterns containing a positively segregated peak at the centerline and negatively segregated minima at either side were obtained via the proposed three-dimensional macrosegregation model, which validated by the measured surface temperatures and segregation degree. Full article