Search Results (8)

The dynamic development of flexible wearable electronics creates new possibilities for the production and use of new types of sensors. Recently, polymer nanocomposites have gained great popularity in the fabrication of sensors. They possess both the mechanical advantages of polymers and the functional properties of nanomaterials. The main drawback of such systems is the complexity of their manufacturing. This article presents, for the first time, fabrication of an antimony sulfoiodide (SbSI) and polyurethane (PU) nanocomposite and its application as a piezoelectric nanogenerator for strain detection. The SbSI/PU nanocomposite was prepared using simple, fast, and efficient technology. It allowed the obtainment of a high amount of material without the need to apply complex chemical methods or material processing. The SbSI/PU nanocomposite exhibited high flexibility and durability. The microstructure and chemical composition of the prepared material were investigated using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS), respectively. These studies revealed a lack of defects in the material structure and relatively low agglomeration of nanowires. The piezoelectric response of SbSI/PU nanocomposite was measured by pressing the sample with a pneumatic actuator at different excitation frequencies. It is proposed that the developed nanocomposite can be introduced into the shoe sole in order to harvest energy from human body movement. Full article

The systematic studies of the extrinsic Maxwell–Wagner–Sillars polarization process in compressed antimony sulfoiodide (SbSI) nanowires are carried out by dielectric spectroscopy. The dielectric response is studied in temperature ($100\le T\le 350$) K and frequency (${10}^{-3}\le f\le {10}^6$) Hz ranges. Dielectric functions commonly used for the analysis of dielectric spectra related to intrinsic polarization processes were applied in the elaboration of experimental data. It was found that the respective “semi-circles” in the Cole–Cole-type plots display a characteristic pear-like shape for the ferroelectric phase. On the other hand, the data for the paraelectric phase form symmetrical arcs. This response is effectively parametrized using the experimental Cole–Davidson and Cole–Cole functions fitted to the data obtained for the ferroelectric and paraelectric phases, respectively. It is deduced that the particular shape of spectra in the ferroelectric phase is due to spontaneous polarization, which is responsible for an asymmetric broadening of relaxation functions related to the interfacial polarization. Full article

For the first time, a composite of ferroelectric antimony sulfoiodide (SbSI) nanowires and non-ferroelectric titanium dioxide (TiO₂) nanoparticles was applied as a pyroelectric nanogenerator. SbSI nanowires were fabricated under ultrasonic treatment. Sonochemical synthesis was performed in the presence of TiO₂ nanoparticles. The mean lateral dimension d_a = 68(2) nm and the length L_a = 2.52(7) µm of the SbSI nanowires were determined. TiO₂ nanoparticles served as binders in the synthesized nanocomposite, which allowed for the preparation of dense films via the simple drop-casting method. The SbSI–TiO₂ nanocomposite film was sandwiched between gold and indium tin oxide (ITO) electrodes. The Curie temperature of T_C = 294(2) K was evaluated and confirmed to be consistent with the data reported in the literature for ferroelectric SbSI. The SbSI–TiO₂ device was subjected to periodic thermal fluctuations. The measured pyroelectric signals were highly correlated with the temperature change waveforms. The magnitude of the pyroelectric current was found to be a linear function of the temperature change rate. The high value of the pyroelectric coefficient p = 264(7) nC/(cm²·K) was determined for the SbSI–TiO₂ nanocomposite. When the rate of temperature change was equal dT/dt = 62.5 mK/s, the maximum and average surface power densities of the SbSI–TiO₂ nanogenerator reached 8.39(2) and 2.57(2) µW/m², respectively. Full article

Antimony sulfoiodide (SbSI) is a ferroelectric semiconductor with many interesting physical properties (optical, photoconductive, ferroelectric, piezoelectric, etc.). The electrical properties of textured polycrystalline SbSI obtained by the rapid cooling of a melted mass in liquid nitrogen are presented in this work using ac impedance spectroscopy over a wide temperature range (275–500 K) in the frequency range of 1 Hz to 100 kHz. Detailed studies of the impedance Z*(ω), conductivity σ*(ω), electric modulus M*(ω), and dielectric permittivity ε*(ω) of this material were performed using complex impedance spectroscopy for the first time. This study showed that the impedance and related parameters are strongly dependent on temperature. The internal domain structure and the presence of grain boundaries in textured polycrystalline SbSI explain the obtained results. Full article

This paper shows a piezoelectric response from an innovative sensor obtained by casting epoxy-SbSI (antimony sulfoiodide) nanowires nanocomposite to a grid structure printed using a fuse deposition modeling (FDM) method. The grid is shown to be a support structure for the nanocomposite. The applied design approach prospectively enables the formation of sensors with a wide spectrum of shapes and a wide applicability. The voltage signal obtained as a result of the piezoelectric effect reached 1.5V and 0.5V under a maximum static stress of 8.5 MPa and under a maximum dynamic stress of 22.3 kPa, respectively. These values are sufficient for potential application in sensor systems. The effect of a systematic increase in the voltage signal with subsequent cycles was also observed, which similarly allows the use of these sensors in monitoring systems for structures exposed to unfavorable cyclical loads. The obtained results also show that the piezoelectric signal improves with increase in strain rate. Full article

Piezocatalysis is a novel method that can be applied for degradation of organic pollutants in wastewater. In this paper, ferroelectric nanowires of antimony sulfoiodide (SbSI) have been fabricated using a sonochemical method. Methyl orange (MO) was chosen as a typical pollutant, as it is widely used as a dye in industry. An aqueous solution of MO at a concentration of 30 mg/L containing SbSI nanowires (6 g/L) was subjected to ultrasonic vibration. High degradation efficiency of 99.5% was achieved after an extremely short period of ultrasonic irradiation (40 s). The large reaction rate constant of 0.126(8) s⁻¹ was determined for piezocatalytic MO decomposition. This rate constant is two orders of magnitude larger than values of reaction rate constants reported in the literature for the most efficient piezocatalysts. These promising experimental results have proved a great potential of SbSI nanowires for their application in environmental purification and renewable energy conversion. Full article

In this paper, ferroelectric antimony sulfoiodide (SbSI) nanowires have been used to produce composites for device fabrication, which can be used for energy harvesting and sensors. SbSI is a very useful material for nanogenerators and nanosensors in which the high values of the piezoelectric coefficient (d₃₃ = 650 pC/N) and the electromechanical coefficient (k₃₃ = 0.9) are essential. Alternatively, cellulose and epoxy resin were matrix materials in these composites, whereas SbSI nanowires fill the matrix. Piezoelectric response induced by vibrations has been presented. Then, a composite with an epoxy resin has been used as an element to construct a fiber-reinforced polymer piezoelectric sensor. For the first time, comparison of piezoelectric properties of cellulose/SbSI and epoxy resin/SbSI nanocomposite has been presented. The influence of concentration of SbSI nanowires for properties of epoxy resin/SbSI nanocomposite and in a fiber-reinforced polymer based on them has also been shown. Results of aligning the SbSI nanowires in the epoxy matrix during a curing process have been presented as well. Full article

A ferroelectric-photovoltaic effect in nanowires of antimony sulfoiodide (SbSI) is presented for the first time. Sonochemically prepared SbSI nanowires have been characterized using high-resolution transmission electron microscopy (HRTEM) and optical diffuse reflection spectroscopy (DRS). The temperature dependences of electrical properties of the fabricated SbSI nanowires have been investigated too. The indirect forbidden energy gap E_gIf = 1.862 (1) eV and Curie temperature T_C = 291 (2) K of SbSI nanowires have been determined. Aligned SbSI nanowires have been deposited in an electric field between Pt electrodes on alumina substrate. The photoelectrical response of such a prepared ferroelectric-photovoltaic (FE-PV) device can be switched using a poling electric field and depends on light intensity. The photovoltage, generated under λ = 488 nm illumination of P_opt = 127 mW/cm² optical power density, has reached U_OC = 0.119 (2) V. The presented SbSI FE-PV device is promising for solar energy harvesting as well as for application in non-volatile memories based on the photovoltaic effect. Full article