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Keywords = anodic dehydrogenative homocoupling

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7 pages, 1871 KB  
Communication
Electrochemical Synthesis of 1,1′-Binaphthalene-2,2′-Diamines via Transition-Metal-Free Oxidative Homocoupling
by Duona Fan, Md. Imrul Khalid, Ganesh Tatya Kamble, Hiroaki Sasai and Shinobu Takizawa
Sustain. Chem. 2022, 3(4), 551-557; https://doi.org/10.3390/suschem3040034 - 4 Dec 2022
Cited by 5 | Viewed by 7705
Abstract
The facile and green synthesis of 1,1′-binaphthalene-2,2′-diamine (BINAM) derivatives was established via the anodic dehydrogenative homo-coupling of 2-naphthylamines. The sustainable protocol provided a series of BINAMs in excellent yields of up to 98% with good current efficiency (66%) and H2 as the [...] Read more.
The facile and green synthesis of 1,1′-binaphthalene-2,2′-diamine (BINAM) derivatives was established via the anodic dehydrogenative homo-coupling of 2-naphthylamines. The sustainable protocol provided a series of BINAMs in excellent yields of up to 98% with good current efficiency (66%) and H2 as the sole coproduct without utilizing transition-metal reagents or stoichiometric oxidants. Full article
(This article belongs to the Topic Green and Sustainable Chemistry)
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