Search Results (8)

This study presented a detailed investigation into the performance of a plate–frame water gap membrane distillation (WGMD) system for the desalination of untreated real seawater. One approach to improving the performance of WGMD is through the proper selection of cooling plate material, which plays a vital role in enhancing the gap vapor condensation process. Hence, the influence of different cooling plate materials was examined and discussed. Furthermore, two different hydrophobic micro-porous polymeric membranes of similar mean pore sizes were utilized in the study. The influence of key operating parameters, including the feed water temperature and flow rate, was examined against the system vapor flux and gained output ratio (GOR). In addition, the used membranes were characterized by means of different techniques in terms of surface morphology, liquid entry pressure, water contact angle, pore size distribution, and porosity. Findings revealed that, at all conditions, the PTFE membrane exhibits superior vapor flux and energy efficiency (GOR), with 9.36% to 14.36% higher flux at a 0.6 to 1.2 L/min feed flow rate when compared to the PVDF membrane. The copper plate, which has the highest thermal conductivity, attained the highest vapor flux, while the acrylic plate, which has an extra-low thermal conductivity, recorded the lowest vapor flux. The increasing order of GOR values for different cooling plates is acrylic < HDPE < copper < aluminum < brass < stainless steel. Results also indicated that increasing the feed temperature increases the vapor flux almost exponentially to a maximum flux value of 30.36 kg/m²hr. The system GOR also improves in a decreasing pattern to a maximum value of 0.4049. Moreover, a long-term test showed that the PTFE membrane, which exhibits superior hydrophobicity, registered better salt rejection stability. The use of copper as a cooling plate material for better system performance is recommended, while cooling plate materials with very low thermal conductivities, such as a low thermally conducting polymer, are discouraged. Full article

The escalating demand for the cost-effective synthesis of valuable fine chemicals has fueled the search for sustainable heterogeneous catalysts. Among these catalytic reactions, Knoevenagel condensation has emerged as a very demanding reaction due to its involvement in the synthesis of new C–C bond formation. Porous metal phosphates have attracted significant attention in catalysis due to their unique surface properties. In this study, we report the synthesis of a novel porous magnesium aluminum phosphate (MALPO) material through a hydrothermal template-free approach. MALPO exhibited very promising specific surface area and hierarchical porosity. Moreover, the plate-like morphology of the material can enhance the exposure of the catalytic sites located at the surfaces, leading to enhanced catalytic activity. MALPO demonstrated excellent catalytic performance, yielding a series of Knoevenagel products with up to 99% yield. Notably, the catalyst displayed remarkable recyclability, retaining its structural integrity throughout multiple reaction cycles. The findings highlight the potential of porous mixed-metal phosphates, exemplified by MALPO, as sustainable and efficient base catalyst for the synthesis of value-added chemicals, contributing to the growing demand of the chemical industry. Further investigations are warranted to explore their catalytic potential in diverse chemical transformations and optimize their performance for large-scale operations. Full article

The associated effect of sodium chloride and dihydrate gypsum on the mechanical performance of a slag-based geopolymer activated by quicklime was investigated by compressive strength, shrinkage, and square circle anti-cracking tests of mortar with a 0.5 water–binder ratio and a 1:3 binder–sand ratio, as well as paste soundness, powder X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), and mercury intrusion porosimetry (MIP) of the paste. The results indicate that (1) when dihydrate gypsum is used alone, it combines with calcium aluminate hydrate (C-A-H) to form calcium sulfoaluminate hydrate (AFt), which encourages the hydration process of slag. A 7.5% addition can result in an increase of 97.33% and 36.92% in 3-day and 28-day compressive strengths, respectively. When NaCl is used by itself, it facilitates the condensation of the aluminum silicate tetrahedron unit and generates zeolite. A 2% dosage can lead to a 66.67% increase in the 3-day compressive strength, while causing a 15.89% reduction in the 28-day compressive strength. (2) The combined effect of 2% NaCl and 7.5% gypsum results in the formation of needle-like and rod-shaped AFt, Friedel’s salt, and plate-like Kuzel’s salt in the geopolymer. This leads to an increase in 3-day and 28-day compressive strengths by 148% and 37.85%, respectively. Furthermore, it reduces the porosity by 18.7%. (3) Both NaCl and gypsum enhance the paste soundness of the slag-based geopolymer, and they do no harm to the crack resistance of the geopolymer. The drying shrinkage of the geopolymer at 28 days is just 0.48 × 10⁻³, which is only 66.7% of OPC. This slag-based geopolymer has a simple preparation process, good volume stability, low raw material cost, low energy consumption, and low carbon emissions. It can be used instead of 32.5 slag Portland cement in plain concrete applications, and has high engineering, economic, and environmental values. Full article

The low freshwater productivity of a conventional solar still is considered a challenge for researchers due to the high temperature of the glass cover or basin water depth. In current work, a newly designed solar still was suggested according to the climatic conditions of Yekaterinburg/Russia, which included an enhanced condensation and evaporation process by spraying a thin water film on a hot absorber plate and then passing the generated water vapor by free convection over the aluminum plate (low temperature). The distillation system under study was tested during July 2020 and 29 July was chosen as a typical day from 08:00 a.m. to 8:00 p.m. The results showed that the largest amount of water vapor condenses on the aluminum plate (about 46%), and the rest condenses on the glass cover. This means that the aluminum plate effectively improved productivity due to the flow of humid air naturally (free convection) on the aluminum plate (its surface temperature was lower than that of the glass cover). The cost analytical calculations showed that the cost of producing one liter of distilled water from the suggested solar still was 0.063$. Full article

Aiming at the problem of end structure heating caused by the excessive eddy current loss of large synchronous condensers used in ultra-high voltage (UHV) power transmission, combined with the actual operation characteristics of the synchronous condenser, a three-dimensional transient electromagnetic field physical model is established, and three schemes for adjusting the end structure of the condenser under rated condition are researched. The original structure has a copper shield and a steel clamping plate. Scheme 1 has no copper shield but has a steel clamping plate. Scheme 2 has no copper shield but has an aluminum clamping plate. By constructing a three-dimensional fluid–solid coupling heat transfer model in the end of the synchronous condenser, and giving the basic assumptions and boundary conditions, the eddy current loss of the structure calculated by the three schemes is applied to the end region of the synchronous condenser as the heat source, and the velocity distribution of the cooling medium and the temperature distribution of each structure under the three different schemes are obtained. In order to verify the rationality of the numerical analysis model and the effectiveness of the calculation method, the temperature of the inner edge of the copper shield in the end of the synchronous condenser is measured, and the temperature calculation results are consistent with the temperature measurement results, which provides a theoretical basis for the electromagnetic design, structural optimization, ventilation and cooling of the synchronous condenser. Full article

The present study reports the experimental results of a parabolic trough collector field and an absorption cooling system with a nominal capacity of 5 kW, which operates with the ammonia-lithium nitrate mixture. The parabolic trough collectors’ field consists of 15 collectors that are made of aluminum plate in the reflector surface and cooper in the absorber tube, with a total area of 38.4 m². The absorption cooling system consists of 5 plate heat exchangers working as the main components. Parametric analyses were carried out to evaluate the performance of both systems under different operating conditions, in independent way. The results showed that the solar collectors’ field can provide up to 6.5 kW of useful heat to the absorption cooling system at temperatures up to 105 °C with thermal efficiencies up to 19.8% and exergy efficiencies up to 14.93, while the cooling system operated at generation temperatures from 85–95 °C and condensation temperatures between 20 and 28 °C, achieving external coefficients of performance up to 0.56, cooling temperatures as low as 6 °C, and exergy efficiencies up to 0.13. The highest value for the solar coefficient of performance reached 0.07. Full article

In order to solve the frosting and blockage problem of an air conditioning evaporator’s fin in winter, the nanoporous aluminum plates with low surface energy has been proposed in this paper, which are fabricated by an anodizing method and then modified by lauric acid. The nanoporous aluminum plates with different nanoporous diameters ranging from 15 nm to 400 nm are obtained by changing the magnitude of the oxidation current. The surface contact angle of the nanoporous aluminum plates is an important factor influencing its surface frost and condensation. The test results show that the surface contact angle is decreased with the increasing of nanoporous diameter. When the nanoporous aluminum plates are modified by lauric acid, the contact angle is proportional to the nanoporous diameter, and the maximum contact angle can reach about 171°. A set of experimental instruments has been set up to simulate the typical winter climate in northern China, and the frosting properties of the nanoporous aluminum plate’s fin is analyzed by experiment. The results show that increasing the contact angle of aluminum plates can effectively improve its anti-frosting properties. The average frosting rate of the aluminum plate with the contact angle of 60° is about 0.33 [g/(min∙m²)], which is 1.74 times that of the aluminum plate with the contact angle of 171°, whose frosting rate is about 0.19 [g/(min∙m²)]. After taking the expanded aperture processing to the aluminum plate, the diameter with 30 nm, 100 nm, 200 nm, 300 nm, and 400 nm nanoporous aluminum plates are obtained and the polished aluminum plates are also prepared for comparing. Through the test results, the nanoporous aluminum plates are shown to have anti-frosting properties, and the nanoporous aluminum plates with diameter of 300 nm are shown to have the best anti-frosting properties. The calculation mode of frosting growth is derived on the base of experimental results. This research will be helpful in indicating the potential research area of the low-carbon-emission and energy-saving technology for the researchers all over the world. Full article

In this paper we proposed the novel air-conditioning system which combined induction ventilation and radiant air-conditioning. The indoor terminal device is the radiant induction-unit (RIDU). The RIDU is the induction unit combined with the pore radiant panel on which the copper pipes with rigid aluminum diffusion fins are installed. The two-stage evaporator chiller with the non-azeotropic mixture refrigerant is utilized in the system to reduce the initial investment in equipment. With the performance test and the steady state heat transfer model based on the theory of radiative heat transfer, the relationship between the induction ratio of the RIDU and the characteristic of the air supply was studied. Based on this, it is verified that the RIDU has a lower dew-point temperature and better anti-condensation performance than a traditional plate-type radiant panel. The characteristics of the radiation and convection heat transfer of the RIDU were studied. The total heat exchange of the RIDU can be 16.5% greater than that of the traditional plate-type radiant terminal. Full article