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22 pages, 63497 KiB  
Article
From Earth to Interface: Towards a 3D Semantic Virtual Stratigraphy of the Funerary Ara of Ofilius Ianuarius from the Via Appia Antica 39 Burial Complex
by Matteo Lombardi and Rachele Dubbini
Heritage 2025, 8(8), 305; https://doi.org/10.3390/heritage8080305 - 30 Jul 2025
Viewed by 191
Abstract
This paper presents the integrated study of the funerary ara of Ofilius Ianuarius, discovered within the burial complex of Via Appia Antica 39, and explores its digital stratigraphic recontextualisation through two 3D semantic workflows. The research aims to evaluate the potential of [...] Read more.
This paper presents the integrated study of the funerary ara of Ofilius Ianuarius, discovered within the burial complex of Via Appia Antica 39, and explores its digital stratigraphic recontextualisation through two 3D semantic workflows. The research aims to evaluate the potential of stratigraphic 3D modelling as a tool for post-excavation analysis and transparent archaeological interpretation. Starting from a set of georeferenced photogrammetric models acquired between 2023 and 2025, the study tests two workflows: (1) an EMF-based approach using the Extended Matrix, Blender, and EMviq for stratigraphic relationship modelling and online visualisation; (2) a semantic integration method using the .gltf format and the CRMArcheo Annotation Tool developed in Blender, exported to the ATON platform. While both workflows enable accurate 3D documentation, they differ in their capacity for structured semantic enrichment and interoperability. The results highlight the value of combining reality-based models with semantically linked stratigraphic proxies and suggest future directions for linking archaeological datasets, ontologies, and interactive digital platforms. This work contributes to the ongoing effort to foster transparency, reproducibility, and accessibility in virtual archaeological reconstruction. Full article
(This article belongs to the Section Digital Heritage)
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17 pages, 2979 KiB  
Article
Discussion on the Design of Sprayed Eco-Protection for Near-Slope Roads Along Multi-Level Slopes
by Haonan Chen and Jianjun Ye
Appl. Sci. 2025, 15(15), 8408; https://doi.org/10.3390/app15158408 - 29 Jul 2025
Viewed by 129
Abstract
This study proposes a design method for near-slope roads along multi-level slopes that integrates excavation requirements and post-construction ecological restoration through sprayed eco-protection. Firstly, the design principles and procedural steps for near-slope roads are established. The planar layouts of multi-level slopes are categorized, [...] Read more.
This study proposes a design method for near-slope roads along multi-level slopes that integrates excavation requirements and post-construction ecological restoration through sprayed eco-protection. Firstly, the design principles and procedural steps for near-slope roads are established. The planar layouts of multi-level slopes are categorized, including mixing areas, turnaround areas, berms, and access ramps. Critical technical parameters, such as curve radii and widths of berms and ramps, as well as dimensional specifications for turnaround areas, are systematically formulated with corresponding design formulas. The methodology is applied to the ecological restoration project of multi-level slopes in the Huamahu mountainous area, and a comparative technical-economic analysis is conducted between the proposed design and the original scheme. Results demonstrate that the optimized design reduces additional maintenance costs caused by near-slope roads by 6.5–8.0% during the curing period. This research advances the technical framework for multi-level slope governance and enhances the ecological design standards for slope protection engineering. Full article
(This article belongs to the Section Earth Sciences)
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17 pages, 5238 KiB  
Article
Study on Reinforcement Technology of Shield Tunnel End and Ground Deformation Law in Shallow Buried Silt Stratum
by Jia Zhang and Xiankai Bao
Appl. Sci. 2025, 15(14), 7657; https://doi.org/10.3390/app15147657 - 8 Jul 2025
Viewed by 323
Abstract
With the rapid advancement of urban underground space development, shield tunnel construction has seen a significant increase. However, at the initial launching stage of shield tunnels in shallow-buried weak strata, engineering risks such as face instability and sudden surface settlement frequently occur. At [...] Read more.
With the rapid advancement of urban underground space development, shield tunnel construction has seen a significant increase. However, at the initial launching stage of shield tunnels in shallow-buried weak strata, engineering risks such as face instability and sudden surface settlement frequently occur. At present, there are relatively few studies on the reinforcement technology of the initial section of shield tunnel in shallow soft ground and the evolution law of ground disturbance. This study takes the launching section of the Guanggang New City depot access tunnel on Guangzhou Metro Line 10 as the engineering background. By applying MIDAS/GTS numerical simulation, settlement monitoring, and theoretical analysis, the reinforcement technology at the tunnel face, the spatiotemporal evolution of ground settlement, and the mechanism of soil disturbance transmission during the launching process in muddy soil layer are revealed. The results show that: (1) the reinforcement scheme combining replacement filling, high-pressure jet grouting piles, and soil overburden counterpressure significantly improves surface settlement control. The primary influence zone is concentrated directly above the shield machine and in the forward excavation area. (2) When the shield machine reaches the junction between the reinforced and unreinforced zones, a large settlement area forms, with the maximum ground settlement reaching −26.94 mm. During excavation in the unreinforced zone, ground deformation mainly occurs beneath the rear reinforced section, with subsidence at the crown and uplift at the invert. (3) The transverse settlement trough exhibits a typical Gaussian distribution and the discrepancy between the measured maximum settlement and the numerical and theoretical values is only 3.33% and 1.76%, respectively. (4) The longitudinal settlement follows a trend of initial increase, subsequent decrease, and gradual stabilization, reaching a maximum when the excavation passes directly beneath the monitoring point. The findings can provide theoretical reference and engineering guidance for similar projects. Full article
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36 pages, 3756 KiB  
Article
The IoT/IoE Integrated Security & Safety System of Pompeii Archeological Park
by Alberto Bruni and Fabio Garzia
Appl. Sci. 2025, 15(13), 7359; https://doi.org/10.3390/app15137359 - 30 Jun 2025
Viewed by 356
Abstract
Pompeii is widely known for its tragic past. In 79 A.D., a massive eruption of Mount Vesuvius buried the city and its inhabitants under volcanic ash. Lost for centuries, it was rediscovered in 1748 when the Bourbon monarchs initiated excavations, marking the beginning [...] Read more.
Pompeii is widely known for its tragic past. In 79 A.D., a massive eruption of Mount Vesuvius buried the city and its inhabitants under volcanic ash. Lost for centuries, it was rediscovered in 1748 when the Bourbon monarchs initiated excavations, marking the beginning of systematic digs. Since then, Pompeii has gained worldwide recognition for its archeological wonders. Despite centuries of looting and damage, it remains a breathtaking site. With millions of visitors annually, the Pompeii Archeological Park is the one most visited site in Italy. Managing such a vast and complex heritage site requires significant effort to ensure both visitor safety and the preservation of its fragile structures. Accessibility is also crucial, particularly for individuals with disabilities and staff responsible for site management. To address these challenges, integrated systems and advanced technologies like the Internet of Things/Everything (IoT/IoE) can provide innovative solutions. These technologies connect people, smart devices (such as mobile terminals, sensors, and wearables), and data to optimize security, safety, and site management. This paper presents a security/safety IoT/IoE-based system for security, safety, management, and visitor services at the Pompeii Archeological Park. Full article
(This article belongs to the Special Issue Advanced Technologies Applied to Cultural Heritage)
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11 pages, 554 KiB  
Article
Exploring the Antimicrobial and Clinical Efficacy of a Novel Technology in Pediatric Endodontics: An In Vivo Study
by Luca De Gregoriis, Tatiane Cristina Dotta, Morena Petrini, Silvia Di Lodovico, Loredana D’Ercole, Simonetta D’Ercole and Domenico Tripodi
Appl. Sci. 2025, 15(12), 6491; https://doi.org/10.3390/app15126491 - 9 Jun 2025
Viewed by 450
Abstract
Pediatric dentistry continually seeks effective and efficient treatments for young patients, especially within pediatric endodontics, where cooperation can often be challenging. This in vivo study aimed to evaluate the effectiveness of a novel photodynamic therapy (PDT) protocol using a 5-aminolevulinic acid gel (Aladent, [...] Read more.
Pediatric dentistry continually seeks effective and efficient treatments for young patients, especially within pediatric endodontics, where cooperation can often be challenging. This in vivo study aimed to evaluate the effectiveness of a novel photodynamic therapy (PDT) protocol using a 5-aminolevulinic acid gel (Aladent, ALAD) combined with light irradiation during the endodontic treatment of primary teeth. This study included primary teeth requiring root canal therapy due to carious lesions or trauma, with clinical symptoms suggesting irreversible pulpitis or acute apical periodontitis. Following local anesthesia and isolation with a rubber dam, carious lesions were excavated, and access to the pulp chamber was established. Canal preparation included determining the working length and using a sequence of k-files. Afterward, ALAD gel was applied, and the patients were divided into two groups based on their visit duration (Group A with a single visit, Group B returning after one week). Microbiological analysis was conducted on the samples taken before and after treatment. The findings demonstrated significant antibacterial efficacy of the PDT protocol in reducing root canal bacterial load, suggesting ALAD-based PDT may serve as an alternative to traditional endodontic treatment in cases where retaining primary teeth is essential for orthodontic or strategic reasons. Clinically, improvement in symptoms and fistula resolution were observed. Treatment time, patient compliance, and protocol safety in pediatric applications are also discussed, highlighting the protocol’s potential to enhance clinical outcomes in pediatric endodontics. Full article
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45 pages, 7008 KiB  
Article
A Comprehensive Review of Open Caisson Modeling Technology: Current Practices and Future Prospects
by Jianxiu Wang, Naveed Sarwar Abbasi, Weqiang Pan, Weifeng Wu, Sharif Nyanzi Alidekyi, Xiaofei Zhang, Panfeng Guan, Hao Li, Ali Asghar and Bilal Ahmed
Appl. Sci. 2025, 15(11), 6029; https://doi.org/10.3390/app15116029 - 27 May 2025
Viewed by 865
Abstract
The rapid advancement of modern megapolises has led to a dearth of surface space, and, in response, engineers have begun to trial substitutes below ground level. Shafts are generally used to provide temporary access and permanent work to the subsurface for tunnelling, as [...] Read more.
The rapid advancement of modern megapolises has led to a dearth of surface space, and, in response, engineers have begun to trial substitutes below ground level. Shafts are generally used to provide temporary access and permanent work to the subsurface for tunnelling, as well as for lifts or ventilation purposes. In urban areas, one important design issue is the prediction of the excavation-induced displacements by open caisson shaft construction. Settlements and ground movements associated with open caisson shafts are influenced by the choice of construction method, soil composition, and excavation geometry. Compared with other geotechnical construction events, for instance, tunnelling, the literature relating to the ground deformations induced from open caisson shafts are comparatively limited. This review offers an evaluation of several case studies that utilize experimental and computational modeling techniques to provide clearer insights into earth pressure distribution and induced surface and subsurface soil displacements, as well as the associated ground deformations during open caisson shaft construction. The modeling test results are compared to the state of the practice ground deformation prediction theories and measured results from field monitoring data. Findings indicate that the lateral earth pressure distribution aligns closely with the theoretical predictions based on Terzaghi’s and Berezantzev’s models, and lateral earth pressure diminishes gradually until the onset of active wall displacement. Current modeling techniques generally fail to properly represent in situ stress states and large-scale complexities, emphasizing the need for hybrid approaches that combine physical and numerical methodologies. In future studies, modern approaches, including artificial intelligence (AI) monitoring (e.g., PINNs, ACPP), multi-field coupling models (e.g., THMC), and transparent soil testing, hold profound potential for real-time prediction, optimization, and visualization of soil deformation. Numerical–physical coupling tests will integrate theory and practice. Improving prediction reliability in complicated soil conditions such as composite and heterogenous strata using different modeling techniques is still unclear, and further investigation is therefore needed. Full article
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28 pages, 7413 KiB  
Article
Spatial Analysis of the Functional Andean Worldview of the Archaeological Site of Ankasmarka, Cusco—Peru 2024
by Doris Esenarro, Jimena Ccalla, Guisela Yabar, Cecilia Uribe, Mario Reyes, Mirko De los Santos, Geoffrey Salas and Javier Condori
Quaternary 2025, 8(2), 27; https://doi.org/10.3390/quat8020027 - 16 May 2025
Viewed by 993
Abstract
The objective of this research is to conduct a spatial analysis of the functional Andean worldview of the Ankasmarka Archaeological Site, located in Calca, Peru. The preservation of cultural heritage in Latin America faces significant challenges that threaten the integrity of key sites [...] Read more.
The objective of this research is to conduct a spatial analysis of the functional Andean worldview of the Ankasmarka Archaeological Site, located in Calca, Peru. The preservation of cultural heritage in Latin America faces significant challenges that threaten the integrity of key sites such as Ankasmarka. Despite its historical relevance, this site lacks available open access information and data, collected in accessible reports, which hinders the attraction of attention and funding necessary for its conservation. Furthermore, urbanization and uncontrolled tourism negatively impact both cultural traditions and the connection of local communities with their past. The methodology employed is based on a systematic review of primary information, supplemented by excavation reports and official sources. Specialized software such as AutoCAD Architecture and Revit were used to carry out the topographic and architectural survey of the site, enabling the precise and rigorous interpretation of the data. This article focuses on the spatial and functional description of the site, with the aim of paving the way for future research in specific areas such as formal and structural analysis, as well as social and political dynamics. The results reveal a complex organizational structure at Ankasmarka, with enclosures designated for various functions, particularly storage and agricultural activities. The site is divided into three sectors: Sector A, which includes housing, storage areas, and tombs; and Sector B and C, with the highest concentration of housing and agricultural zones with storage areas, respectively. The findings underscore the interrelationship between agriculture, funerary practices, and architecture, highlighting the importance of Ankasmarka in the lives of its ancient inhabitants and the need for continued future research. Full article
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13 pages, 3737 KiB  
Article
Digitalisation and Building Information Modelling Integration of Basement Construction Using Unmanned Aerial Vehicle Photogrammetry in Urban Singapore
by Siau Chen Chian, Jieyu Yang, Suyi Wong, Ker-Wei Yeoh and Ahmad Tashrif Bin Sarman
Buildings 2025, 15(7), 1023; https://doi.org/10.3390/buildings15071023 - 23 Mar 2025
Cited by 1 | Viewed by 454
Abstract
With advancement in Unmanned Aerial Vehicle (UAV) photogrammetry, productivity in construction management can now be achieved with accuracy and is less labour-intensive. In the basement construction of buildings, prudent earthwork activities are often necessary, setting the basis of the building footprint. As such, [...] Read more.
With advancement in Unmanned Aerial Vehicle (UAV) photogrammetry, productivity in construction management can now be achieved with accuracy and is less labour-intensive. In the basement construction of buildings, prudent earthwork activities are often necessary, setting the basis of the building footprint. As such, monitoring earthwork volume estimation becomes important to avoid over- or under-cutting the earth. Conventional methods by means of land surveying are time-consuming, labour-intensive, and susceptible to varying degrees of accuracy. Moreover, earthwork sites often have multiple activities ongoing that increase the complexity of volume estimation through land surveying. This study explores the use of UAV photogrammetry to estimate earthwork excavation volume in a complex urban earthwork site in Singapore over time and discusses the feasibility, challenges and productivity enhancements of integrating the technology into the construction process. In this study, the earthwork site and controlled trials show that the models reconstructed with UAV photogrammetry data can produce volume measurements that fulfil the stakeholder’s accuracy tolerance of 5% between the estimated and actual volume. The filtering of unwanted objects in the model, such as columns, cranes and trucks, was successful but was insufficient for objects that occluded large areas of the soil surface. The integration of UAV photogrammetry with a highly automated acquisition and processing workflow for earthwork monitoring brings about productivity enhancements in time and labour efforts and improves the efficiency and consistency of models. Furthermore, the digitalisation of earthwork sites into point clouds and three-dimensional (3D) models increases data visualisation and accessibility, facilitates project team collaboration, and enables cross-platform compatibility into Building Information Modelling (BIM), which can significantly aid in reporting and decision-making processes. Full article
(This article belongs to the Section Construction Management, and Computers & Digitization)
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33 pages, 66884 KiB  
Article
Automated Design and Parametric Modeling of Excavator Buckets
by Nikolay Stankov and Aleksandar Ivanov
Appl. Sci. 2025, 15(6), 3389; https://doi.org/10.3390/app15063389 - 20 Mar 2025
Cited by 1 | Viewed by 1122
Abstract
This paper presents the process of automated designing and parametric modeling of excavator buckets using the CAD system. A methodology has been developed that covers all stages of design, from the creation of 3D models of the parts, sub-assemblies, and assemblies to the [...] Read more.
This paper presents the process of automated designing and parametric modeling of excavator buckets using the CAD system. A methodology has been developed that covers all stages of design, from the creation of 3D models of the parts, sub-assemblies, and assemblies to the generation of design documentation, using template files. The presented approach allows the creation of parametric models with multiple configurations, which cover different variants of the products according to their technical characteristics and purpose. This paper describes in detail the technological process, including the manufacture of parts and the assembling of sub-assemblies, in accordance with modern production requirements. Bucket classification according to excavator operating weight is included. Parametric modeling of the main components, such as the base and upper part of the bucket, is also described. In addition, an algorithm for automation of design documentation has been developed that integrates PDM systems for engineering data management. Using the presented methodology leads to a reduction in the volume of created documentation and optimizes the design process, providing the opportunity for rapid adaptation to various client requirements. Data management within a PDM system ensures centralized storage, actuality, and accessibility of information, which contribute to more efficient production and management of product data. Full article
(This article belongs to the Special Issue Computer-Aided Design in Mechanical Engineering)
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23 pages, 8259 KiB  
Article
Study on the Design and Construction Methods of Auxiliary Workings for the Deepening of Shaft II in the Borynia Mine
by Paweł Kamiński, Aleksandra Otto, Piotr Dawidziuk, Artur Dyczko and Dariusz Prostański
Appl. Sci. 2025, 15(6), 3131; https://doi.org/10.3390/app15063131 - 13 Mar 2025
Viewed by 630
Abstract
This study explores the design and construction methods for auxiliary workings for the deepening of Shaft II at the Borynia Mine. The shaft, an essential intake structure for personnel and material transport, is being extended from 980 m to 1150 m to provide [...] Read more.
This study explores the design and construction methods for auxiliary workings for the deepening of Shaft II at the Borynia Mine. The shaft, an essential intake structure for personnel and material transport, is being extended from 980 m to 1150 m to provide access to a new mining level at 1120 m. Given the challenging geological and operational conditions, a top-to-bottom deepening method was adopted, with excavation from a sub-level accessed via an auxiliary incline. The study details the planning and implementation of key auxiliary workings, including hoisting machine chamber and technological shaft inset. A comprehensive geotechnical analysis was conducted to assess rock mass properties, classify geological formations, and estimate mechanical parameters affecting excavation stability. The support system design was carried out using both analytical and numerical methods, ensuring safe and efficient construction. The applied primary and secondary support structures have successfully maintained excavation stability. The findings demonstrate the reliability of the adopted engineering solutions and their applicability in deep mining environments. Full article
(This article belongs to the Special Issue Advances in Tunnel and Underground Construction)
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21 pages, 4796 KiB  
Article
Prediction and Control of Existing High-Speed Railway Tunnel Deformation Induced by Shield Undercrossing Based on BO-XGboost
by Ruizhen Fei, Hongtao Wu and Limin Peng
Sustainability 2024, 16(23), 10563; https://doi.org/10.3390/su162310563 - 2 Dec 2024
Cited by 1 | Viewed by 1233
Abstract
The settlement of existing high-speed railway tunnels due to adjacent excavations is a complex phenomenon influenced by multiple factors, making accurate estimation challenging. To address this issue, a prediction model combining extreme gradient boosting (XGBoost) with Bayesian optimization (BO), namely BO-XGBoost, was developed. [...] Read more.
The settlement of existing high-speed railway tunnels due to adjacent excavations is a complex phenomenon influenced by multiple factors, making accurate estimation challenging. To address this issue, a prediction model combining extreme gradient boosting (XGBoost) with Bayesian optimization (BO), namely BO-XGBoost, was developed. Its predictive performance was evaluated against conventional models, such as artificial neural networks (ANNs), support vector machines (SVMs), and vanilla XGBoost. The BO-XGBoost model showed superior results, with evaluation metrics of MAE = 0.331, RMSE = 0.595, and R2 = 0.997. In addition, the BO-XGBoost model enhanced interpretability through an accessible analysis of feature importance, identifying volume loss as the most critical factor affecting settlement predictions. Using the prediction model and a particle swarm optimization (PSO) algorithm, a hybrid framework was established to adjust the operational parameters of a shield tunneling machine in the Changsha Metro Line 3 project. This framework facilitates the timely optimization of operational parameters and the implementation of protective measures to mitigate excessive settlement. With this framework’s assistance, the maximum settlements of the existing tunnel in all typical sections were strictly controlled within safety criteria. As a result, the corresponding environmental impact was minimized and resource management was optimized, ensuring construction safety, operational efficiency, and long-term sustainability. Full article
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13 pages, 5421 KiB  
Article
Sustainability of Discontinuously Supported Slopes in Temporary Shallow Excavations for Building Construction: A Stability Analysis Procedure
by Miguel A. Millán, David Mencías-Carrizosa and Alejandro Calle
Sustainability 2024, 16(23), 10393; https://doi.org/10.3390/su162310393 - 27 Nov 2024
Viewed by 1029
Abstract
Sustainable building construction requires a design process that ensures long-term structural durability and minimizes risks of failure or damage during construction and throughout the structure’s service life. One critical aspect of this process is the excavation of simple basements, which often requires discontinuously [...] Read more.
Sustainable building construction requires a design process that ensures long-term structural durability and minimizes risks of failure or damage during construction and throughout the structure’s service life. One critical aspect of this process is the excavation of simple basements, which often requires discontinuously supported excavation (shielding) when soil stability is compromised, or nearby buildings or infrastructure are at risk. Despite the apparent simplicity of this technique, the lack of a standardized procedure to verify the safety of excavated slopes frequently leads to accidents and damage to adjacent structures. This research introduces a methodology for assessing the safety of discontinuously supported excavations. The proposed method involves a series of calculations based on the Finite Element Method (FEM) to develop a stability chart. Currently, no established approach exists to address this complex three-dimensional problem. The models used are characterized by the slope height and the width between supports. The soil is modeled as elastoplastic, following the Mohr–Coulomb failure criterion, with parameters including the friction angle and the cohesive strength. A comprehensive set of simulations is conducted for various heights, widths, and friction angles to determine the minimum cohesive strength required to achieve a specific safety factor. All results are appropriately non-dimensionalized to generate stability charts, which provide an accessible tool for assessing the stability of discontinuously supported slope configurations with a given width between shields. Full article
(This article belongs to the Special Issue Research Advances in Sustainable Materials and Structural Engineering)
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13 pages, 1945 KiB  
Article
A Combination of Traditional and Mechanized Logging for Protected Areas
by Natascia Magagnotti, Benno Eberhard and Raffaele Spinelli
Forests 2024, 15(11), 2021; https://doi.org/10.3390/f15112021 - 16 Nov 2024
Viewed by 796
Abstract
Teaming draught animals with modern forest machines may offer an innovative low-impact solution to biomass harvesting in protected areas. Machine traffic only occurs on pre-designated access corridors set 50 m apart, while trees are cut with chainsaws and dragged to the corridor’s edge [...] Read more.
Teaming draught animals with modern forest machines may offer an innovative low-impact solution to biomass harvesting in protected areas. Machine traffic only occurs on pre-designated access corridors set 50 m apart, while trees are cut with chainsaws and dragged to the corridor’s edge by draught horses. The operation presented in this study included one chainsaw operator, two draught horses with their driver, an excavator-based processor with its driver and a helper equipped with a chainsaw for knocking off forks and large branches, and a light forwarder (7 t) with his driver. Researchers assessed work productivity and harvesting cost through a time study repeated on 20 sample plots. Descriptive statistics were used to estimate productivity and cost benchmark figures, which were matched against the existing references for the traditional alternatives. The new system achieved a productivity in excess of 4 m3 over bark per scheduled hour (including delays). Harvesting cost averaged EUR 53 m−3, which was between 15% and 30% cheaper than the traditional alternatives. What is more, the new system increased labor and horse productivity by a factor of 2 and 7, respectively, which can effectively counteract the increasingly severe shortage of men and animals. Full article
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13 pages, 4395 KiB  
Article
NBS-Mediated C(sp2)-H Bond Chlorination of Enaminones: Using DCE as Chlorine Source
by Menglin Peng, Yunhua Xie, Siyu Song, Zhilai Zhang, Yuanzheng Wei, Huimin Hu, Yongchao Wang and Fuchao Yu
Int. J. Mol. Sci. 2024, 25(22), 12073; https://doi.org/10.3390/ijms252212073 - 10 Nov 2024
Viewed by 1136
Abstract
Commercial DCE is excavated as both a “Cl” source and a solvent for the vinyl C(sp2)-H chlorination. The strategy involves a metal-free NBS-mediated C(sp2)-H chlorination of enaminones, and affords diverse, functionalized α-chlorinated enaminones with a Z-configuration. This [...] Read more.
Commercial DCE is excavated as both a “Cl” source and a solvent for the vinyl C(sp2)-H chlorination. The strategy involves a metal-free NBS-mediated C(sp2)-H chlorination of enaminones, and affords diverse, functionalized α-chlorinated enaminones with a Z-configuration. This mild and effective approach not only advances the vinyl C(sp2)-H chlorination, employing DCE as the “Cl” source, but also provides a new strategy for accessing chlorinated enaminone derivatives. Full article
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27 pages, 9077 KiB  
Article
Investigating the Spatial Patterns of Heavy Metals in Topsoil and Asthma in the Western Salt Lake Valley, Utah
by Long Yin Lee, Ruth Kerry, Ben Ingram, Connor S. Golden and Joshua J. LeMonte
Environments 2024, 11(10), 223; https://doi.org/10.3390/environments11100223 - 13 Oct 2024
Viewed by 2083
Abstract
Mining activities, particularly in large excavations like the Bingham Canyon Copper Mine in Utah, have been increasingly linked to respiratory conditions due to heavy-metal-enriched waste and dust. Operating continuously since 1906, the Bingham Canyon Copper Mine contributes 4.4% of the Salt Lake Valley [...] Read more.
Mining activities, particularly in large excavations like the Bingham Canyon Copper Mine in Utah, have been increasingly linked to respiratory conditions due to heavy-metal-enriched waste and dust. Operating continuously since 1906, the Bingham Canyon Copper Mine contributes 4.4% of the Salt Lake Valley PM2.5 pollution. However, the extent of its contributions to larger-sized particulate matter (PM10) dust, soil and water contamination, and human health impacts is largely unknown. Aerosol optical depth data from Sentinel-2 imagery revealed discernible dust clouds downwind of the mine and smelter on non-prevailing-wind days, suggesting potential heavy metal dispersion from this fugitive dust and subsequent deposition to nearby surface soils. Our analysis of topsoils from across the western Salt Lake Valley found mean arsenic, copper, lead, and zinc concentrations to be well above global background concentrations. Also, the minimum values for arsenic and maximum values for lead were well above the US EPA regional screening levels for residential soils. Thus, arsenic is the metal of greatest concern for impacts on human health. Elevated concentrations of all metals were most notable near the mine, smelter, and tailings pond. Our study linked these elevated heavy metal levels to regional asthma outcomes through cluster analysis and distance-related comparison tests. Significant clusters of high asthma rates were observed in regions with elevated topsoil heavy metal concentrations, impacting both low- and high-income neighborhoods. The findings of this preliminary study suggest that the mine, smelter, and recent construction activities, especially on lands reclaimed from former tailings ponds, could be contributing to atmospheric dust containing high levels of heavy metals and exacerbating asthma outcomes for residents. However, the methods used in the study with aggregated health outcome data cannot determine causal links between the heavy metal contents of soil and health outcomes; they can only point to potential links and a need for further investigation. Such further investigation should involve individual-level data and control for potential confounding factors, such as socioeconomic status, access to healthcare, and lifestyle factors, to isolate the effect of metal exposures on asthma outcomes. This study focused on atmospheric deposition as a source of heavy metal enrichment of topsoil. However, future research is also essential to assess levels of heavy metals in subsoil parent materials and local surface and groundwaters to be able to assess the links between the sources or methods of soil contamination and health outcomes. Full article
(This article belongs to the Special Issue New Insights in Soil Quality and Management)
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