Search Results (24)

Laser-induced breakdown spectroscopy (LIBS) has played a critical role in Mars exploration missions, substantially contributing to the geochemical analysis of Martian surface substances. However, the complex nonlinearity of LIBS processes can considerably limit the quantification accuracy of conventional LIBS chemometric methods. Hence chemometrics based on artificial neural network (ANN) algorithms have become increasingly popular in LIBS analysis due to their extraordinary ability in nonlinear feature modeling. The hidden layer activation functions are key to ANN model performance, yet common activation functions usually suffer from problems such as gradient vanishing (e.g., Sigmoid and Tanh) and dying neurons (e.g., ReLU). In this study, we propose a novel LIBS quantification method, named the Bayesian optimization-based tunable Softplus backpropagation neural network (BOTS-BPNN). Based on a dataset comprising 1800 LIBS spectra collected by a laboratory duplicate of the MarSCoDe instrument onboard the Zhurong Mars rover, we have revealed that a BPNN model adopting a tunable Softplus activation function can achieve higher prediction accuracy than BPNN models adopting other common activation functions if the tunable Softplus parameter β is properly selected. Moreover, the way to find the proper β value has also been investigated. We demonstrate that the Bayesian optimization method surpasses the traditional grid search method regarding both performance and efficiency. The BOTS-BPNN model also shows superior performance over other common machine learning models like random forest (RF). This work indicates the potential of BOTS-BPNN as an effective chemometric method for analyzing Mars in situ LIBS data and sheds light on the use of chemometrics for data analysis in future planetary explorations. Full article

The Zhurong rover of the Tianwen-1 mission has detected sulfates in its landing area. The analysis of these sulfates provides scientific evidence for exploring past hydration conditions and atmospheric evolution on Mars. As a non-contact technique with long-range detection capability, Laser-Induced Breakdown Spectroscopy (LIBS) is widely used for elemental identification on Mars. However, quantitative analysis of anionic elements using LIBS remains challenging due to the weak characteristic spectral lines of evaporite salt elements, such as sulfur, in LIBS spectra, which provide limited quantitative information. This study proposes a quantitative analysis method for sulfur in sulfate-containing Martian analogs by leveraging spectral line correlations, full-spectrum information, and prior knowledge, aiming to address the challenges of sulfur identification and quantification in Martian exploration. To enhance the accuracy of sulfur quantification, two analytical models for high and low sulfur concentrations were developed. Samples were classified using infrared spectroscopy based on sulfur content levels. Subsequently, multimodal deep learning models were developed for quantitative analysis by integrating LIBS and infrared spectra, based on varying concentrations. Compared to traditional unimodal models, the multimodal method simultaneously utilizes elemental chemical information from LIBS spectra and molecular structural and vibrational characteristics from infrared spectroscopy. Considering that sulfur exhibits distinct absorption bands in infrared spectra but demonstrates weak characteristic lines in LIBS spectra due to its low ionization energy, the combination of both spectral techniques enables the model to capture complementary sample features, thereby effectively improving prediction accuracy and robustness. To validate the advantages of the multimodal approach, comparative analyses were conducted against unimodal methods. Furthermore, to optimize model performance, different feature selection algorithms were evaluated. Ultimately, an XGBoost-based feature selection method incorporating prior knowledge was employed to identify optimal LIBS spectral features, and the selected feature subsets were utilized in multimodal modeling to enhance stability. Experimental results demonstrate that, compared to the BPNN, SVR, and Inception unimodal methods, the proposed multimodal approach achieves at least a 92.36% reduction in RMSE and a 46.3% improvement in R². Full article

This study conducted a comprehensive geological background investigation of the Zhurong rover’s landing area in Utopia Planitia using 3.5 m/pixel DEM and 0.7 m/pixel DOM data and completed the compilation of a 1:250,000-scale geological map. A total of 17 geological structures were systematically identified within the landing area. Additionally, focusing on scientific questions regarding the evolution of troughs, cone units, and mesas, we theoretically designed an exploration route considering slope constraints by taking the Zhurong rover route design as a case study. This route, a conceptual design, starts from the hibernation location of the Zhurong rover and has a total length of 126 km. It can provide a reference for advancing detection strategies for volatile components (e.g., water and ice) and contribute to the design of the Tianwen-3 exploration route. Ultimately, this study aims to establish a general guideline for integrating geological mapping with rover mobility planning in future extraterrestrial exploration missions. Full article

Dust storms, as an important extreme weather event on Mars, have significant impacts on the Martian atmosphere and climate and the activities of Martian probes. Therefore, it is necessary to analyze and predict the activity trends of Martian dust storms. This study uses historical data on global Column Dust Optical Depth (CDOD) from the Martian years (MYs) 24–36 (1998–2022) to develop a CDOD prediction method based on deep learning and predicts the spatiotemporal trends of dust storms in the landing areas of Martian rovers at high latitudes, the tropics, and the equatorial region. Firstly, based on a trained Particle Swarm Optimization (PSO) Long Short-Term Memory (LTSM)-CDOD network, the rolling predictions of CDOD average values for several sols in the future are performed. Then, an evaluation method based on the accuracy of the test set gives the maximum predictable number of sols and categorizes the predictions into four accuracy intervals. The effective prediction time of the model is about 100 sols, and the accuracy is higher in the tropics and equatorial region compared to at high latitudes. Notably, the accuracy of the Zhurong landing area in the north subtropical region is the highest, with a coefficient of determination (R²) and relative mean error (RME) of 0.98 and 0.035, respectively. Additionally, a Convolutional LSTM (ConvLSTM) network is used to predict the spatial distribution of CDOD intensity for different latitude landing areas of the future sol. The results are similar to the time predictions. This study shows that the LSTM-based prediction model for the intensity of Martian dust storms is effective. The prediction of Martian dust storm activity is of great significance to understanding changes in the Martian atmospheric environment and can also provide a scientific basis for assessing the impact on Martian rovers’ landing and operations during dust storms. Full article

The planet Mars is the most probable among the terrestrial planets in our solar system to support human settlement or colonization in the future. The detection of water ice or liquid water on the shallow subsurface of Mars is a crucial scientific objective for both the Chinese Tianwen-1 and United States Mars 2020 missions, which were launched in 2020. Both missions were equipped with Rover-mounted ground-penetrating radar (GPR) instruments, specifically the RoPeR on the Zhurong rover and the RIMFAX radar on the Perseverance rover. The in situ radar provides unprecedented opportunities to study the distribution of shallow subsurface water ice on Mars with its unique penetrating capability. The presence of water ice on the shallow surface layers of Mars is one of the most significant indicators of habitability on the extraterrestrial planet. A considerable amount of evidence pointing to the existence of water ice on Mars has been gathered by previous researchers through remote sensing photography, radar, measurements by gamma ray spectroscopy and neutron spectrometers, soil analysis, etc. This paper aims to review the various approaches utilized in detecting shallow subsurface water ice on Mars to date and to sort out the past and current evidence for its presence. This paper also provides a comprehensive overview of the possible clues of shallow subsurface water ice in the landing area of the Perseverance rover, serving as a reference for the RIMFAX radar to detect water ice on Mars in the future. Finally, this paper proposes the future emphasis and direction of rover-mounted radar for water ice exploration on the Martian shallow subsurface. Full article

Rocks, prominent features on the surface of Mars, are a primary focus of Mars exploration missions. The accuracy of recognizing rock information, including size and position, deeply affects the path planning for rovers on Mars and the geological exploration of Mars. In this paper, we present a rock measurement method for the Mars surface based on a Rover Attitude and Camera Parameter (RACP). We analyze the imaging process of the Navigation and Terrain Camera (NaTeCam) on the Zhurong rover, which involves utilizing a semi-spherical model (SSM) to characterize the camera’s attitude, a projection model (PM) to connect the image data with the three-dimensional (3D) environment, and then estimating the distance and size of rocks. We conduct a test on NaTeCam images and find that the method is effective in measuring the distance and size to Martian rocks and identifying rocks at specific locations. Furthermore, an analysis of the impact of uncertain factors is conducted. The proposed RACP method offers a reliable solution for automatically analyzing the rocks on Mars, which provides a possible solution for the route planning in similar tasks. Full article

Ground-penetrating radar (GPR) has been extensively utilized in deep-space exploration. However, GPR modeling commonly employs simplified antenna models and carrier-free impulse signals, resulting in reduced accuracy and interpretability. In this paper, we addressed these limitations by combining a tilted monopole antenna and linear frequency modulation continuous wave (LFMCW) to simulate real conditions. Additionally, a radiation-pattern-compensation back-propagation (RPC-BP) algorithm was developed to improve the illumination of the right-inclined structure. We first introduced the LFMCW used by the Mars Rover Penetrating Radar (RoPeR) onboard the Zhurong rover, where frequencies range from 15 to 95 MHz. Although the LFMCW signal improves radiation efficiency, it increases data processing complexity. Then, the radiation patterns and response of the tilted monopole antenna were analyzed, where the radiated signal amplitude varies with frequency. Finally, a series of numerical and laboratory experiments were conducted to interpret the real RoPeR data. The results indicate that hyperbolic echoes tilt in the opposite direction of the survey direction. This study demonstrates that forward modeling considering real transmit signals and complex antenna models can improve modeling accuracy and prevent misleading interpretations on deep-space exploration missions. Moreover, the migration process can improve imaging quality by considering radiation pattern compensation. Full article

As part of China’s Tianwen-1 Mars mission, the Mars Surface Composition Detector (MarSCoDe) instrument on the Zhurong rover adopts laser-induced breakdown spectroscopy (LIBS) to perform chemical component detection of the materials on the Martian surface. However, it has always been a challenging issue to achieve high accuracy in LIBS quantification. This study investigated the effect of chemometrics and spectral data preprocessing approaches on LIBS quantification accuracy based on different chemometrics algorithms and diverse preprocessing methods. A total of 2340 LIBS spectra were collected from 39 kinds of geochemical samples by a laboratory duplicate model of the MarSCoDe instrument. The samples and the MarSCoDe laboratory model were placed in a simulated Martian atmosphere environment based on equipment called the Mars-Simulated Detection Environment Experiment Platform (MarSDEEP). To quantify the concentration of MgO in the samples, we employed two common LIBS chemometrics; i.e., partial least squares (PLS) and a back-propagation neural network (BPNN). Meanwhile, in addition to necessary routine preprocessing such as dark subtraction, we used five specific preprocessing approaches, namely intensity normalization, baseline removal, Mg-peak wavelength correction, Mg-peak feature engineering, and concentration range reduction. The results indicated that the performance of the BPNN was better than that of the PLS and that the preprocessing of Mg-peak wavelength correction had the most prominent effect to improve the quantification accuracy. The results of this study are expected to provide inspiration for the processing and analysis of the in situ LIBS data acquired by MarSCoDe on Mars. Full article

China’s first Mars rover, Zhurong, landed on the southern region of Utopia Planitia, Mars, on 14 May 2021 (UTC). Zhurong is equipped with the Mars Surface Composition Detection Package (MarSCoDe), which analyzes the Martian surface’s material composition. Composed of laser-induced breakdown spectroscopy (LIBS), short-wave infrared spectroscopy (SWIR), and a microimaging camera, MarsCoDe can work at a distance of 1.6–7 m to analyze element abundance and the mineralogy of targets on the Martian surface. Analysis shows that the wavelengths of MarSCoDe onboard LIBS spectra acquired within the same probe period will have different degrees of drift, leading to deviation in qualitative and quantitative elemental analysis. This paper finds that the spectrum drift follows a quadratic function relationship with the CCD temperature of the MarSCoDe spectrometer, based on which a wavelength calibration method is established. According to the function, the drift of a certain channel is calculated by the corresponding CCD temperature, and then the wavelength of the spectrum is calibrated by the drift. The accuracy of this calibration method for the position of peak wavelength in the LIBS spectrum can reach about 1/5 of the apparatus spectral width, and the cross-validation analysis using a norite standard sample shows that it is comparable to the wavelength calibration accuracy of the ChemCam onboard data product. Full article

The Mars Surface Composition Detector (MarSCoDe) carried by the Zhurong rover of China’s Tianwen-1 mission uses Laser-Induced Breakdown Spectroscopy (LIBS) to detect and analyze the material composition on Martian surfaces. As one extraterrestrial remote LIBS system, it is necessary to adopt effective and reliable preprocessing methods to correct the spectral drift caused by the changes in environmental conditions, to ensure the analysis accuracy of LIBS scientific data. This paper focuses on the initial spectral drift correction and estimates the accuracy of on-board wavelength calibration on the LIBS calibration target measured by the MarSCoDe LIBS. There may be two cases during the instrument launch and landing, as well as the long-term operation: (a) the initial wavelength calibration relationship can still apply to the on-board LIBS measurement; and (b) the initial wavelength calibration relationship has been changed, and a new on-board calibration is needed to establish the current relationship. An approach of matching based on global iterative registration (MGR) is presented in respect to case (a). It is also compared with the approach of particle swarm optimization (PSO) for case (b). Furthermore, their accuracy is estimated with the comparison to the National Institute of Standards and Technology (NIST) database. The experimental results show that the proposed approach can effectively correct the drift of the on-board LIBS spectrum. The the root-mean-square error (RMSE) of the internal accord accuracy for three channels is 0.292, 0.223 and 0.247 pixels, respectively, compared with the corrected Ti-alloy spectrum and the NIST database, and the RMSE of the external accord accuracy is 0.232, 0.316 and 0.229 pixels, respectively, for other samples. The overall correction accuracy of the three channels is better than one-third of the sampling interval. Full article

A Mars Surface Composition Detector (MarSCoDe) instrument mounted on Zhurong rover of Tianwen-1, adopts Laser-Induced Breakdown Spectroscopy (LIBS), with no sample preparation or dust and coatings ablation required, to conduct rapid multi-elemental analysis and characterization of minerals, rocks and soils on the surface of Mars. To test the capability of MarSCoDe LIBS measurement and quantitative analysis, some methods of multivariate analysis on olivine samples with gradient concentrations were inspected based on the spectra acquired in a Mars-simulated environment before the rover launch in 2020. Firstly, LIBS spectra need preprocessing, including background subtraction, random signal denoising, continuum baseline removal, spectral drift correction and wavelength calibration, radiation calibration, and multi-channel spectra subset merging. Then, the quantitative analysis with univariate linear regression (ULR) and multivariate linear regression (MLR) are performed on the characteristic lines, while principal component regression (PCR), partial least square regression (PLSR), ridge, least-absolute-shrinkage-and-selection-operator (LASSO) and elastic net, and nonlinear analysis with back-propagation (BP) are conducted on the entire spectral information. Finally, the performance on the quantitative olivine analyzed by MarSCoDe LIBS is compared with the mean spectrum and all spectra for each sample and evaluated by some statistical indicators. The results show that: (1) the calibration curve of ULR constructed by the characteristic line of magnesium and iron indicates the linear relationship between the spectral signal and the element concentration, and the limits of detection of forsterite and fayalite is 0.9943 and 2.0536 (c%) analyzed by mean spectra, and 2.3354 and 3.8883 (c%) analyzed by all spectra; (2) the R² value on the calibration and validation of all the methods is close to 1, and the predicted concentration estimated by these calibration models is close to the true concentration; (3) the shrinkage or regularization technique of ridge, LASSO and elastic net perform better than the ULR and MLR, except for ridge overfitting on the testing sample; the best results can be obtained by the dimension reduction technique of PCR and PLSR, especially with PLSR; and BP is more applicable for the sample measured with larger spectral dataset. Full article

The optical properties of rocks and minerals provide a reliable way to measure their chemical and mineralogical composition due to the specific reflection behaviors, which is also the key insight behind most automatic identification and classification approaches. However, the inter-category spectral similarity poses a great challenge to the automatic identification and classification tasks because of the diversity of rocks and minerals. Therefore, this paper develops a recognition and classification approach of rocks and minerals using the highly discriminative representation derived from their raw spectral signatures. More specifically, a transformer-based classification approach integrated with category-aware contrastive learning is constructed and trained in an end-to-end manner, which would force instances of the same category to remain close-by while pushing instances of a dissimilar category far apart in the high-dimensional feature space, in order to produce the highly discriminative feature representation of the rocks and minerals. From both qualitative and quantitative views, experiments are conducted on the laboratory sample dataset with 30 types of rocks and minerals shared from the National Mineral Rock and Fossil Specimens Resource Center, and the spectral information of the laboratory rocks and minerals is captured using a multi-spectral sensor, with a duplicated payload of the counterpart onboard the Zhurong rover. Quantitative results demonstrate that the developed approach can effectively distinguish 30 types of rocks and minerals, with a high overall accuracy of 96.92%. Furthermore, the developed approach is remarkably superior to other existing methods, with average differences of 4.75% in the overall accuracy. Furthermore, we also visualized the derived highly discriminative features of different types of rocks and minerals by projecting them onto a two-dimensional map, where the same categories tend to be modeled by nearby locations and the dissimilar categories by distant locations with high probability. It can be observed that, compared with those in the raw spectral feature space, the clusters are formed better in the derived highly discriminative feature space, which further confirms the promising representation capability. Full article

Zhurong rover successfully landed on the southern of Utopia Planet of Mars on 15 May 2021. One laser-induced breakdown spectroscopy (LIBS) system, the main payload of the Mars Surface Composition Detector (MarSCoDe), was installed on the Zhurong rover aimed to measure the elements and their abundance in Martian regolith. Now, there are three sets of LIBS system (ChemCam, SuperCam and MarSCoDe) working on Mars at difference landing sites with diverse geologic features. For Mars exploration, cross-validation is necessary to expand the model compatibility, test data validity, and get more available data of the same type payloads. Spectral transformation approach is the first step and crucial for cross-validation of LIBS analysis model. Herein, a new 4-step spectral transformation approach was proposed to transform the LIBS spectra between three different LIBS systems (i.e., ChemCam, MarSCoDe, SDU-LIBS (recorded by self-built LIBS system)), whose data were partly different in spectral characteristics. Based on this approach, SDU-LIBS and MarSCoDe spectra data were transformed into ChemCam uniform and then the three kinds of LIBS data can have more similar spectral features and share one PLS (partial least squares) model for quantitative analysis. Our approach enables to make up the signal differences between different LIBS systems and gets acceptable quantitative analysis results of SDU-LIBS and MarSCoDe spectra using quantitative PLS model built by ChemCam calibration sample set. This work verified feasibility and availability of our approach for cross validation of different LIBS systems. Based on this method, MarSCoDe data were analyzed and got the preliminary satisfying results although no analysis model of laboratory replica payload was available under the existing conditions. Full article

China’s first Mars exploration mission, named Tianwen-1, landed on Mars on 15 May 2021. The Mars Surface Composition Detector (MarSCoDe) payload onboard the Zhurong rover applied the laser-induced breakdown spectroscopy (LIBS) technique to acquire chemical compositions of Martian rocks and soils. The quantitative interpretation of MarSCoDe-LIBS spectra needs to establish a LIBS spectral database that requires plenty of terrestrial geological standards. In this work, we selected 316 terrestrial standards including igneous rocks, sedimentary rocks, metamorphic rocks, and ores, whose chemical compositions, rock types, and chemical weathering characteristics were comparable to those of Martian materials from previous orbital and in situ detections. These rocks were crushed, ground, and sieved into powders less than <38 μm and pressed into pellets to minimize heterogeneity at the scale of laser spot. The chemical compositions of these standards were independently measured by X-ray fluorescence (XRF). Subsequently, the LIBS spectra of MAL standards were acquired using an established LIBS system at Shandong University (SDU-LIBS). In order to evaluate the performance of these standards in LIBS spectral interpretation, we established multivariate models using partial least squares (PLS) and least absolute shrinkage and selection (LASSO) algorithms to predict the abundance of major elements based on SDU-LIBS spectra. The root mean squared error (RMSE) values of these models are comparable to those of the published models for MarSCoDe, ChemCam, and SuperCam, suggesting these PLS and LASSO models work well. From our research, we can conclude that these 316 MAL targets are good candidates to acquire geochemistry information based on the LIBS technique. These targets could be regarded as geological standards to build a LIBS database using a prototype of MarSCoDe in the near future, which is critical to obtain accurate chemical compositions of Martian rocks and soils based on MarSCoDe-LIBS spectral data. Full article

On 15 May 2021, the Zhurong rover of China’s first Mars mission, Tianwen-1 (TW-1), successfully landed in southern Utopia Planitia on Mars. Various landforms were present in the landing area, and this area recorded a complex geological history. Cones are one of the typical landforms in the landing area and Utopia Planitia, and they have a great significance to the local geological processes due to the diversity of their origins. Using High-Resolution Imaging Camera (HiRIC) images collected by the TW-1 orbiter, we identified a total of 272 well-preserved circular cones in the landing area. Detailed surveys of their spatial distribution, morphological characteristics, and morphometric parameters were conducted. A preliminary analysis of the surface characteristics of these cones also provides additional information to strengthen our understanding of them. The results of the high-resolution topographic analysis show that the cone heights are in the range of 10.5–90.8 m and their basal diameters range from 178.9–1206.6 m. We compared the morphometric parameters of the cones in the landing area with terrestrial and Martian analogous features and found that our measured cones are consistent with the ranges of mud volcanoes and also a small subset of igneous origin cones. However, the result of spatial analysis is more favorable to mud volcanoes, and the lower thermal inertia of the cones in the landing area compared to their surrounding materials is also a typical characteristic of mud volcanoes. Based on current evidence and analysis, we favor interpreting the cones in the TW-1 landing area as mud volcanoes. Full article