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Keywords = PLA bondlines

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11 pages, 2663 KiB  
Article
Closed-Loop Composite Welding and Bonding System Using Radio-Frequency Heating and Pressure
by Ian Enriquez, Colin Noronha, Katrina Teo, Anubhav Sarmah, Surabhit Gupta, Ankush Nandi, Blake Fishbeck, Micah J. Green and Aniruddh Vashisth
J. Compos. Sci. 2023, 7(3), 116; https://doi.org/10.3390/jcs7030116 - 13 Mar 2023
Cited by 4 | Viewed by 2797
Abstract
Polymer parts often replace traditional metallic parts in load-bearing applications due to their high strength-to-weight ratio, with thermoplastics at the forefront. Conventional manufacturing processes rely on using fasteners or adhesives to hold composite assemblies together, but thermoplastics can be welded together. Ultrasonic welding [...] Read more.
Polymer parts often replace traditional metallic parts in load-bearing applications due to their high strength-to-weight ratio, with thermoplastics at the forefront. Conventional manufacturing processes rely on using fasteners or adhesives to hold composite assemblies together, but thermoplastics can be welded together. Ultrasonic welding is widely used but becomes challenging for complex geometries, and new parameters need to be developed for different polymers and specimen geometries. In this work, we developed a closed-loop welding machine that employs the recent discovery of radio-frequency (RF) heating of carbonaceous materials. The machine is successfully able to weld polylactic acid (PLA) coupons with graphitic RF susceptors at the bondline in less than 2 min and using less than 50 W of input RF power. We found that a higher areal density of the graphitic paint lowers the mechanical properties of the weld because the carbonaceous materials hinder polymer chain diffusion. A significant change was not observed in weld properties for welding pressure ranges between 0 and 0.3 MPa. However, increasing out-of-plane welding displacement increased the modulus and strength of the weld. This work provides an interesting new automated system for welding polymer composites using RF fields, with potential applications in various manufacturing industries. Full article
(This article belongs to the Special Issue Progress in Polymer Composites, Volume II)
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12 pages, 1418 KiB  
Article
Understanding the PLA–Wood Adhesion Interface for the Development of PLA-Bonded Softwood Laminates
by Warren J. Grigsby, Marc Gaugler and Desiree Torayno
Fibers 2022, 10(6), 51; https://doi.org/10.3390/fib10060051 - 9 Jun 2022
Cited by 2 | Viewed by 2523
Abstract
With polylactic acid (PLA) usage projected to increase in wood-based composite materials, a study comparing composite processing parameters with resulting PLA−wood adhesion and panel performance is warranted. In this study, PLA-softwood veneer laminates have been prepared and spatial chemical imaging via FTIR analysis [...] Read more.
With polylactic acid (PLA) usage projected to increase in wood-based composite materials, a study comparing composite processing parameters with resulting PLA−wood adhesion and panel performance is warranted. In this study, PLA-softwood veneer laminates have been prepared and spatial chemical imaging via FTIR analysis was applied to identify PLA bondlines characterizing bondline thickness and the extent of PLA migration into the wood matrix. These PLA–wood adhesion interface characteristics have been compared with the performance of panels varying in pressing temperature, pressing time and PLA grades. For amorphous PLA, bondline thicknesses (60–120 μm) were similar, pressing at 140 °C or 160 °C, whereas with semi-crystalline PLA, the bondline thickness (340 μm) significantly reduced (155–240 μm) only when internal panel temperatures exceeded 140 °C during pressing. Internal temperatures also impacted PLA penetration, with greater PLA migration from bondlines evident with higher pressing temperatures and times with distinctions between PLA grades and bondline position. Performance testing revealed thinner PLA bondlines were associated with greater dry strength for both PLA grades. Cold-water soaking revealed laminated panels exhibit a range of wet-strength performance related to panel-pressing regimes with the semi-crystalline PLA pressed at 180 °C having similar tensile strength in dry and wet states. Moreover, an excellent correlation between wet-strength performance and bondline thickness and penetration values was evident for this PLA grade. Overall, study findings demonstrate PLA wood composite performance can be tuned through a combination of the PLA grade and the pressing regime employed. Full article
(This article belongs to the Collection Feature Papers in Fibers)
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8 pages, 3159 KiB  
Article
Chemical Imaging of the Polylactic Acid − Wood Adhesion Interface of Bonded Veneer Products
by Warren J. Grigsby, Desiree Torayno, Marc Gaugler, Jan Luedtke and Andreas Krause
Fibers 2022, 10(2), 17; https://doi.org/10.3390/fib10020017 - 9 Feb 2022
Cited by 4 | Viewed by 2437
Abstract
The increasing use and potential of polylactic acid (PLA) in wood-based composite materials due to its greater performance over common polyolefins provides the justification for a closer examination of the PLA−wood adhesion performance. In PLA-bonded laminates and composites, the optical differentiation between PLA [...] Read more.
The increasing use and potential of polylactic acid (PLA) in wood-based composite materials due to its greater performance over common polyolefins provides the justification for a closer examination of the PLA−wood adhesion performance. In PLA-bonded laminates and composites, the optical differentiation between PLA polymer and wood is not possible and necessitates complex techniques such as fluorescence microscopy to characterize the PLA adhesion interface. In this study, spatial chemical imaging via FTIR analysis has been successfully applied to directly identify PLA bondlines within PLA-bonded veneer laminates and to determine the migration of semi-crystalline and amorphous PLAs from the bondline into the wood structure. This method uses involved point contouring line spectra over the bondline area to distinguish the PLA polymer from the wood. From this quantitative analysis, it is revealed that bondline thickness and PLA penetration values depend on pressing temperature, and this has implications for the reinforcement of the adhesion interface and the bondline performance. Furthermore, in developing a methodology for this assessment, this spatial chemical imaging approach can equally be applied to other polyester, amide, and urethane systems used to bond wood laminates. Full article
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13 pages, 1567 KiB  
Article
Bonding Wood Veneer with Biobased Poly(Lactic Acid) Thermoplastic Polyesters: Potential Applications for Consolidated Wood Veneer and Overlay Products
by Warren J. Grigsby, Arpit Puri, Marc Gaugler, Jan Lüedtke and Andreas Krause
Fibers 2020, 8(8), 50; https://doi.org/10.3390/fib8080050 - 31 Jul 2020
Cited by 6 | Viewed by 4514
Abstract
This study reports on the use of poly(lactic acid) (PLA) as a renewable thermoplastic adhesive for laminated panels using birch, spruce, and pine veneers. Consolidated panels were prepared from veneer and PLA foils by hot-pressing from 140 to 180 °C to achieve minimum [...] Read more.
This study reports on the use of poly(lactic acid) (PLA) as a renewable thermoplastic adhesive for laminated panels using birch, spruce, and pine veneers. Consolidated panels were prepared from veneer and PLA foils by hot-pressing from 140 to 180 °C to achieve minimum bondline temperatures. Evaluation of panel properties revealed that the PLA-bonded panels met minimum tensile strength and internal bond strength performance criteria. However, the adhesion interface which developed within individual bondlines varied with distinctions between hardwood and softwood species and PLA grades. Birch samples developed greater bondline strength with a higher pressing temperature using semi-crystalline PLA, whereas higher temperatures produced a poorer performance with the use of amorphous PLA. Panels formed with spruce or pine veneers had lower bondline performance and were also similarly distinguished by their pressing temperature and PLA grade. Furthermore, the potential for PLA-bonded laminated panels was demonstrated by cold water soak testing. Samples exhibiting relatively greater bondline adhesion had wet tensile strength values comparable to those tested in dry state. Our study outcomes suggest the potential for PLA bonding of veneers and panel overlays with the added benefits of being renewable and a no added formaldehyde system. Full article
(This article belongs to the Special Issue Wood Plastic Composites)
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12 pages, 2877 KiB  
Article
Quantitative Assessment and Visualisation of the Wood and Poly(Lactic Acid) Interface in Sandwich Laminate Composites
by Warren Grigsby, Victor Gager, Kimberly Recabar, Andreas Krause, Marc Gaugler and Jan Luedtke
Fibers 2019, 7(2), 15; https://doi.org/10.3390/fib7020015 - 11 Feb 2019
Cited by 8 | Viewed by 5824
Abstract
Fluorescence microscopy was applied to understand adhesion interfaces developed within laminated composite sandwiches formed between poly(lactic acid) (PLA) and wood veneers. Composites formed with maple veneer had greater tensile bond strength when manufactured at 200 °C (10.4 N/mm2) compared to formation [...] Read more.
Fluorescence microscopy was applied to understand adhesion interfaces developed within laminated composite sandwiches formed between poly(lactic acid) (PLA) and wood veneers. Composites formed with maple veneer had greater tensile bond strength when manufactured at 200 °C (10.4 N/mm2) compared to formation at 140 °C (8.7 N/mm2), while significantly lower bond strength was achieved using spruce veneers, at 5.2 and 3.5 N/mm2, respectively. Qualitative and quantitative confocal microscopy assessments revealed differing bondline thicknesses and PLA ingress within the wood ultrastructure. Forming maple veneer composites at 200 °C promoted greater PLA mobility away from the bondline to reinforce the wood–PLA interface and deliver associated greater composite bond strength. The addition of 25% wood fibre to PLA led to fibre alignment and overlap within bondlines contributing to relatively thicker, heterogeneous bondlines. Study outcomes show that the composite processing temperature impacts the adhesion interface and composite performance and will have broad application over veneer overlays, laminates and wood plastic composites (WPCs) using wood, particles or fibres with PLA. Full article
(This article belongs to the Special Issue Wood Plastic Composites)
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