Search Results (2)

One of the promising processing methods for non-conductive structural and functional ceramics based on ZrO₂, Al₂O₃, and Si₃N₄ systems is electrical discharge machining with the assistance of an auxiliary electrode that can be presented in the form of conductive films with a thickness up to 4–10 µm or nanoparticles - granules, tubes, platelets, multidimensional particles added in the working zone as a free poured powder the proper concentration of which can be provided by ultrasound emission or by dielectric flows or as conductive additives in the structure of nanocomposites. However, the described experimental approaches did not reach the production market and industry. It is related mostly to the chaotic development of the knowledge and non-systematized data in the field when researchers often cannot ground their choice of the material for auxiliary electrodes, assisting powders, or nano additives or they cannot explain the nature of processes that were observed in the working tank during experiments when their results are not correlated to the measured specific electrical conductivity of the electrodes, particles, ceramic workpieces or nanocomposites but depends on something else. The proposed review includes data on the main electrophysical and chemical properties of the components in the presence of heat when the temperature in the interelectrode gap reaches 10,000 °C, and the systematization of data on ceramic pressing methods, including spark plasma sintering, the chemical reactions that occur in the interelectrode gap during sublimation of primary (brass and copper) and auxiliary electrodes made of transition metals Ti, Cr, Co, and carbon, auxiliary electrodes made of metals with low melting point Zn, Ag, Au, Al, assisting powder of oxide ceramics TiO₂, CeO₂, SnO₂, ITO, conductive additives Cu, W, TiC, WC, and components of Al₂O₃ and Zr₂O workpieces in interaction with the dielectric fluid - water and oil/kerosene medium. Full article

Aluminum and aluminum alloys have the advantage of a high strength-to-weight ratio, but their low hardness and poor wear resistance often cause wear damage. In the present study, the cladding layer was prepared using argon-shielded arc cladding of CuZn40-WC powders which were pre-coated on a pure aluminum substrate. The effects of WC proportion on the morphology, microstructure, and properties of cladding layers were investigated in detail. The results indicated that the optimal WC proportion in CuZn40-WC powders was 60 wt.%. With the increase of WC proportion, although the morphology of the cladding layer became slightly worse, the surface quality of the cladding layer was acceptable for industrial application until the WC proportion was 80 wt.%. Meanwhile, the top width and maximum depth of the cladding layer decreased. The maximum microhardness and optimal wear resistance of the cladding layer were 4.5 and 2.5 times that of the aluminum substrate, respectively. The increased microhardness and wear resistance were mainly attributed to the formation of Al₄W in the cladding layer. The wear scar of the high wear resistance specimen was smoother and some bulk Al₄W compounds were clearly observed on the wear surface. Full article