Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (47)

Search Parameters:
Keywords = Cu-Ni-PGE mineralization

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
24 pages, 13891 KiB  
Article
Fertility of Gabbroic Intrusions in the Paleoproterozoic Lynn Lake Greenstone Belt, Manitoba, Canada: Insights from Field Relationships, Geochemical and Metallogenic Characteristics
by Xue-Ming Yang
Minerals 2025, 15(5), 448; https://doi.org/10.3390/min15050448 - 26 Apr 2025
Viewed by 620
Abstract
Magmatic nickel–copper–platinum group element (PGE) deposits hosted in mafic–ultramafic intrusions within volcanic arc systems are highly attractive targets for mineral exploration, yet their genesis remains poorly understood. This study investigates metagabbroic intrusions in the Paleoproterozoic Lynn Lake greenstone belt of the Trans-Hudson Orogen [...] Read more.
Magmatic nickel–copper–platinum group element (PGE) deposits hosted in mafic–ultramafic intrusions within volcanic arc systems are highly attractive targets for mineral exploration, yet their genesis remains poorly understood. This study investigates metagabbroic intrusions in the Paleoproterozoic Lynn Lake greenstone belt of the Trans-Hudson Orogen to identify the key factors, in the original gabbros, that control the formation of magmatic Ni-Cu-PGE deposits in volcanic arc systems. By examining the field relationships, geochemical and sulfur and oxygen stable isotope compositions, mineralogy, and structural fabrics, this study aims to explain why some intrusions host mineralization (e.g., Lynn Lake and Fraser Lake intrusions), whereas others remain barren (e.g., Ralph Lake, Cartwright Lake, and Snake Lake intrusions). Although both the fertile and barren gabbroic, likewise original, intrusions exhibit metaluminous, tholeiitic to calc-alkaline affinity with volcanic arc geochemical signatures, they differ significantly in shape, ranging from vertical and tube-like to tabular forms, reflecting distinct geological settings and magma dynamics. The gabbroic rocks of fertile intrusions exhibit erratic trace element profiles, lower (Nb/Th)N and higher (Cu/Zr)N ratios, as well as a larger range of δ34S values than those in barren intrusions. Key factors influencing Ni-Cu-PGE mineralization include the degree of partial melting of the mantle, early sulfide segregation, and crustal contamination, particularly from volcanogenic massive sulfide deposits. These processes likely triggered sulfide saturation in the mafic magmas. Geochemical proxies, such as PGE concentrations and sulfur and oxygen stable isotopes, provide critical insights into these controlling factors. The results of this study enhance our understanding of the metallogenic processes responsible for the formation of magmatic Ni-Cu-PGE deposits in the gabbroic intrusions emplaced in an extensional setting due to slab rollback, during the geological evolution of the Lynn Lake greenstone belt, offering valuable guidance for mineral exploration efforts. Full article
(This article belongs to the Special Issue Novel Methods and Applications for Mineral Exploration, Volume III)
Show Figures

Figure 1

48 pages, 12213 KiB  
Review
Metasomatic Mineral Systems with IOA, IOCG, and Affiliated Critical and Precious Metal Deposits: A Review from a Field Geology Perspective
by Louise Corriveau and Jean-François Montreuil
Minerals 2025, 15(4), 365; https://doi.org/10.3390/min15040365 - 31 Mar 2025
Cited by 2 | Viewed by 1457
Abstract
Worldwide, a growing list of critical (Bi, Co, Cu, F, Fe, Mo, Ni, P, PGE, REE, W, U, and Zn) and precious metal (Ag and Au) resources have been identified in mineral systems forming Fe-oxide-copper-gold (IOCG) deposits; Fe-oxide-apatite (IOA); Fe-sulfide Cu-Au (ISCG); and [...] Read more.
Worldwide, a growing list of critical (Bi, Co, Cu, F, Fe, Mo, Ni, P, PGE, REE, W, U, and Zn) and precious metal (Ag and Au) resources have been identified in mineral systems forming Fe-oxide-copper-gold (IOCG) deposits; Fe-oxide-apatite (IOA); Fe-sulfide Cu-Au (ISCG); and affiliated W skarn; Fe-rich Au-Co-Bi or Ni; albitite-hosted U or Au ± Co; and five-element (Ag, As, Co, Ni, and U) vein deposits. This paper frames the genesis of this metallogenic diversity by defining the Metasomatic Iron and Alkali-Calcic (MIAC) mineral system and classifying its spectrum of Fe-rich-to-Fe-poor and alkali-calcic deposits. The metasomatic footprint of MIAC systems consists of six main alteration facies, each recording a distinct stage of mineralization as systems have evolved. The fluid flow pathways and the thermal and chemical gradients inferred from the space–time distribution of the alteration facies within a system are best explained by the ascent and lateral propagation of a voluminous hypersaline fluid plume. The primary fluid plume evolves, chemically and physically, as metasomatism progresses and through periodic ingresses of secondary fluids into the plume. Exploration strategies can take advantage of the predictability and the expanded range of exploration targets that the MIAC system framework offers, the building blocks of which are the alteration facies as mappable prospectivity criteria for the facies-specific critical and precious metal deposits the systems generate. Global case studies demonstrate that these criteria are applicable to MIAC systems worldwide. Full article
Show Figures

Figure 1

15 pages, 4916 KiB  
Article
Sulfide Globule and a Localized Domain Ultra-Enriched in PGMs in the Main Reef Anorthosite from the Yoko-Dovyren Massif
by Ivan V. Pshenitsyn, Alexey A. Ariskin, Dmitry V. Korost, Sergei N. Sobolev, Vasily O. Yapaskurt and Georgy S. Nikolaev
Minerals 2025, 15(2), 160; https://doi.org/10.3390/min15020160 - 9 Feb 2025
Cited by 1 | Viewed by 760
Abstract
The results of a detailed examination of an anomalously PGM-rich anorthositic fragment from the Main Reef of the Yoko-Dovyren massif (Northern Transbaikalia, Russia) are presented. This fragment is to represent a 15 mm core drilled out from a typical low-sulfide PGE-rich anorthosite, occurring [...] Read more.
The results of a detailed examination of an anomalously PGM-rich anorthositic fragment from the Main Reef of the Yoko-Dovyren massif (Northern Transbaikalia, Russia) are presented. This fragment is to represent a 15 mm core drilled out from a typical low-sulfide PGE-rich anorthosite, occurring within the transition zone between troctolite and a rhythmically stratified sequence of olivine gabbro. Coupling multistage X-ray computed tomography (CT) with SEM studies allowed for revealing a heterogeneous distribution of PGMs and sulfides observable as (i) the main 4 mm sulfide globule containing some small PGMs around its periphery, with (ii) the bulk of the PGMs concentrated within a 3 mm sized scattered sulfide nest, comprising about 6 vol.% of the globule and located at a distance of 2–3 mm from it. Mass-balance calculations showed that the average sulfide composing this nest is 120fold richer in PGE than the sulfide globule. Calculations of sulfide minerals proportions showed that the globule consists of 39 vol.% Po, 21% Pn, 34% Cub, and 6% Ccp (consistent with 35.2 wt.% S, 48.2% Fe, 6.4% Ni, 9.9% Cu, and 0.4% Co), whereas the PGM-enriched sulfide domain includes (vol.%): Po—34, Pn—15, Ccp—23, and Cub—28 (respectively, S—35.2 wt.%, Fe—45.8%, Ni—4.6%, Cu—14.2%, and Co—0.3%). Thus, the PGM-enriched nest demonstrates an obvious increase in Cu relative to the sulfide globule. Further SEM studies of four thin sections of the globule and associated nest showed that they differ not only in the ratios of base metal sulfides, but also in the PGE mineralogy. The globule contains more high-temperature PGMs, such as moncheite, while the nest is enriched in “low-temperature” PGMs, including notable amounts of lead and mercury. The overwhelming majority of the numerous PGMs in the unusual domain were detected as tetraferroplatinum, with subordinate potarite and zvyagintsevite, associated with chlorite and apatite. Such a subdivision of anorthositic sulfides into two types demonstrating different composition and mineralogy, as well as contrasting distributions of PGE in the sulfide segregations, was established for the first time! The origin of the contrast PGM-sulfide assemblages is discussed. Full article
(This article belongs to the Section Mineral Deposits)
Show Figures

Figure 1

26 pages, 8849 KiB  
Article
The Evolution of Permian Mafic–Ultramafic Magma of the Yunhai Intrusion in the Northern Tianshan, Northwest China, and Its Implications for Cu-Ni Mineralization
by Yuxuan Pei, Mengting Chen, Yujing Zhao, Dahai Li, Jiashun Chen, Zhaoying Chen, Xiaojie Li and Shilin Sun
Minerals 2025, 15(2), 102; https://doi.org/10.3390/min15020102 - 22 Jan 2025
Viewed by 1002
Abstract
The early Permian mafic–ultramafic intrusion-related Cu-Ni mineralization in Northern Tianshan offers valuable insights into the nature of the mantle beneath the Central Asian Orogenic Belt (CAOB) and enhances the understanding of magmatic sulfide mineralization processes in orogenic environments. The Yunhai intrusion, rich in [...] Read more.
The early Permian mafic–ultramafic intrusion-related Cu-Ni mineralization in Northern Tianshan offers valuable insights into the nature of the mantle beneath the Central Asian Orogenic Belt (CAOB) and enhances the understanding of magmatic sulfide mineralization processes in orogenic environments. The Yunhai intrusion, rich in Cu-Ni sulfides, marks a significant advancement for Cu-Ni exploration in the covered regions of the western Jueluotag orogenic belt in Northern Tianshan. This intrusion is well-differentiated, featuring a lithological assemblage of olivine pyroxenite, hornblende pyroxenite, gabbro, and diorite, and contains about 50 kilotons of sulfides with average grades of 0.44 wt% Ni and 0.62 wt% Cu. Sulfide mineralization occurs predominantly as concordant layers or lenses of sparsely and densely disseminated sulfides within the olivine pyroxenite and hornblende pyroxenite. In situ zircon U-Pb dating for the Yunhai intrusion indicates crystallization ages between 288 ± 1 and 284 ± 1 Ma, aligning with several Cu-Ni mineralization-associated mafic–ultramafic intrusions in Northern Tianshan. Samples from the Yunhai intrusion exhibit enrichment in light rare earth elements (LREE), distinct negative Nb and Ta anomalies, positive εNd(t) values ranging from 2.75 to 6.56, low initial (87Sr/86Sr)i ratios between 0.7034 and 0.7053, and positive εHf(t) values from 9.27 to 15.9. These characteristics, coupled with low Ce/Pb (0.77–6.55) and Nb/U (5.47–12.0) ratios and high Ti/Zr values (38.7–102), suggest very restricted amounts (ca. 5%) of crustal assimilation. The high Rb/Y (0.35–4.27) and Th/Zr (0.01–0.03) ratios and low Sm/Yb (1.47–2.32) and La/Yb (3.10–7.52) ratios imply that the primary magma of the Yunhai intrusion likely originated from 2%–10% partial melting of weak slab fluids–metasomatized subcontinental lithospheric mantle (peridotite with 2% spinel and/or 1% garnet) in a post-collisional environment. The ΣPGE levels in the Yunhai rocks and sulfide-bearing ores range from 0.50 to 54.4 ppb, which are lower compared to PGE-undepleted Ni-Cu sulfide deposits. This PGE depletion in the Yunhai intrusion’s parental magma may have been caused by early sulfide segregation from the primary magma at depth due to the high Cu/Pd ratios (43.5 × 103 to 2353 × 103) of all samples. The fractional crystallization of minerals such as olivine and pyroxene might be a critical factor in provoking significant sulfide segregation at shallower levels, leading to the extensive disseminated Cu-Ni mineralization at Yunhai. These characteristics are similar to those of typical deposits in the eastern section of the Jueluotage orogenic belt (JLOB), which may indicate that the western and eastern sections of the belt have the same ore-forming potential. Full article
(This article belongs to the Special Issue Metallogenesis of the Central Asian Orogenic Belt)
Show Figures

Figure 1

16 pages, 22557 KiB  
Article
HRTEM Study of Desulfurization of Pt- and Pd-Rich Sulfides from New Caledonia Ophiolite
by Néstor Cano, José M. González-Jiménez, Fernando Gervilla and Thomas N. Kerestedjian
Minerals 2025, 15(1), 66; https://doi.org/10.3390/min15010066 - 12 Jan 2025
Viewed by 1049
Abstract
Oxygen-bearing platinum group minerals (O-bearing PGMs) are intergrown with base metal sulfides (BMS, e.g., pentlandite–[NiFe]9S8) within fractures in chromite grains from chromitite bodies on Ouen Island, New Caledonia. These PGMs are hosted in chlorite and serpentine, which formed during [...] Read more.
Oxygen-bearing platinum group minerals (O-bearing PGMs) are intergrown with base metal sulfides (BMS, e.g., pentlandite–[NiFe]9S8) within fractures in chromite grains from chromitite bodies on Ouen Island, New Caledonia. These PGMs are hosted in chlorite and serpentine, which formed during serpentinization of olivine and pyroxene. The O-bearing PGM grains are polygonal, show microfracturing (indicating volume loss), and contain Pt-Pd-rich sulfide remnants, suggesting pseudomorphic replacement of primary (magmatic) sulfides. They display chemical zonation, with Pt(-Pd-Ni-Fe) relict sulfide cores replaced by Pt-Fe-Ni oxidized alloy mantles and Pt-Cu-Fe(-Pd) alloy rims (tulameenite), indicating desulfurization. The core and mantle show a nanoporous structure, interpreted as the result of coupled dissolution–reprecipitation reactions between magmatic sulfides and low fO2fS2 serpentinite-related fluids, probably formed during olivine transformation to serpentine + magnetite (early stages of serpentinization). This fluid infiltrated magmatic sulfides (PGE-rich and BMS), degrading them to secondary products and releasing S and metals that were accommodated in the mantle and rim of O-bearing PGMs. Upon olivine exhaustion, an increase in fO2 might have stabilized Pt-Fe-O compounds (likely Pt0/Pt-Fe + Fe oxyhydroxides) alongside Ni-Fe alloys. Our results show that post-magmatic desulfurization of primary sulfides produces complex nano-scale intergrowths, mainly driven by changes in the fluid’s physicochemical properties during serpentinization. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
Show Figures

Figure 1

25 pages, 6929 KiB  
Review
Case Studies of Magnetic and Electromagnetic Techniques Covering the Last Fifteen Years
by Marc A. Vallée, Mouhamed Moussaoui and Khorram Khan
Minerals 2024, 14(12), 1286; https://doi.org/10.3390/min14121286 - 18 Dec 2024
Viewed by 2791
Abstract
Magnetic and electromagnetic techniques have a long history of application in mineral exploration to detect deposits and their surroundings. Their implementation over the last fifteen years has been affected by strong variations in the mining market in parallel with important technological developments. During [...] Read more.
Magnetic and electromagnetic techniques have a long history of application in mineral exploration to detect deposits and their surroundings. Their implementation over the last fifteen years has been affected by strong variations in the mining market in parallel with important technological developments. During this period, both methods were the subject of numerous documented case studies all over the globe, which is a sign of popularity and longevity of these techniques. Through a review of case histories from the main geophysical journals, we analyze the principal usage of these methods when applied to mineral exploration, while the majority of documented cases originate from North America, Asia, and Australia. There are more case studies describing the use of the magnetic method and we attribute this popularity to direct and indirect use of this method for mineral exploration. In particular, there is an increasing number of magnetic surveys conducted with drones. Combining magnetic and electromagnetic techniques is also common. The number of magnetic and EM technique case histories range by descending order from gold, porphyry copper, polymetallic, massive sulfides, uranium, Ni-Cu-PGE, iron ore, kimberlite, and iron-oxide copper-gold, with a number of single continent-specific applications. Full article
Show Figures

Figure 1

13 pages, 23345 KiB  
Article
Clinopyroxenite-Wehrlite Porya Guba Complex with Fe-Ti-V and PGE-Cu-Ni Mineralization in the Northeastern Part of the Fennoscandian Shield: Evidence of Post-Orogenic Formation from Sm-Nd Isotope System
by Pavel A. Serov and Nikolay Yu. Groshev
Minerals 2024, 14(11), 1099; https://doi.org/10.3390/min14111099 - 29 Oct 2024
Viewed by 823
Abstract
The Porya Guba clinopyroxenite–wehrlite complex is located in the core of the Lapland–Kola collisional orogen (~2.0–1.9 billion years old) in the northeastern part of the Fennoscandian Shield and contains iron–titanium–vanadium and nickel–copper mineralization with platinum group elements (PGEs). The controversial geological position of [...] Read more.
The Porya Guba clinopyroxenite–wehrlite complex is located in the core of the Lapland–Kola collisional orogen (~2.0–1.9 billion years old) in the northeastern part of the Fennoscandian Shield and contains iron–titanium–vanadium and nickel–copper mineralization with platinum group elements (PGEs). The controversial geological position of the complex within the mafic granulites of the Kolvitsa mélange (pre-, syn- or post-orogenic) is clarified by Sm-Nd isotopic dating of the rocks and mineralization. The Sm-Nd age of the barren clinopyroxenites that dominate the complex is 1858 ± 34 Ma (εNd(T) = −1.5) and is interpreted as the time of its emplacement as evidenced by a sample from the largest intrusion, named Zhelezny. This age is younger than that of the peak of granulite metamorphism in the host rocks (1925–1915 Ma) and coincides within error with the age of rutile from granulites (1880–1870 Ma), indicating the time at which cooling to 450 °C occurs. Emplacement in the cooled rocks is confirmed by the detection of quenching zones in clinopyroxenites around granulite xenoliths. Magnetite ores, as well as mineralized pyroxenites with sulfide disseminations, are formed during a late stage of the complex development, as suggested by active assimilation of granulite xenoliths by these rocks. The isotopic age of mineralized pyroxenites enriched in PGEs is 1832 ± 35 Ma (εNd(T) = –2.0), while the age of magnetite ores is 1823 ± 19 Ma (εNd(T) = –2.5). Thus, the obtained isotopic data indicate that the emplacement of the Porya Guba complex and probably other small mafic–ultramafic intrusions in the Kolvitsa mélange granulites took place after the end of the Lapland–Kola collision. Full article
Show Figures

Figure 1

21 pages, 6293 KiB  
Article
The Formation Age and Magma Source of the Xiaonanshan–Tunaobao Cu-Ni-PGE Deposit in the Northern Margin of the North China Craton
by Guanlin Bai, Jiangang Jiao, Xiaotong Zheng, Yunfei Ma and Chao Gao
Minerals 2024, 14(7), 733; https://doi.org/10.3390/min14070733 - 22 Jul 2024
Viewed by 1114
Abstract
The Xiaonanshan–Tunaobao Cu-Ni-PGE deposit is located in the northern margin of the North China Craton (N-NCC) in central Inner Mongolia. However, the age, magma source, petrogenesis, and sulfide mineralization mechanism of the ore-related Xiaonanshan-Tunaobao pluton remain unclear. Zircon U-Pb dating indicates the Tunaobao [...] Read more.
The Xiaonanshan–Tunaobao Cu-Ni-PGE deposit is located in the northern margin of the North China Craton (N-NCC) in central Inner Mongolia. However, the age, magma source, petrogenesis, and sulfide mineralization mechanism of the ore-related Xiaonanshan-Tunaobao pluton remain unclear. Zircon U-Pb dating indicates the Tunaobao pluton formed at 275.9 ± 2.8 Ma (Early Permian), similar to the Xiaonanshan pluton (272.7 ± 2.9 Ma). The ore-related gabbro is enriched in LREE and LILE (e.g., Rb) and depleted in HREE and HFSE (e.g., Nb and Ti). It likely originated from enriched mantle metasomatized by subduction fluids, supported by enriched Hf-Nd isotopes (–34.34 to –6.16 for zircon εHf(t) and –7.24 to –5.92 for whole-rock εNd(t) values) and high Ba/La but low Rb/Y ratios. The δ34S values of the Xiaonanshan sulfides range from 4.5‰ to 11.4‰, indicating a mantle origin with contribution from surrounding rocks. Combining previous recognition with this study, we propose that the Xiaonanshan–Tunaobao pluton formed in a post-collision extensional setting. Full article
(This article belongs to the Special Issue Mineral Resources in North China Craton)
Show Figures

Figure 1

28 pages, 16832 KiB  
Article
The Tepsi Ultrabasic Intrusion, the Northern Part of the Lapland–Belomorian Belt, Kola Peninsula, Russia
by Andrei Y. Barkov, Andrey A. Nikiforov, Robert F. Martin, Sergey A. Silyanov and Boris M. Lobastov
Minerals 2024, 14(7), 685; https://doi.org/10.3390/min14070685 - 29 Jun 2024
Cited by 3 | Viewed by 1170
Abstract
The Tepsi ultrabasic body is located in the northeastern Fennoscandian Shield close to the junction of the Serpentinite Belt–Tulppio Belt (SB–TB) with suites of the Lapland–Belomorian Belt (LBB) of Paleoproterozoic age. The body is a deformed laccolith that has tectonic contacts with Archean [...] Read more.
The Tepsi ultrabasic body is located in the northeastern Fennoscandian Shield close to the junction of the Serpentinite Belt–Tulppio Belt (SB–TB) with suites of the Lapland–Belomorian Belt (LBB) of Paleoproterozoic age. The body is a deformed laccolith that has tectonic contacts with Archean rocks. Its primary textures and magmatic parageneses are widely preserved. Fine-grained olivine varies continuously from Fo90.5 to Fo65.4. The whole-rock variations in MgO, Fe2O3, SiO2, and other geochemical data are also indicative of a significant extent of differentiation. Compositional variations were examined in the grains of calcic and Mg-Fe amphiboles, clinochlore, micas, plagioclase, members of the chromite–magnetite series, ilmenite, apatite, pentlandite, and a number of other minor mineral species. Low-sulfide disseminated Ni-Cu-Co mineralization occurred sporadically, with the presence of species enriched in As or Bi, submicrometric grains rich in Pt and Ir, or diffuse zones in pentlandite enriched in (Pd + Bi). We recognize two series: the pentlandite series (up to 2.5–3 wt.% Co) and the cobaltpentlandite series (~1 to ~8 apfu Co). The latter accompanied serpentinization. The two series display differences in their substitutions: Ni ↔ Fe and Co → (Ni + Fe), respectively. Relative enrichments in H2O, Cl, and F, observed in grains of apatite (plus high contents of Cl in hibbingite or parahibbingite), point to the abundance of volatiles accumulated during differentiation. We provide the first documentation of scheelite grains in ultrabasic rocks, found in evolved olivine-rich rocks (Fo77–72). We also describe unusual occurrences of hypermagnesian clinopyroxene associated with tremolite and serpentine. Abundant clusters of crystallites of diopside display a microspinifex texture. They likely predated serpentinization and formed owning to rapid crystallization in a differentiated portion of a supercooled oxidized melt or, less likely, fluid, after bulk crystallization of the olivine. We infer that the laccolithic Tepsi body crystallized rapidly, in a shallow setting, and could thus not form megacycles in a layered series or produce a well-organized structure. Our findings point to the existence of elevated PGE-Au-Ag potential in numerous ultrabasic–basic complexes of the SB–TB–LBB megastructure. Full article
Show Figures

Figure 1

7 pages, 1689 KiB  
Proceeding Paper
Mining and Mineral Exploration Projects within the Natura 2000 Area: Case Studies from Northern Finland
by Toni Eerola, Nike Luodes and Hannu Panttila
Mater. Proc. 2023, 15(1), 86; https://doi.org/10.3390/materproc2023015086 - 24 Apr 2024
Viewed by 2175
Abstract
The Rompas–Prajapat (Au-Co) and Sakatti (Ni-Cu-PGE) mineral deposits are among the only important discoveries of the last few decades in Finland. Both are partially located in Natura 2000 areas, which are among the most sensitive land use contexts in which mining and mineral [...] Read more.
The Rompas–Prajapat (Au-Co) and Sakatti (Ni-Cu-PGE) mineral deposits are among the only important discoveries of the last few decades in Finland. Both are partially located in Natura 2000 areas, which are among the most sensitive land use contexts in which mining and mineral disputes have emerged in Finland. Consequently, the project holders apply low-impact mineral exploration technologies and practice active stakeholder engagement and communication. In fact, projects seem to be mostly favored by local populations. However, because of their association with protected areas (and uranium in the case of Rompas), projects are opposed by non-governmental organizations, as well as by reindeer herders in the case of Sakatti. Project holders perform feasibility studies and environmental impact assessments. Mining licenses are applied under a new Finnish mining act and the European Union’s Raw Materials acts. Full article
Show Figures

Figure 1

27 pages, 14617 KiB  
Article
Mineral and S-Isotope Compositions of Cu-Sulfide Deposits in Southern Siberia (Kodar–Udokan Region), Russia
by Bronislav Gongalsky, Tatyana Velivetskaya and Vladimir Taskaev
Minerals 2024, 14(3), 228; https://doi.org/10.3390/min14030228 - 24 Feb 2024
Cited by 2 | Viewed by 2711
Abstract
The Kodaro–Udokan region is a huge Cu metallogenic province in Southern Siberia, one of the largest on Earth. It contains world-class copper sandstone-hosted Udokan (Cu reserves of 26.7 Mt) and PGE-Ni-Cu Chineysky deposits related to gabbro–anorthosite pluton (Cu—10 Mt; Fe-Ti-V, 30 Gt of [...] Read more.
The Kodaro–Udokan region is a huge Cu metallogenic province in Southern Siberia, one of the largest on Earth. It contains world-class copper sandstone-hosted Udokan (Cu reserves of 26.7 Mt) and PGE-Ni-Cu Chineysky deposits related to gabbro–anorthosite pluton (Cu—10 Mt; Fe-Ti-V, 30 Gt of ore). Furthermore, there are many small deposits of sulfide ores in sedimentary and igneous rocks in this region as well. For many decades, their genesis has been hotly debated. We studied the mineral composition and the sulfur isotopes in several deposits located at different levels of the stratigraphic sequence and in gabbro intruded in sandstones of the Udokan complex. The differences in ore compositions were found. The Burpala and Skvoznoy deposits consisting of the chalcocite–bornite association are characterized only by negative δ34S. The δ34S values for the Udokan deposits are mostly <0 (up to −28‰). The positive δ34S data characterize the ores of the Chineysky and Luktursky intrusions. Two Cu sandstone-hosted deposits are characterized by complex ore composition, i.e., the Krasny deposit, comprising chalcopyrite–pyrrhotite ores, is enriched in Co, Ni, Bi, Sb, Mo, Pb, Zn, Se, Te, and U and has a wide range of δ34S = −8.1–+13.5‰, and the Pravoingamakitsky deposit (Basaltovy section), consisting of quartz–chalcopyrite veins, has high PGE contents in ores with δ34S = +2.9–+4.0‰. These deposits are located near the gabbro massifs, and it is supposed that their ore compositions were influenced by magmatic fluids. The general regularities of the localization of the deposits in rift zones, and the proximity of mineral and isotopic composition allow us to conclude that the main source of copper could be rocks of basic composition because only they contain high Cu contents. Fluids from deep zones could penetrate to the surface and form Cu sandstone-hosted deposits. Full article
Show Figures

Figure 1

22 pages, 4750 KiB  
Review
Fertility Indicators for Porphyry-Cu-Au+Pd±Pt Deposits: Evidence from Skouries, Chalkidiki Peninsula, Greece, and Comparison with Worldwide Mineralizations
by Maria Economou-Eliopoulos, Federica Zaccarini and Giorgio Garuti
Minerals 2023, 13(11), 1413; https://doi.org/10.3390/min13111413 - 6 Nov 2023
Cited by 2 | Viewed by 2389
Abstract
The research interest for many authors has been focused on the origin, recovery, and exploration of critical metals, including platinum-group elements (PGEs), with the aim of finding new potential sources. Many giant porphyry Cu deposits are well known around the Pacific Rim, in [...] Read more.
The research interest for many authors has been focused on the origin, recovery, and exploration of critical metals, including platinum-group elements (PGEs), with the aim of finding new potential sources. Many giant porphyry Cu deposits are well known around the Pacific Rim, in the Balkan–Carpathian system, Himalayas, China, and Malaysia. However, only certain porphyry Cu-Au deposits are characterized by the presence of significant Pd and Pt contents (up to 20 ppm). This contribution provides new analytical data on porphyry-Cu-Au±Pd±Pt deposits from the Chalkidiki Peninsula and an overview of the existing geochemical characteristics of selected porphyry-Cu deposits worldwide in order to define significant differences between PGE-fertile and PGE-poor porphyry-Cu intrusions. The larger Mg, Cr, Ni, Co, and Re contents and smaller LILE elements (Ba and Sr) in fertile porphyry-Cu-Au-(PGE) reflect the larger contribution from the mantle to the parent magmas. In contrast, the smaller Mg, Cr, Ni, Co, and Re contents and larger Ba and Sr in PGE-poor porphyry-Cu-Mo deposits from the Chalkidiki Peninsula (Vathi, Pontokerasia, and Gerakario) and Russia–Mongolia suggest the presence of parent magmas with a more crustal contribution. Although there is an overlap in the plots of those elements, probably due to the evolution of the ore-forming system, consideration of the maximum contents of Mg, Cr, Ni, and Co is proposed. Magnetite which separated from the mineralized Skouries porphyry of Greece showed small negative Eu anomalies (Eu/Eu* ≥ 0.55), reflecting a relatively high oxidation state during the cooling of the ore-forming system. The relatively high, up to 6 ppm (Pd+Pt), and low Cr content towards the transition from the porphyry to epithermal environment, coupled with the occurrence of Pd, Te, and Se minerals (merenskyite, clausthalite), and tetrahedrite–tennantite in fertile porphyry Cu deposits (Elatsite deposit, Bulgaria), reflect a highly fractionated ore-forming system. Thus, in addition to the crustal and mantle recycling, metasomatism, high oxidation state, and abundant magmatic water, other factors required for the origin of fertile porphyry-Cu deposits are the critical degree of mantle melting to release Pt and Pd in the ore-forming fluids and the degree of fractionation, as reflected in the mineral chemistry and geochemical data. Full article
Show Figures

Figure 1

22 pages, 8725 KiB  
Article
Using 1D Thermal Modeling to Evaluate Formation Models of Mafic-Ultramafic Intrusions and Associated Sulfide Cu-Ni-PGE Mineralization
by Dmitry Stepenshchikov and Nikolay Groshev
Minerals 2023, 13(8), 1046; https://doi.org/10.3390/min13081046 - 6 Aug 2023
Viewed by 1455
Abstract
In this paper, we trace the thermal history of the mafic–ultramafic intrusions of the Monchegorsk (MC), Fedorova–Pana (FPC), and Norilsk ore-bearing complexes (NC) using an upgraded version of the author’s software Gehenna 2.2. It is shown that a key role in the concentration [...] Read more.
In this paper, we trace the thermal history of the mafic–ultramafic intrusions of the Monchegorsk (MC), Fedorova–Pana (FPC), and Norilsk ore-bearing complexes (NC) using an upgraded version of the author’s software Gehenna 2.2. It is shown that a key role in the concentration of sulfides in the lower parts of the intrusions belongs to the preliminary heating of the host rocks by early magmatic influxes. In the presence of late ore-bearing magmatic phases of a relatively small volume, the pattern of sulfide distribution within such a phase can be used to estimate the time gap with the main influx. Thermal modeling shows that the Gabbro-10 massif, an additional ore-bearing phase of the Nyud-Poaz intrusion of the MC, is separated from the main influx by a time gap of no more than 100 ka, while the minimum gap between the magmatic phases of the Fedorova intrusion of the FPC is 650–700 ka. The development of a hornfels halo around mafic–ultramafic rocks makes it possible to estimate the duration of the process of continuous magma flow inside intrusions, which, as an example from the Kharaelakh intrusion of the NC shows, can reach 1000 years and more. Thermal modeling is recommended both for formulating genetic hypotheses and for testing different scenarios for the formation of sulfide Cu-Ni-PGE mineralization in mafic–ultramafic complexes. Full article
Show Figures

Figure 1

38 pages, 5802 KiB  
Review
Palladian Gold: Chemical Composition, Minerals in Association, and Physicochemical Conditions of Formation at Different Types of Gold Deposits
by Galina A. Palyanova, Pavel S. Zhegunov, Tatiana V. Beliaeva, Valery V. Murzin, Andrey A. Borovikov and Nikolay A. Goryachev
Minerals 2023, 13(8), 1019; https://doi.org/10.3390/min13081019 - 30 Jul 2023
Cited by 8 | Viewed by 3338
Abstract
This paper reviews and summarizes the available information on the composition of palladian gold with various contents and sets of isomorphic impurities (Ag, Cu, Hg) at 50 deposits and ore occurrences with Au-Pd mineralization. It is revealed that Palladian gold is represented by [...] Read more.
This paper reviews and summarizes the available information on the composition of palladian gold with various contents and sets of isomorphic impurities (Ag, Cu, Hg) at 50 deposits and ore occurrences with Au-Pd mineralization. It is revealed that Palladian gold is represented by the systems Au–Pd, Au–Pd–Hg, Au–Pd–Cu, and Au–Pd–Ag–Hg, but more frequently corresponds to Au–Pd–Ag, Au–Pd–Ag–Cu, and Au–Pd–Ag–Cu–Hg. Objects with palladian gold belong to different types of gold deposits and to the deposits at which the main components of ores are PGE, Cr, Cu, Ni, V, and Ti. We propose a classification of the types of deposits with palladian gold: (1) PGE ore deposits related to mafic–ultramafic magmatic complexes (two subtypes—(a) low-sulfide-grade (less than 2%–5% sulfides) Alaskan, and (b) high-sulfide-grade (more than 5% sulfides) Norilsk); (2) orogenic gold deposits (OG); (3) epithermal (porphyry) gold–copper deposits (EPGC); (4) iron oxide copper gold deposits (IOCG); (5) ferruginous quartzite deposits; (6) volcanic exhalation; and (7) gold-PGE placers of five subtypes corresponding to the types of 1–5 primary sources. Physicochemical conditions of the formation of palladian gold at some deposits of type 1 cover two areas—magmatic high-temperature and hydrothermal low-temperature. At the majority of deposits of types 2–4, its formation proceeds with the participation of hydrothermal fluids (300–60 °C) of various salinities (0.2–30 wt.% NaCl eq.). Palladian gold is mainly high-fineness (910‰–990‰), is less frequently medium-fineness, and contains Ag and Cu, but does not contain Hg at the deposits of types 1, 3, and 4. The only exception is the Au-Pd-Hg Itchayvayam ore occurrence (Kamchatka, Russia), for which two varieties of Pd,Hg-bearing native gold (fineness 816‰–960‰ and 580‰–660‰) are determined. Low-fineness palladian gold with the major content of Ag is typical of OGD deposits. Medium-fineness palladian gold occurs at ferruginous quartzite deposits and in volcanic exhalations. Hg, Ag, Cu-bearing high-fineness palladian gold is present mainly in placer deposits (type 7). The most common minerals in association with palladian gold are arsenides, stibioarsenides, sulfides, stannides, bismuthides, tellurides, and selenides of Pd and Pt. These are typical of deposit types 1 and 7. The minerals of Au, Ag, and Cu (tetra-auricupride, aurostibite, chalcopyrite, bornite, chalcocite, eucairite, etc.) are in association with palladian gold at OG, EPGC, and IOCG deposits. Hg minerals (cinnabar, tiemannite, coloradoite, potarite) are at some deposits (types 1, 2, 7-1, 7-4). Cu, Fe, and Pd oxides (tenorite, hematite, magnetite, PdO, (Pd,Cu)O) and Fe and Pd hydroxides (goethite, (Fe,Pd)OOH) occur at the deposits of the 3, 4, and 7 groups and indicate the highly oxidizing conditions of ore formation. The most common minerals among host minerals are quartz and muscovite, including fuchsite (Cr-Ms), chlorite, albite, K-feldspar, hornblende, and carbonates (calcite, siderite, etc.). The fineness, content, and set of impurities in palladian gold and minerals in association with it reflect the mineralogy of Au-Pd ores and allow them to be used as indicators for the deposit types. Full article
(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits)
Show Figures

Figure 1

24 pages, 34695 KiB  
Article
Petrology and Age of the Yamaat Uul Mafic Complex, Khangai Mountains, Western Mongolia
by Roman Shelepaev, Maria Shapovalova, Vera Egorova, Yaroslav Shelepov, Tumen-Ulzii Oyunchimeg and Nadezhda Tolstykh
Minerals 2023, 13(6), 833; https://doi.org/10.3390/min13060833 - 20 Jun 2023
Cited by 1 | Viewed by 1785
Abstract
The Yamaat Uul mafic complex with Cu-Ni mineralization is located in the Khangai Mountains of Western Mongolia. We have received new unique data for mafic rocks of the complex: U-Pb dating (SHRIMP II), mineralogy (WDS) and geochemistry (XRF, ICP-MS), Sm-Nd and Rb-Sr isotope [...] Read more.
The Yamaat Uul mafic complex with Cu-Ni mineralization is located in the Khangai Mountains of Western Mongolia. We have received new unique data for mafic rocks of the complex: U-Pb dating (SHRIMP II), mineralogy (WDS) and geochemistry (XRF, ICP-MS), Sm-Nd and Rb-Sr isotope data and sulphur isotopes. The Yamaat Uul mafic complex consists of two intrusions: Intrusion 1 is represented by rocks of plagioclase cumulates and olivine–pyroxene cumulates; Intrusion 2 consists of monzogabbro. Intrusions 1 and 2 are different in composition of minerals such as olivine, plagioclase and biotite. The monzogabbro has higher contents of incompatible elements (REE, K, Ti, P) than rocks of Intrusion 1. Zircon U-Pb dating of the anorthosite and Bt-Am-Ol gabbronorite shows a Late Permian age (255.8 ± 2.9 Ma and 262.6 ± 3.1 Ma, respectively) for the Yamaat Uul mafic complex. All of the rocks of the complex are derived from a unified parental melt due to different amounts of trapped melts in plagioclase and olivine–pyroxene cumulates and without crustal contamination. The Cu-Ni mineralization of the complex has a low degree of evolution of the sulphide melt, similar to PGE-Cu-Ni mafic–ultramafic intrusions of the Khangai Mountains (Nomgon and Oortsog Uul). The Yamaat Uul mafic complex together with other mafic–ultramafic intrusions of the Khangai Mountains is related to the Khangai LIP and can be considered as potential for the PGE-Cu-Ni. The new geological, petrological, geochemical and isotope–geochronological data can later be used to reconstruct the geotectonics of the Khangai Mountains and the Central Asian orogenic belt as a whole. Full article
(This article belongs to the Special Issue Large Igneous Provinces: Research Frontiers)
Show Figures

Figure 1

Back to TopTop