Search Results (31)

The effect of 0.2%Cr addition on the structure, phase composition, and mechanical properties of the novel cast and wrought Al-2.5Zn-2.5Mg-2.5Cu-0.2Zr-Er(Y) alloys were investigated in detail. Chromium is distributed between primary crystals (5.7–6.8%) of the intermetallic phase and the aluminum solid solution (0.2%) (Al). The primary crystals contain for the main part Cr, Ti, Er(Y). The experimental phase composition is in good correlation with the thermodynamic computation data. The micron-sized solidification origin phases (Al₈Cu₄Er(or Y) and Mg₂Si) and supersaturated (Al) with nano-sized Al₃(Zr,Ti) and E (Al₁₈Mg₃Cr₂) precipitates are presented in the microstructure of the novel alloys after solution treatment. The nucleation of η (MgZn₂) (0.5%), S (Al₂CuMg) (0.4%), and T (Al,Zn,Mg,Cu) (8.8%) phase precipitates at 180 °C, providing the achievement of a maximum hardness of 135 HV in the Al2.5Zn2.5Mg2.5CuYCr alloy. The corrosion potential of the novel alloy is similar to the E_cor of the referenced alloy, but the corrosion current density (0.68–0.98 µA/sm²) is still significantly lower due to the formation of E (Al₁₈Mg₃Cr₂) precipitates and S phase precipitates of the aging origin, in addition to the T phase. The formation of E (Al₁₈Mg₃Cr₂) precipitates under the solution treatment provides a lower proportion of recrystallized grains (2.5–5% vs. 22.4–25.1%) and higher hardness (110 HV vs. 85–95 HV) in the Cr-rich alloys compared to the referenced alloys. Solution treated, hot and cold rolled, recrystallized, water quenched and aged at 210 °C alloys demonstrate an excellent microstructure stability and tensile properties: YS = 299–300 MPa, UTS = 406–414 MPa, and El. = 9–12.3%. Full article

The engineering application of additively manufactured (AM) metallic materials is quite limited by their fatigue behaviors, which are very inconsistent with that of conventionally wrought or cast ones. Here, based on advanced material characterization techniques, such as focused ion beam (FIB), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), the microstructures underneath fracture surfaces were thoroughly investigated in an AM aluminum (AlSi10Mg) alloy with horizontal and vertical building orientation enduring very high cycle fatigue (VHCF) loading under the stress ratios R = −1, 0, and 0.5. Two VHCF failure specimens A and B were representatively selected to further examine SEM and TEM sample preparation via FIB milling. Specimen A was horizontally printed and failed at R = −1; specimen B was vertically printed and failed at R = 0. TEM samples A1 and B1 were lifted from locations near the crack initiation sites on the fracture surfaces of specimens A and B; The locations of TEM samples A2 and B2 kept away from the crack origin sites but still within the “fish-eye” region of crack steady growth. TEM observations show that there was no characteristic microstructure induced by VHCF in different oriented specimens and under various R values. Full article

Low sensitivity to hot cracking is very important not only for casting but also for ingots of wrought alloys. Doping of Al-Cu-(Mg) alloys by eutectic forming elements provides an increasing resistance to hot cracking susceptibility, but it also leads to a decrease in plasticity. The quasi-binary alloys based on an Al-Cu-REM system with an atomic ratio of Cu/REM = 4 have a high solidus temperature, narrow solidification range and fine microstructure. The detailed investigation of microstructure, precipitation and hot deformation behavior, and mechanical properties of novel Al-Cu-Y-Mg-Cr-Zr-Ti-Fe-Si alloy was performed in this study. The fine Al₈Cu₄Y, needle-shaped Al₁₁Cu₂Y₂Si₂, compact primary (Al,Ti)₈₄Cu_6.4Y_4.3Cr_5.3 and Q (Al₈Cu₂Mg₈Si₆) phases were identified in the as-cast microstructure. Near-spherical coarse Al₃(Zr,Y) and fine Al₄₅Cr₇ precipitates with a size of 60 nm and 10 nm were formed after 3 h of solution treatment at 580 °C. S′(Al₂CuMg) precipitates with an average diameter of 140 nm, thickness of 6 nm and calculated volume fraction of 0.033 strengthened 36 HV during aging at 210 °C for 3 h. Three-dimensional hot processing maps demonstrated an excellent and stable deformation behavior at 440–540 °C and strain rates of 0.01–10 s⁻¹. The rolled sheets had a good combination of yield strength (313 MPa) and plasticity (10.8%) in the recrystallized at 580 °C, with water quenched and aged at 210 °C for a 3 h state. The main calculated effect in the yield strength was contributed by Al₄₅Cr₇ precipitates. Full article

The purpose of this investigation is to improve the mechanical properties of AlMnFeMgSi wrought alloys by forming a high number density of nano-scaled strengthening dispersoids during homogenisation annealing. The process chain for AlMnFeMgSi wrought alloys includes homogenisation annealing after continuous casting. In this step, inhomogeneities and segregations are dissolved and dispersoids are precipitated. The formed dispersoids hinder grain growth, but usually cannot increase the strength due to their coarse size of some 100 nm. Lower homogenisation temperatures should result in the precipitation of smaller dispersoids during homogenisation. The addition of Zr was investigated to increase this effect. Zr should form further dispersoids from the Al₃Zr phase. This requires a fundamental understanding of the temperature-dependent kinetics and the nature of precipitation formation during homogenisation. For this purpose, the as-cast state is first characterised via differential scanning calorimetry. Subsequently, a large number of homogenisation parameters are investigated and quantified via hardness testing. The micro- and nanostructure are investigated for promising parameters and a particle analysis is performed. In the present study, it was possible to precipitate fine dispersoids of few 10 nm by reducing the homogenisation temperature, which resulted in a significant increase in hardness. Alloying with Zr enabled the precipitation of further dispersoids with a size of a few nm in a high number density, which further increased the strength. Full article

The importance of both recycling and additive manufacturing (AM) is increasing; however, there has been a limited focus on the development of AM alloys that are compatible in terms of recyclability with the larger scrap loops of wrought 5xxx, 6xxx and cast 3xx aluminium alloys. In this work, the powder bed fusion (PBF) printability of AlMgSi alloys in the interval of 0–30 wt% Mg and 0–4 wt% Si is screened experimentally with a high-throughput method. This method produces PBF-mimicked material by PVD co-sputtering, followed by laser remelting. Strong evidence was found for AlMgSi alloys being printable within two different composition ranges: Si + Mg < 0.7 wt% or for Si + 2/3 Mg > 4 wt% when Mg < 3 wt% and Si > 3 wt%. Increasing the amount of Mg and Si influences the grain structure by introducing fine columnar grains at the melt pool boundary, although the melt pool interior was unaffected. Hardness in an as-built state increased with both Mg and Si, although Si had a neglectable effect at low levels of Mg. Both the evaporative loss of Mg and the amount of Mg in solid solution increased linearly with the amount of Mg. Full article

Aluminum alloy 6201 is a wrought, heat-treatable alloy, which is used in electricity transmission and distribution lines. The alloy is processed in a commercial continuous casting and rolling system, which includes a series of in-line thermomechanical processes involving hot working, quenching, cold working and artificial aging. In this study and following cold working, the alloy is subjected to a solution heat treatment at 510 °C for an hour, quenched in ice water, and artificially aged at various temperatures for various times (150–200 °C for 2–30 h) (T6-temper) in order to investigate the effect of precipitation on mechanical properties and electrical conductivity. The results show that optimum mechanical properties and electrical conductivity were obtained after artificial aging at 155 °C for 30 h (155-30). The tensile strength was almost equal to that of the as received cold drawn wire of 326 MPa, but interestingly, electrical conductivity significantly increased to 58.6% IACS from a value of 52.7% IACS of the as received cold drawn wire. Intermetallic particles α-AlFeSi (Al₈Fe₂Si) and β-AlFeSi (Al₅FeSi and Al₉Fe₂Si₂) were observed in all samples, which were nucleated during solidification and homogenization; they were not affected by the aging process. β″/β′/β -precipitates formed during artificial aging, which affected the final mechanical properties and the final electrical conductivity. Full article

High-Si aluminum foundry alloys are an important material class for products with complex 3D geometries where casting is the most suitable production method. With Mg and/or Cu additions, these alloys gain strength upon heat treatment due to the formation of nanoprecipitates. These precipitated phases are of the same kind as in the wrought Al–Mg–Si(–Cu) alloys having much lower Si contents, which have been the subject of a high number of studies. Some of these studies indicate that atomic clusters formed during storage at room temperature have a strong effect on the phases that evolve during artificial aging. In this work, foundry alloys containing Si, Mg, and Cu are investigated. Room-temperature storage is found to have a great influence on kinetics during early aging. Cu additions accelerate the formation of hardening precipitates during early aging, but 1 month of room-temperature storage negates the positive effect of Cu. The maximum achievable strength is found to be limited mainly by the solubility limits of Si and Mg at the solution heat treatment temperature. With insights derived from transmission electron microscopy and atom probe tomography results, this study contributes to the understanding of the solute balance and early aging kinetics and how wrought and foundry alloys differ in these respects. Full article

In this study, a newly developed high-strength cast Fe81Cr15V3C1 (wt%) steel with a high resistance against dry abrasion and chloride-induced pitting corrosion is presented. The alloy was synthesized through a special casting process that yielded high solidification rates. The resulting fine, multiphase microstructure is composed of martensite, retained austenite and a network of complex carbides. This led to a very high compressive strength (>3800 MPa) and tensile strength (>1200 MPa) in the as-cast state. Furthermore, a significantly higher abrasive wear resistance in comparison to the conventional X90CrMoV18 tool steel was determined for the novel alloy under very harsh wear conditions (SiC, α-Al₂O₃). Regarding the tooling application, corrosion tests were conducted in a 3.5 wt.% NaCl solution. Potentiodynamic polarization curves demonstrated a similar behavior during the long-term testing of Fe81Cr15V3C1 and the X90CrMoV18 reference tool steel, though both steels revealed a different nature of corrosion degradation. The novel steel is less susceptible to local degradation, especially pitting, due to the formation of several phases that led to the development of a less dangerous form of destruction: galvanic corrosion. In conclusion, this novel cast steel offers a cost- and resource-efficient alternative to conventionally wrought cold-work steels, which are usually required for high-performance tools under highly abrasive as well as corrosive conditions. Full article

The physical and mechanical properties of an entirely (wrought alloys) or partly (cast alloys) dendritically solidified alloy strongly depend on the secondary dendrite arm spacing (SDAS). The casting practice and the simulation of solidification need a usable but simple method to calculate the SDAS during and at the end of solidification as a function of the cooling rate. Based on many solidification experiments, a simple equation to calculate the SDAS (empirical method) is known to use the local solidification time, which can be obtained from the measured cooling curves (equiaxed solidification), or can be calculated from the temperature gradient and front velocity (directional solidification). This equation is not usable for calculating the SDAS during solidification. Kirkwood developed a semi-empirical method based on the liquid phase’s diffusion, which contains only one geometric factor that seems constant for different alloys. This equation contains some physical parameters that depend on the temperature, so the equation cannot be integral in closed form. In the present work, first, we show the effect of the curvature of the solid/liquid interface on the equilibrium concentrations and then the different processes of SDA coarsening. In our earlier paper, we demonstrated that using the empirical method, the final SDAS can be calculated with acceptable correctness in the case of four unidirectional solidification experiments of Al-7wt%Si alloy. The present work shows that numerically integrated Kirkwood’s equations used the known cooling curve; the SDAS can be calculated at the end and during solidification in good agreement with these experimental results. Compared to the two calculation methods, we stated that the correctness of the methods is similar. Still, the results of the solidification simulation (the microsegregation) will be more correct using the dynamical method. It is also shown that with the dynamical method, the SDAS can be calculated from any type of cooling curve, and using the dynamical method, it is proved that some different SDASs could belong to the same local solidification time. Full article

Aging behavior of wrought Al-12.7Si-0.7 Mg alloy was investigated during isothermal aging at 180 °C. Two aging peaks were observed at 3 h and 8 h, respectively. To examine precipitate evolution during aging, the alloy’s microstructure in different aging states was investigated by regular and high-resolution transmission electron microscopy (TEM and HRTEM). The results revealed that the variation of mechanical properties is attributed to the combining effect of Si particles, the grain boundary, and the character of precipitates. The predominant precipitates’ type, size, and volume fraction vary as aging time increases. Full article

In this paper, the results from studies regarding near-eutectic Al-Si alloys with Sn as an alloying addition are presented. In most Al-Si alloys, tin is regarded as a contaminant; thus, its amount is limited to up to 0.3 wt.%. The few studies that can be found in the literature regarding the behaviour of tin in aluminium alloys suggest the beneficial effect of this element on selected properties. However, these results were obtained for hypereutectic Al-Si alloys or wrought aluminium alloys. In our studies, the influence of tin contents of up to 1.7 wt.% was determined on the AlSi10 alloy. Thermal analysis, measurements of the mechanical properties of the cast and heat-treated alloy, metallographic observations (light microscopy, scanning electron microscopy), and EDS (X-ray energy dispersive spectrometry) measurement allowed us to fully describe the effect of tin on the aluminium alloy. The results of the thermal analysis showed changes in the range of the α-Al solution crystallisation and the α+β eutectic through a decrease in the alloy’s solidification start point and eutectic solidification point. As a result, the elongation of the alloy was more than double in the AlSi10Sn1.7 alloy, with an A5 value of 8.1% and a tensile strength that was above 200 MPa. Full article

Gas-atomized powders are frequently used in metal additive manufacturing (MAM) processes. During consolidation, certain properties and microstructural features of the feedstock can be retained. Such features include porosity, secondary phases, and oxides. Of particular importance to alloys such as Al 6061, secondary phases found in the feedstock powder can be directly related to those of the final consolidated form, especially for solid-state additive manufacturing. Al 6061 is a heat-treatable alloy that is commonly available in powder form. While heat treatments of 6061 have been widely studied in wrought form, little work has been performed to study the process in powders. This work investigates the evolution of the Fe-containing precipitates in gas-atomized Al 6061 powder through the use of scanning and transmission electron microscopy (SEM and TEM) and energy dispersive X-ray spectroscopy (EDS). The use of coupled EDS and thermodynamic modeling suggests that the as-atomized powders contain Al₁₃Fe₄ at the microstructure boundaries in addition to Mg₂Si. After one hour of thermal treatment at 530 °C, it appears that the dissolution of Mg₂Si and Al₁₃Fe₄ occurs concurrently with the formation of Al₁₅Si₂M₄, as suggested by thermodynamic models. Full article

The impact of the artificial aging response on the microstructure and tensile mechanical properties of aluminum alloy 6156 was investigated. Specimens were artificially aged at three different artificial aging temperatures and for various holding times to investigate all possible aging conditions, including the under-aged (UA), peak-aged (PA) and over-aged (OA) tempers. Microstructural investigation as well as tensile tests were performed immediately after the isothermal artificial aging heat treatment. An almost 50% increase in yield stress (around 340 MPa) was noticed in the PA temper and this was attributed to the precipitation of β′ and Q′ phases, consistent with the modelling predictions. This high yield stress value is accompanied by high values of elongation at fracture (>10%) that is essential for damage tolerance applications. The lack of large or interconnected grain boundary precipitates contributes to this high elongation. Slanted fracture was noticed for both UA and PA tempers, exhibiting a typical ductile and shear fracture mechanism. At the OA temper, coarsening of the precipitates along with broadening of the precipitate free zones resulted in a reduction in the strengthening effectiveness of the precipitates, and a small increase in the tensile ductility of approximately 12% was noticed. Full article

Electron beam directed energy deposition (EB-DED) is a promising manufacturing process for the fabrication of large-scale, fully dense and near net shape metallic components. However, limited knowledge is available on the EB-DED process of titanium alloys. In this study, a near-α high-temperature titanium alloy Ti60 (Ti-5.8Al-4Sn-4Zr-0.7Nb-1.5Ta-0.4Si) was fabricated via EB-DED. The chemical composition, microstructure, tensile property (at room temperature and 600 °C), and creep behavior of the fabricated alloy were investigated and compared with those of the conventional wrought lamellar and bimodal counterparts. Results indicated that the average evaporation loss of Al and Sn was 10.28% and 5.01%, respectively. The microstructure of the as-built alloy was characterized by coarse columnar grains, lamellar α, and the precipitated elliptical silicides at the α/β interfaces. In terms of tensile properties, the vertical specimens exhibited lower strength but higher ductility than the horizontal specimens at both room temperature and 600 °C. Furthermore, the tensile creep strain of the EB-DED Ti60 alloy measured at 600 °C and 150 MPa for 100 h under as-built and post-deposition STA conditions was less than 0.15%, which meets the standard requirements for the wrought Ti60 alloy. The creep resistance of the EB-DED Ti60 alloy was superior to that of its wrought bimodal counterpart. Full article

This paper presents a comprehensive study conducted to optimize the mechanical properties for a laser-melting-deposition fabricated TC31 (Ti-Al-Sn-Zr-Mo-Nb-W-Si) alloy, which is a newly developed high-temperature alloy used in the aerospace industry. The results showed that the laser melting deposition (LMD)-built sample exhibited columnar structures with very fine α-laths inside. Annealing and solution treatment resulted in an α+β lamellar structure consisting of α-laths and β-films, of which thicknesses depended on the temperature. Solution treatment and subsequent aging did not significantly change the lamellar structure. However, aging at 650 °C led to the formation of nanoscale α precipitates within the remaining β, while aging at 750 °C resulted in coarse α precipitates. The solution-treated samples exhibited the best combination of strength and ductility at room temperature, ultimate tensile strength of 1047 MPa, and elongation of 13.0%, which is superior to the wrought TC31 counterparts. The sample after solution treatment at 980 °C and subsequent aging at 650 °C obtained an attractive combination of strength and ductility both at room temperature and high temperature due to the synergistic effect of the soft α + β lamellar structure and hard fine α precipitates. These findings provide valuable information on developments of LMD-built TC31 alloy for aerospace applications and shed light on AM of other titanium alloys with desirable high-temperature properties. Full article