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Keywords = Al-Si-Cu (Ni) filler metals

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14 pages, 6526 KiB  
Article
Controlled Atmosphere Brazing of 3003 Aluminum Alloy Using Low-Melting-Point Filler Metal Fabricated by Melt-Spinning Technology
by Zeng Gao, Zhen Qin and Qingsong Lu
Materials 2022, 15(17), 6080; https://doi.org/10.3390/ma15176080 - 1 Sep 2022
Cited by 10 | Viewed by 3501
Abstract
3003 aluminum alloy was widely used for the manufacturing of heat exchangers in the automotive industry by employing controlled atmosphere brazing (CAB) with NOCOLOK flux brazing technology. However, commercially available filler metals for NOCOLOK flux brazing technology are usually required to be carried [...] Read more.
3003 aluminum alloy was widely used for the manufacturing of heat exchangers in the automotive industry by employing controlled atmosphere brazing (CAB) with NOCOLOK flux brazing technology. However, commercially available filler metals for NOCOLOK flux brazing technology are usually required to be carried out at a relatively high temperature, causing the assembled heat exchanger to be partially molten or easily deformed. A new low-melting-point brazing filler metal Al-5.0Si-20.5Cu-2.0Ni was prepared by using melt-spinning technology and then applied to CAB of 3003 aluminum alloy in this research. The solidus and liquidus of brazing filler metal was 513.21 °C and 532.48 °C. All elements were evenly distributed and free from elemental segregation. The microstructure of brazing filler metal was uniform, and the grain size was less than 500 nm. As the brazing temperature reached 575 °C, the void in the joint disappeared completely. The morphology of CuAl2 was sensitive to the brazing temperature and dwell time. The appearance of net-like CuAl2 brazed at 575 °C for 20 min was more beneficial to improve joint mechanical properties. The leakage rate of the joint was qualified to be 10−10 Pa·m3/s when the brazing temperature was 570 °C or higher. The maximum shear strength of 76.1 MPa can be obtained when the joint was brazed at 575 °C for 20 min. More dwell time induced growth of the interfacial layer and reduced joint shear strength. The open circuit potential and corrosion current density test indicated that the brazing filler metal Al-5.0Si-20.5Cu-2.0Ni had better corrosion resistance than that of 3003 aluminum alloy. Full article
(This article belongs to the Special Issue Quality, Microstructure and Properties of Metal Alloys)
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25 pages, 11815 KiB  
Article
Thermophysical Properties of Electric Arc Plasma and the Wire Melting Effect with Lanthanum and Sulfur Fluorides Addition in Wire Arc Additive Manufacturing
by Sergey G. Parshin and Peter Mayr
Metals 2021, 11(11), 1756; https://doi.org/10.3390/met11111756 - 1 Nov 2021
Cited by 3 | Viewed by 3006
Abstract
Achieving a higher quality in wire arc additive manufacturing (WAAM) is a result of the development of welding metallurgy, the development of filler wires, and the control of the thermophysical properties of the electric arc. In this paper, the authors developed composite wires [...] Read more.
Achieving a higher quality in wire arc additive manufacturing (WAAM) is a result of the development of welding metallurgy, the development of filler wires, and the control of the thermophysical properties of the electric arc. In this paper, the authors developed composite wires for WAAM with a Ni-LaF3, Ni-LaB6 coating. The addition of LaF3, LaB6, and SF6 increases specific heat, thermal conductivity, enthalpy, and degree of plasma ionization, which leads to the increase in the transfer of heat from the arc plasma to the wire and to the change in the balance of forces during wire melting. The increase in the Lorentz electromagnetic force and the decrease in the surface tension force made it possible to reduce the droplet diameter and the number of short circuits during wire melting. The change in the thermophysical properties of the plasma and droplet transfer with the addition of LaF3, LaB6, and SF6 made it possible to increase the welding current, penetration depth, accuracy of the geometric dimensions of products in WAAM, reduce the wall thickness of products, and refine the microstructure of the weld metal using G3Si1, 316L, AlMg5Mn1Ti, and CuCr0.7 wires. Full article
(This article belongs to the Special Issue Advances in Additive Manufacturing of Metals)
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14 pages, 6858 KiB  
Article
Research on a Low Melting Point Al-Si-Cu (Ni) Filler Metal for 6063 Aluminum Alloy Brazing
by Chengyin Peng, Dandan Zhu, Kaifeng Li, Xiang Du, Fei Zhao, Mingpan Wan and Yuanbiao Tan
Appl. Sci. 2021, 11(9), 4296; https://doi.org/10.3390/app11094296 - 10 May 2021
Cited by 17 | Viewed by 4151
Abstract
A new type of low melting point Al-Si-Cu (Ni) filler metal for brazed 6063 aluminum alloy was designed, and the microstructure and properties of the filler metal were systematically studied. The results show that when the content of Cu in the Al-Si-Cu filler [...] Read more.
A new type of low melting point Al-Si-Cu (Ni) filler metal for brazed 6063 aluminum alloy was designed, and the microstructure and properties of the filler metal were systematically studied. The results show that when the content of Cu in the Al-Si-Cu filler metal increased from 10 wt.% to 20 wt.%, the liquidus temperature of the filler metal decreased from 587.8 °C to 533.4 °C. Its microstructures were mainly composed of the α-Al phase, a primary Si phase, and a θ(Al2Cu) phase. After a proper amount of Ni was added to the Al-Si-20Cu filler metal, its melting range was narrowed, the spreading wettability was improved, and the microstructure was refined. Its microstructure mainly includes α-Al solid solution, Si particles, and θ(Al2Cu) and δ(Al3Ni2) intermetallic compounds. The results of the shear strength test indicate that the shear strength of the brazed joint with Al-6.5Si-20Cu-2.0Ni filler metal was 150.4 MPa, which was 28.32% higher than that of the brazed joint with Al-6.5Si-20Cu filler metal. Full article
(This article belongs to the Topic Metallurgical and Materials Engineering)
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16 pages, 7686 KiB  
Article
Joining of Silicon Particle-Reinforced Aluminum Matrix Composites to Kovar Alloys Using Active Melt-Spun Ribbons in Vacuum Conditions
by Zeng Gao, Xianli Ba, Huanyu Yang, Congxin Yin, Shanguang Liu, Jitai Niu and Josip Brnic
Materials 2020, 13(13), 2965; https://doi.org/10.3390/ma13132965 - 2 Jul 2020
Cited by 8 | Viewed by 2960
Abstract
The vacuum brazing of dissimilar electronic packaging materials has been investigated. In this research, this applies silicon particle-reinforced aluminum matrix composites (Sip/Al MMCs) to Kovar alloys. Active melt-spun ribbons were employed as brazing filler metals under different joining temperatures and times. [...] Read more.
The vacuum brazing of dissimilar electronic packaging materials has been investigated. In this research, this applies silicon particle-reinforced aluminum matrix composites (Sip/Al MMCs) to Kovar alloys. Active melt-spun ribbons were employed as brazing filler metals under different joining temperatures and times. The results showed that the maximum joint shear strength of 96.62 MPa was achieved when the joint was made using Al-7.5Si-23.0Cu-2.0Ni-1.0Ti as the brazing filler metal at 580 °C for 30 min. X-ray diffraction (XRD) analysis of the joint indicated that the main phases were composed of Al, Si and intermetallics, including CuAl, TiFeSi, TiNiSi and Al3Ti. When the brazing temperature ranged from 570 °C to 590 °C, the leakage rate of joints remained at 10−8 Pa·m3/s or better. When the joint was made using Al-7.5Si-23.0Cu-2.0Ni-2.5Ti as the brazing filler metal at 580 °C for 30 min, the higher level of Ti content in the brazing filler metal resulted in the formation of a flake-like Ti(AlSi)3 intermetallic phase with an average size of 7 µm at the interface between the brazing seam and Sip/Al MMCs. The joint fracture was generally in the form of quasi-cleavage fracture, which primarily occurred at the interface between the filler metal and the Sip/Al MMCs. The micro-crack propagated not only Ti(AlSi)3, but also the Si particles in the substrate. Full article
(This article belongs to the Collection Welding and Joining Processes of Materials)
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