Search Results (3)

Nanocomposites of poly (vinylidene fluoride) PVDF with graphene nanoflakes (GNF) were prepared using two different routes. Initially, a mix-melting method was used to prepare composites, and their thermal and mechanical properties were evaluated to choose the better method for future experiment and properties investigation. Then, nanocomposite films were prepared by a simple solution-casting technique using a PVDF/graphene solution. In both cases, the amount of graphene was varied to observe and to compare their thermal and mechanical properties. The addition of graphene to the PVDF matrix resulted in changes in the crystallization and melting behaviors as confirmed by DSC analyses. Increasing the graphene content led to improved thermal stability of the PVDF nanocomposites prepared using both methods. Improvements in mechanical properties by the addition of graphene were also observed. Better performance was observed by the nanocomposites prepared by a mix-melting technique suggesting better dispersion and strong interface bonding between PVDF and graphene particles. Thermal and electrical conductivity were measured and compared. Microstructure and morphology were characterized using FTIR, XRD, and SEM analyses. Full article

We have fabricated poly(ε-caprolactone) (PCL) films with flat and honeycomb-patterned (HCP) structures to coat polyaniline (PANI) on the film surface. In addition, the effect of chemical modification of PANI by sulfuric acid (H₂SO₄) was also studied for antibacterial activity. The flat and HCP PCL films were obtained by simple evaporation of the solvent and via the breath figure (BF) method, respectively. The morphology and chemical composition of PANI coated on the film surface were evaluated by scanning electron microscopy (SEM) and X-ray spectroscopy (EDX). Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analyses (TGA) were obtained to identify the PANI coating. The wettability and conductivity of the films were also measured. Applicational aspects were evaluated by assessing antibacterial and antibiofilm activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). The EDX, TGA, and FT-IR findings indicated chemical modification of PCL film by PANI and H₂SO₄. The conductivity of the films was increased by the coating of PANI to the patterned surface and additionally increased by the chemically modified PANI. The antibacterial activity was 69.79%, 78.27%, and 88% against E. coli, and 32.73%, 62.65%, and 87.97% against S. aureus, for flat PANI, HCP PANI, and H₂SO₄-treated HCP films, respectively. Likewise, the PANI coated flat, HCP, and H₂SO₄-treated HCP films inhibited E. coli biofilm formation by around 41.62%, 63%, and 83.88% and S. aureus biofilm formation by 17.81%, 69.83%, and 96.57%, respectively. The antibacterial activity of the HCP film was higher than that of flat PANI films, probably due to the higher coating of PANI on the HCP surface. Moreover, sulfonation of the HCP film with H₂SO₄ might have improved the wettability, thereby enhancing the antibacterial and antibiofilm properties. Our results showed that topographical changes, as well as doping, offer simple and cost-effective ways to modify the structural and functional properties of films. Full article

Recent developments in the field of the breath figure (BF) method have led to renewed interest from researchers in the pore-selective functionalization of honeycomb-patterned (HCP) films. The pore-selective functionalization of the HCP film gives unique properties to the film which can be used for specific applications such as protein recognition, catalysis, selective cell culturing, and drug delivery. There are several comprehensive reviews available for the pore-selective functionalization by the self-assembly process. However, considerable progress in preparation technologies and incorporation of new materials inside the pore surface for exact applications have emerged, thus warranting a review. In this review, we have focused on the pore-selective functionalization of the HCP films by the modified BF method, in which the self-assembly process is accompanied by an interfacial reaction. We review the importance of pore-selective functionalization, its applications, present limitations, and future perspectives. Full article