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Authors = Anna Pražanová ORCID = 0000-0002-1627-6381

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26 pages, 7805 KiB  
Review
Acoustic Emission Technique for Battery Health Monitoring: Comprehensive Literature Review
by Eliška Sedláčková, Anna Pražanová, Zbyněk Plachý, Nikola Klusoňová, Vaclav Knap and Karel Dušek
Batteries 2025, 11(1), 14; https://doi.org/10.3390/batteries11010014 - 1 Jan 2025
Cited by 3 | Viewed by 2586
Abstract
The rapid adoption of electric vehicles (EVs) has increased the demand for efficient methods to assess the state of health (SoH) of lithium-ion batteries (LIBs). Accurate and prompt evaluations are essential for safety, battery life extension, and performance optimization. While traditional techniques such [...] Read more.
The rapid adoption of electric vehicles (EVs) has increased the demand for efficient methods to assess the state of health (SoH) of lithium-ion batteries (LIBs). Accurate and prompt evaluations are essential for safety, battery life extension, and performance optimization. While traditional techniques such as electrochemical impedance spectroscopy (EIS) are commonly used to monitor battery degradation, acoustic emission (AE) analysis is emerging as a promising complementary method. AE’s sensitivity to mechanical changes within the battery structure offers significant advantages, including speed and non-destructive assessment, enabling evaluations without disassembly. This capability is particularly beneficial for diagnosing second-life batteries and streamlining decision-making regarding the management of used batteries. Moreover, AE enhances diagnostics by facilitating early detection of potential issues, optimizing maintenance, and improving the reliability and longevity of battery systems. Importantly, AE is a non-destructive technique and belongs to the passive method category, as it does not introduce any external energy into the system but instead detects naturally occurring acoustic signals during the battery’s operation. Integrating AE with other analytical techniques can create a comprehensive tool for continuous battery condition monitoring and predictive maintenance, which is crucial in applications where battery reliability is vital, such as in EVs and energy storage systems. This review not only examines the potential of AE techniques in battery health monitoring but also underscores the need for further research and adoption of these techniques, encouraging the academic community and industry professionals to explore and implement these methods. Full article
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20 pages, 3351 KiB  
Review
Direct Recycling Technology for Spent Lithium-Ion Batteries: Limitations of Current Implementation
by Anna Pražanová, Zbyněk Plachý, Jan Kočí, Michael Fridrich and Vaclav Knap
Batteries 2024, 10(3), 81; https://doi.org/10.3390/batteries10030081 - 28 Feb 2024
Cited by 13 | Viewed by 10355
Abstract
The significant deployment of lithium-ion batteries (LIBs) within a wide application field covering small consumer electronics, light and heavy means of transport, such as e-bikes, e-scooters, and electric vehicles (EVs), or energy storage stationary systems will inevitably lead to generating notable amounts of [...] Read more.
The significant deployment of lithium-ion batteries (LIBs) within a wide application field covering small consumer electronics, light and heavy means of transport, such as e-bikes, e-scooters, and electric vehicles (EVs), or energy storage stationary systems will inevitably lead to generating notable amounts of spent batteries in the coming years. Considering the environmental perspective, material resource sustainability, and terms of the circular economy, recycling represents a highly prospective strategy for LIB end-of-life (EOL) management. In contrast with traditional, large-scale, implemented recycling methods, such as pyrometallurgy or hydrometallurgy, direct recycling technology constitutes a promising solution for LIB EOL treatment with outstanding environmental benefits, including reduction of energy consumption and emission footprint, and weighty economic viability. This work comprehensively assesses the limitations and challenges of state-of-the-art, implemented direct recycling methods for spent LIB cathode and anode material treatment. The introduced approaches include solid-state sintering, electrochemical relithiation in organic and aqueous electrolytes, and ionothermal, solution, and eutectic relithiation methods. Since most direct recycling techniques are still being developed and implemented primarily on a laboratory scale, this review identifies and discusses potential areas for optimization to facilitate forthcoming large-scale industrial implementation. Full article
(This article belongs to the Special Issue Lithium-Ion Battery Recycling)
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19 pages, 3971 KiB  
Perspective
Second-Life of Lithium-Ion Batteries from Electric Vehicles: Concept, Aging, Testing, and Applications
by Kateřina Nováková, Anna Pražanová, Daniel-Ioan Stroe and Vaclav Knap
Energies 2023, 16(5), 2345; https://doi.org/10.3390/en16052345 - 28 Feb 2023
Cited by 19 | Viewed by 6059
Abstract
The last decade has seen a significant increase in electromobility. With this trend, it will be necessary to start dealing with the subsequent recycling and disposal of electric vehicles, including the batteries. Currently, the battery is one of the most expensive components of [...] Read more.
The last decade has seen a significant increase in electromobility. With this trend, it will be necessary to start dealing with the subsequent recycling and disposal of electric vehicles, including the batteries. Currently, the battery is one of the most expensive components of an electric vehicle, which in part hinders their sufficient competitiveness with the internal combustion engine. Furthermore, the lifetime of a battery for use in an electric vehicle is assumed to be 8–10 years/160,000 km, after which the battery capacity drops to 80% of the initial capacity. However, it transpires that a battery at the end of its life in an electric vehicle does not need to be disposed of immediately, but can be used in other applications wherein the emphasis is not so strictly on an excellent power and capacity capability related to its volume or weight. Thus, reusing batteries can help reduce their cost for use in electric vehicles, increase their utility value, and reduce the environmental impact of batteries. This paper discusses methods for researching battery aging in electric vehicles, testing methods for batteries during the transition from first life to second life, and prospective battery second-life use and its specifics. The main contribution of this perspective article is to provide a comprehensive view of the current state of second-life batteries and an overview of the challenges that need to be overcome in order to use them on a large industrial scale. Full article
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14 pages, 5636 KiB  
Article
Pre-Recycling Material Analysis of NMC Lithium-Ion Battery Cells from Electric Vehicles
by Anna Pražanová, Jan Kočí, Martin Havlík Míka, Dominik Pilnaj, Zbyněk Plachý and Vaclav Knap
Crystals 2023, 13(2), 214; https://doi.org/10.3390/cryst13020214 - 24 Jan 2023
Cited by 9 | Viewed by 4864
Abstract
Environmental concerns push for a reduction in greenhouse gas emissions and technologies with a low carbon footprint. In the transportation sector, this drives the transition toward electric vehicles (EVs), which are nowadays mainly based on lithium-ion batteries (LIBs). As the number of produced [...] Read more.
Environmental concerns push for a reduction in greenhouse gas emissions and technologies with a low carbon footprint. In the transportation sector, this drives the transition toward electric vehicles (EVs), which are nowadays mainly based on lithium-ion batteries (LIBs). As the number of produced EVs is rapidly growing, a large amount of waste batteries is expected in the future. Recycling seems to be one of the most promising end-of-life (EOL) methods; it reduces raw material consumption in battery production and the environmental burden. Thus, this work introduces a comprehensive pre-recycling material characterization of waste nickel-manganese-cobalt (NMC) LIB cells from a fully electric battery electric vehicle (BEV), which represents a basis for cost-effective and environmentally friendly recycling focusing on the efficiency of the implemented technique. The composition of the NCM 622 battery cell was determined; it included a LiNi0.6Co0.2Mn0.2O2 spinel on a 15 μm Al-based current collector (cathode), a graphite layer on 60 μm copper foil (anode), 25 μm PE/PVDF polymer separator, and a LiPF6 salt electrolyte with a 1:3 ratio in primary solvents DMC and DEC. The performed research was based on a series of X-ray, infrared (IR) measurements, gas chromatography–mass spectrometry (GC-MS), and inductively coupled plasma–optical emission spectrometry (ICP-OES) characterization of an aqueous solution with dissolved electrolytes. These results will be used in subsequent works devoted to optimizing the most suitable recycling technique considering the environmental and economic perspectives. Full article
(This article belongs to the Special Issue Advanced Technologies in Lithium-Ion Batteries)
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44 pages, 3366 KiB  
Review
Literature Review, Recycling of Lithium-Ion Batteries from Electric Vehicles, Part II: Environmental and Economic Perspective
by Anna Pražanová, Vaclav Knap and Daniel-Ioan Stroe
Energies 2022, 15(19), 7356; https://doi.org/10.3390/en15197356 - 6 Oct 2022
Cited by 33 | Viewed by 8332
Abstract
Lithium-ion batteries (LIBs) are crucial for consumer electronics, complex energy storage systems, space applications, and the automotive industry. The increasing requirements for decarbonization and CO2 emissions reduction affect the composition of new production. Thus, the entire automotive sector experiences its turning point; [...] Read more.
Lithium-ion batteries (LIBs) are crucial for consumer electronics, complex energy storage systems, space applications, and the automotive industry. The increasing requirements for decarbonization and CO2 emissions reduction affect the composition of new production. Thus, the entire automotive sector experiences its turning point; the production capacities of new internal combustion engine vehicles are limited, and the demand for electric vehicles (EVs) has continuously increased over the past years. The growing number of new EVs leads to an increasing amount of automotive waste, namely spent LIBs. Recycling appears to be the most suitable solution for lowering EV prices and reducing environmental impacts; however, it is still not a well-established process. This work is the second part of the review collection based on the performed literature survey, where more than 250 publications about “Recycling of Lithium-ion Batteries from Electric Vehicles” were divided into five sections: Recycling Processes, Battery Composition, Environmental Impact, Economic Evaluation, and Recycling and Rest. This paper reviews and summarizes 162 publications dedicated to recycling procedures and their environmental or economic perspective. Both reviews cover the techno-environmental economic impacts of recycling spent LIBs from EVs published until 2021. Full article
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29 pages, 33138 KiB  
Review
Literature Review, Recycling of Lithium-Ion Batteries from Electric Vehicles, Part I: Recycling Technology
by Anna Pražanová, Vaclav Knap and Daniel-Ioan Stroe
Energies 2022, 15(3), 1086; https://doi.org/10.3390/en15031086 - 1 Feb 2022
Cited by 51 | Viewed by 12928
Abstract
During recent years, emissions reduction has been tightened worldwide. Therefore, there is an increasing demand for electric vehicles (EVs) that can meet emission requirements. The growing number of new EVs increases the consumption of raw materials during production. Simultaneously, the number of used [...] Read more.
During recent years, emissions reduction has been tightened worldwide. Therefore, there is an increasing demand for electric vehicles (EVs) that can meet emission requirements. The growing number of new EVs increases the consumption of raw materials during production. Simultaneously, the number of used EVs and subsequently retired lithium-ion batteries (LIBs) that need to be disposed of is also increasing. According to the current approaches, the recycling process technology appears to be one of the most promising solutions for the End-of-Life (EOL) LIBs—recycling and reusing of waste materials would reduce raw materials production and environmental burden. According to this performed literature review, 263 publications about “Recycling of Lithium-ion Batteries from Electric Vehicles” were classified into five sections: Recycling Processes, Battery Composition, Environmental Impact, Economic Evaluation, and Recycling & Rest. The whole work reviews the current-state of publications dedicated to recycling LIBs from EVs in the techno-environmental-economic summary. This paper covers the first part of the review work; it is devoted to the recycling technology processes and points out the main study fields in recycling that were found during this work. Full article
(This article belongs to the Collection Batteries, Fuel Cells and Supercapacitors Technologies)
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22 pages, 12291 KiB  
Article
Understanding the Effect of Reflow Profile on the Metallurgical Properties of Tin–Bismuth Solders
by Karel Dušek, David Bušek, Petr Veselý, Anna Pražanová, Martin Plaček and Julia Del Re
Metals 2022, 12(1), 121; https://doi.org/10.3390/met12010121 - 8 Jan 2022
Cited by 16 | Viewed by 4711
Abstract
Sn–Bi alloys are desirable candidates for soldering components on printed circuit boards (PCBs) because of their low melting point and reduced cost. While certain tin–bismuth solders are well characterized many new alloys in this family have been developed which need proper characterization. The [...] Read more.
Sn–Bi alloys are desirable candidates for soldering components on printed circuit boards (PCBs) because of their low melting point and reduced cost. While certain tin–bismuth solders are well characterized many new alloys in this family have been developed which need proper characterization. The following study looks at the behavior of four different Sn–Bi alloys—traditional 42Sn58Bi and 42Sn57Bi1Ag and two new tin–bismuth alloys—in solder paste during the reflow soldering process. Each alloy was processed using different reflow profiles that had varying times above liquidus (TALs) and peak temperatures. The PCBs were then analyzed to see how the processing variables influenced wetting, voiding, microstructure, intermetallic layer composition, and thickness. After analysis, the PCBs were then subjected to thermal cycling experiments to see how reflow profile impacted microstructure evolution. The results demonstrated that reflow profile affects properties such as metal wetting and voiding. It does not however, greatly impact key metallurgical properties such as intermetallic layer thickness. Full article
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