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Authors = Alexander V. Demura ORCID = 0000-0003-4392-8848

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11 pages, 376 KiB  
Article
Approximate Solution of the Thomas–Fermi Equation for Free Positive Ions
by Aleksey A. Mavrin and Alexander V. Demura
Atoms 2021, 9(4), 87; https://doi.org/10.3390/atoms9040087 - 23 Oct 2021
Cited by 6 | Viewed by 2312
Abstract
The approximate solution of the nonlinear Thomas–Fermi (TF) equation for ions is found by the Fermi method. The solution is based on the new asymptotic representation of the TF ion size valid for any ionization degree. The two universal functions and their derivatives, [...] Read more.
The approximate solution of the nonlinear Thomas–Fermi (TF) equation for ions is found by the Fermi method. The solution is based on the new asymptotic representation of the TF ion size valid for any ionization degree. The two universal functions and their derivatives, introduced by Fermi, are calculated by recent effective algorithms for the Emden–Fowler type equations with the accuracy sufficient for majority of applications. The comparison of our results with those obtained previously shows high accuracy and validity for arbitrary values of ionization degree. This study could potentially be of interest for the statistical TF method applications in physics and chemistry. Full article
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28 pages, 1542 KiB  
Review
Beyond the Linear Stark Effect: A Retrospective
by Alexander V. Demura
Atoms 2018, 6(2), 33; https://doi.org/10.3390/atoms6020033 - 6 Jun 2018
Cited by 16 | Viewed by 4161
Abstract
A review of studies of the electric-field influence on spectral lines is presented, beginning from the discovery of the Stark effect, and in particular focused on phenomena related to the effects of the plasma microfield non-uniformity. Full article
(This article belongs to the Special Issue Spectral Line Shapes in Plasmas II)
20 pages, 548 KiB  
Article
Tungsten Ions in Plasmas: Statistical Theory of Radiative-Collisional Processes
by Alexander V. Demura, Mikhail B. Kadomtsev, Valery S. Lisitsa and Vladimir A. Shurygin
Atoms 2015, 3(2), 162-181; https://doi.org/10.3390/atoms3020162 - 25 May 2015
Cited by 17 | Viewed by 6964
Abstract
The statistical model for calculations of the collisional-radiative processes in plasmas with tungsten impurity was developed. The electron structure of tungsten multielectron ions is considered in terms of both the Thomas-Fermi model and the Brandt-Lundquist model of collective oscillations of atomic electron density. [...] Read more.
The statistical model for calculations of the collisional-radiative processes in plasmas with tungsten impurity was developed. The electron structure of tungsten multielectron ions is considered in terms of both the Thomas-Fermi model and the Brandt-Lundquist model of collective oscillations of atomic electron density. The excitation or ionization of atomic electrons by plasma electron impacts are represented as photo-processes under the action of flux of equivalent photons introduced by E. Fermi. The total electron impact single ionization cross-sections of ions Wk+ with respective rates have been calculated and compared with the available experimental and modeling data (e.g., CADW). Plasma radiative losses on tungsten impurity were also calculated in a wide range of electron temperatures 1 eV–20 keV. The numerical code TFATOM was developed for calculations of radiative-collisional processes involving tungsten ions. The needed computational resources for TFATOM code are orders of magnitudes less than for the other conventional numerical codes. The transition from corona to Boltzmann limit was investigated in detail. The results of statistical approach have been tested by comparison with the vast experimental and conventional code data for a set of ions Wk+. It is shown that the universal statistical model accuracy for the ionization cross-sections and radiation losses is within the data scattering of significantly more complex quantum numerical codes, using different approximations for the calculation of atomic structure and the electronic cross-sections. Full article
(This article belongs to the Special Issue Atomic Data for Tungsten)
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23 pages, 1514 KiB  
Article
Spectral-Kinetic Coupling and Effect of Microfield Rotation on Stark Broadening in Plasmas
by Alexander V. Demura and Evgeny Stambulchik
Atoms 2014, 2(3), 334-356; https://doi.org/10.3390/atoms2030334 - 30 Jul 2014
Cited by 8 | Viewed by 6721
Abstract
The study deals with two conceptual problems in the theory of Stark broadening by plasmas. One problem is the assumption of the density matrix diagonality in the calculation of spectral line profiles. This assumption is closely related to the definition of zero wave [...] Read more.
The study deals with two conceptual problems in the theory of Stark broadening by plasmas. One problem is the assumption of the density matrix diagonality in the calculation of spectral line profiles. This assumption is closely related to the definition of zero wave functions basis within which the density matrix is assumed to be diagonal, and obviously violated under the basis change. A consistent use of density matrix in the theoretical scheme inevitably leads to interdependence of atomic kinetics, describing the population of atomic states with the Stark profiles of spectral lines, i.e., to spectral-kinetic coupling. The other problem is connected with the study of the influence of microfield fluctuations on Stark profiles. Here the main results of the perturbative approach to ion dynamics, called the theory of thermal corrections (TTC), are presented, within which the main contribution to effects of ion dynamics is due to microfield fluctuations caused by rotations. In the present study the qualitative behavior of the Stark profiles in the line center within predictions of TTC is confirmed, using non-perturbative computer simulations. Full article
(This article belongs to the Special Issue Spectral Line Shapes in Plasmas)
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18 pages, 1545 KiB  
Article
Influence of Microfield Directionality on Line Shapes
by Annette Calisti, Alexander V. Demura, Marco A. Gigosos, Diego González-Herrero, Carlos A. Iglesias, Valery S. Lisitsa and Evgeny Stambulchik
Atoms 2014, 2(2), 259-276; https://doi.org/10.3390/atoms2020259 - 19 Jun 2014
Cited by 14 | Viewed by 5107
Abstract
In the framework of the Spectral Line Shapes in Plasmas Code Comparison Workshop (SLSP), large discrepancies appeared between the different approaches to account for ion motion effects in spectral line shape calculations. For a better understanding of these effects, in the second edition [...] Read more.
In the framework of the Spectral Line Shapes in Plasmas Code Comparison Workshop (SLSP), large discrepancies appeared between the different approaches to account for ion motion effects in spectral line shape calculations. For a better understanding of these effects, in the second edition of the SLSP in August, 2013, two cases were dedicated to the study of the ionic field directionality on line shapes. In this paper, the effects of the direction and magnitude fluctuations are separately analyzed. The effects of two variants of electric field models, (i) a pure rotating field with constant magnitude and (ii) a time-dependent magnitude field in a given direction, together with the effects of the time-dependent ionic field on shapes of the He II Lyman-α and -β lines for different densities and temperatures, are discussed. Full article
(This article belongs to the Special Issue Spectral Line Shapes in Plasmas)
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