Cryo, Volume 1, Issue 2 (June 2025) – 3 articles

The excessive use of fossil fuels could bring about a global environmental crisis. Transitioning from a carbon-based to a hydrogen-based economy is an important way to realize the low-carbon energy transition. The key to this economy transformation lies in the efficient utilization of hydrogen. Hydrogen liquefaction is an efficient technology for the transportation and storage of hydrogen, and the liquid hydrogen produced is also a direct feedstock for many important fields. Large-scale liquefaction of hydrogen has not been commercialized due to its high energy consumption (>10 kWh/kg_LH2) and low efficiency (<30%). However, conceptual designs for hydrogen liquefaction with a low energy consumption (about 6.4 kWh/kg_LH2) and high efficiency (>40%) are frequently reported in the existing literature. Therefore, in this paper, the production process of liquid hydrogen is reviewed from three aspects, which are hydrogen pre-cooling, hydrogen cryo-cooling, and ortho-para hydrogen (OPH) conversion. The focus is to summarize effective and realistic hydrogen liquefaction schemes in the existing studies to provide process guidance for the subsequent practical production of liquid hydrogen. The development of open and closed refrigeration cycles for hydrogen pre-cooling is reviewed following the lead of pre-coolant types. The implementation methods of structural optimization of different hydrogen cryo-cooling cycles are clarified and the performance improvements achieved are compared. Different modes of OPH conversion are presented and their realization in simulation and practical applications is summarized. Finally, subjective recommendations are given regarding the content of the review. Full article

Using hydrogen as a working fluid in cryocoolers can potentially benefit cryocooling technologies and hydrogen liquefaction. Moreover, in flow-through thermoacoustic systems, hydrogen can be efficiently cooled and undergo ortho-parahydrogen isomeric conversion, which is important for the efficient storage of cryogenic hydrogen. A traveling-wave regenerator is analyzed in this study, using the thermoacoustic theory with a superimposed mean flow and an empirical correlation for hydrogen isomer conversion. A regenerator with hydrogen fluid is shown to achieve higher performance in comparison with helium as the working fluid. However, the hydrogen system performance degrades at supercritical pressures and subcritical temperatures in compressed liquid states. In regenerators with mean flow, using hydrogen as the working fluid leads to higher cooling powers and efficiencies, but helium systems are able to achieve colder temperatures. Full article

The cryogenic supercritical hydrogen storage system offers notable advantages including heightened hydrogen storage density and operation under relatively moderate conditions compared to conventional hydrogen storage methodologies. In this study, a cryogenic supercritical hydrogen storage system based on the multi-stage Joule–Brayton refrigeration cycle is presented, analyzed, and optimized. The proposed system employs a five-stage cascade cycle, each stage utilizes a distinct refrigerant, including propane, ethylene, methane, and hydrogen, facilitated by Joule–Brayton cycles, with expanders employed for mechanical work recovery, which is capable of effectively cooling hydrogen from ambient temperature and atmospheric pressure to a cryogenic supercritical state of −223.15 °C (50 K), 18,000 kPa, exhibiting a density of 73.46 kg/m³ and a hydrogen processing capacity of 2 kg_H2/s. The genetic algorithm is applied to optimize 25 key parameters in the system, encompassing temperature, pressure, and flow rate, with the objective function is specific energy consumption. Consequently, the specific energy consumption of the system is 5.71 kWh/kg_H2 with an exergy efficiency of 56.2%. Comprehensive energy analysis, heat transfer analysis, and exergy analysis are conducted based on the optimized system parameters, yielding insights crucial for the development of medium- and large-scale supercritical hydrogen storage systems. Full article