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Article

Enhancing Light Harvesting in Dye-Sensitized Solar Cells through Mesoporous Silica Nanoparticle-Mediated Diffuse Scattering Back Reflectors

by
Jeffrie Fina
1,
Navdeep Kaur
1,
Chen-Yu Chang
1,
Cheng-Yu Lai
1,2 and
Daniela R. Radu
1,*
1
Department of Mechanical and Materials Engineering, Florida International University, Miami, FL 33174, USA
2
Department of Chemistry and Biochemistry, Florida International University, Miami, FL 33199, USA
*
Author to whom correspondence should be addressed.
Electron. Mater. 2023, 4(3), 124-135; https://doi.org/10.3390/electronicmat4030010
Submission received: 4 August 2023 / Revised: 23 August 2023 / Accepted: 29 August 2023 / Published: 30 August 2023
Browse Figures
Versions Notes

Abstract

:
Dye-sensitized solar cells (DSSCs) hold unique promise in solar photovoltaics owing to their low-cost fabrication and high efficiency in ambient conditions. However, to improve their commercial viability, effective, and low-cost methods must be employed to enhance their light harvesting capabilities, and hence photovoltaic (PV) performance. Improving the absorption of incoming light is a critical strategy for maximizing solar cell efficiency while overcoming material limitations. Mesoporous silica nanoparticles (MSNs) were employed herein as a reflective layer on the back of transparent counter electrodes. Chemically synthesized MSNs were applied to DSSCs via bar coating as a facile fabrication step compatible with roll-to-roll manufacturing. The MSNs diffusely scatter the unused incident light transmitted through the DSSCs back into the photoactive layers, increasing the absorption of light by N719 dye molecules. This resulted in a 20% increase in power conversion efficiency (PCE), from 5.57% in a standard cell to 6.68% with the addition of MSNs. The improved performance is attributed to an increase in photon absorption which led to the generation of a higher number of charge carriers, thus increasing the current density in DSSCs. These results were corroborated with electrochemical impedance spectroscopy (EIS), which showed improved charge transport kinetics. The use of MSNs as reflectors proved to be an effective practical method for enhancing the performance of thin film solar cells. Due to silica’s abundance and biocompatibility, MSNs are an attractive material for meeting the low-cost and non-toxic requirements for commercially viable integrated PVs.

1. Introduction

With historically escalating global energy demands, the dependence on fossil fuels as a primary energy source has led to severe political, economic, and environmental consequences, creating an urgent need for alternative sustainable energy sources [1,2]. As the largest source of the Earth’s energy budget, solar energy has been one of the leading candidates for fueling our world, prompting a photovoltaic (PV) solar cell technology boom. Dye-sensitized solar cells (DSSCs) are third-generation solar cells with key advantages such as light weight, non-toxicity, flexibility, color tuning, and processability in ambient conditions, which makes them feasible for roll-to-roll manufacturing [3,4]. Furthermore, their operability in low-light conditions makes them an attractive alternative to other PV technologies, such as silicon or perovskites, as integrated PVs for indoor and mobile device applications [5,6,7].
The first DSSC was reported in 1991 by Grätzel and O’Regan [8]. The standard Grätzel-type sandwich cell consists of a mesoporous TiO2 (m-TiO2) photoanode sensitized by a monolayer of N719 dye molecules, an ( I − / I 3 − ) redox electrolyte, and a platinum (Pt) counter electrode (CE). The mesoporous photoanode layer, characterized by pore sizes ranging from 2 to 50 nm in diameter, serves as the key electronic material that enables the absorption of substantial amounts of photoactive dye. This capability arises from its extensive surface area, which contributes to the impressive performance of DSSCs. While DSSCs have unique advantages, their lower absorption of incident light by sensitizer dye molecules, accompanied by recombination of photo-generated charge carriers at the photoanode–electrolyte interface, limits their power conversion efficiency (PCE). Several modifications to the structure of DSSCs have thus been researched to improve light harvesting and reduce recombination reactions, raising their PCE [9,10,11,12]. Optical modifications, like reflective layers, enhance light harvesting by reflecting unabsorbed photons back into the photoactive layers, recycling them into the system [13]. The extended path length of the photons increases the probability of absorption and charge generation, thereby raising the photocurrent and subsequently improving PCE. CE back reflectors have the key advantage of enhancing light harvesting without modifying the standard cell materials. Several types of back reflectors have thus been researched, such as metal-based mirrors and photonic crystals, showing promising results [14,15,16,17,18]. However, DSSC modifications must incorporate earth-abundant materials with lower fabrication costs in order to reduce their environmental impact and cost of energy.
Towards this direction, mesoporous silica nanoparticles (MSNs) have garnered increased attention as light-scattering reflective layers in DSSCs owing to their ordered porous structure, high surface area, mechanical stability, and strong lights-scattering capabilities [19,20,21]. Light scattering layers are typically composed of dielectric nanoparticles that reflect light of a wavelength in the same order of magnitude as their particle size, as described by Mie theory [22,23,24]. Incorporating these nanoparticles as a photoanode overlayer was shown to successfully trap photons and improve PCE [25], but this configuration can lead to an increased thickness and concentration of grain boundaries, which in turn can raise the charge recombination rate [26]. However, despite their favorable properties for enhancing PV performance of DSSCs, MSNs have yet to be tested as external back reflectors. Employing MSNs as a CE back reflector could enhance the incident light absorption of dye sensitizers by reflecting unabsorbed light to the photoanodes, while also improving the charge transfer kinetics. Thus, a similar enhancement in light harvesting can be achieved using MSN back reflectors without altering the electronic layers of DSSCs, considering the strong light-scattering properties of MSNs along with their large surface area. The degree of scattering by MSNs determines the angular distribution of reflected light, and thus the optical performance of the reflector [27]. MSNs show increased light scattering capabilities because of reflections and refractions that occur at the interfaces between the silica pore channels and air due to their contrast in refractive index [28]. Unabsorbed photons are thereby scattered by the MSNs, extending their path length in the photoactive layers. The result is a diffuse back reflector that recycles photons and confines them within the system, improving the absorption of light [29]. Dielectric reflectors have shown superior diffuse scattering efficiency compared to metallic reflectors, with the advantage of lower cost [30]. Since DSSCs perform exceptionally well under diffuse light conditions [31], the enhanced harvesting of ambient light owing to MSN reflectors makes them suitable for low-light and indoor applications. Maintaining high efficiency in these conditions is pivotal for DSSCs to reach the photovoltage requirements needed to become an alternative energy source for portable electronics.
In this work, the PV performance of standard DSSCs was enhanced by using MSNs as a reflective scattering layer on the back of a Pt CE. Synthesized MSNs were characterized via X-ray diffraction, transmission electron microscopy, nitrogen physisorption (the Brunauer–Emmett–Teller method), dynamic light scattering, and Fourier transform infrared spectroscopy. The optical properties of MSNs were characterized by UV–visible reflectance measurements to analyze their effectiveness as a diffuse reflector. The resulting change in light harvesting when applied on DSSCs was evaluated through current density–voltage (J–V) measurements and correlated with changes in charge transport kinetics using electrochemical impedance spectroscopy (EIS).

2. Materials and Methods

All chemicals for this work were used as received and without further purification. For the synthesis of MSNs, hexadecyltrimethylammonium bromide (CTAB, ≥99%) was purchased from Sigma-Aldrich (Saint Louis, MI, USA). Tetraethyl orthosilicate (TEOS, 99.9%) was purchased from Alfa Aesar (Haverhill, MA, USA). Sodium hydroxide (NaOH), hydrochloric acid (HCl, 37%), and methanol were purchased from ThermoFisher Scientific (Waltham, MA, USA). ACS reagent-grade nanopure water was purchased from LabChem (Zelienople, PA, USA). Ethanol (200 proof, 100% by volume) was purchased from Decon Labs (King of Prussia, PA, USA). For DSSC fabrication, fluorine-doped tin oxide (FTO) substrates were purchased from Hartford Glass Co., Inc., titanium (IV) isopropoxide (TTIP) and titanium dioxide (TiO2) paste from Sigma-Aldrich (Saint Louis, MI, USA), Platisol-T from Solaronix (Aubonne, Switzerland), Di-tetrabutylammonium cis-bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato) ruthenium(II) (N719) dye, and EL-HSE electrolyte from Greatcell Solar Co. Ltd. (Queanbeyan, Australia). Butvar B-98 (PVB) binder was purchased from TALAS (Brooklyn, NY, USA).
The MSNs synthesized in this work were characterized by a variety of analytical methods to understand how these features contribute to their light scattering capabilities. Evaluation of MSNs by X-ray diffraction (XRD) is customary for this class of materials given their parallel pores, packed in hexagonal arrays, that confer the material a significant structural order leading to diffraction under X-ray. The XRD measurements were conducted on a Rigaku MiniFlex 600 equipped with Cu Kα radiation (λ = 1.5405 Å) operating at 40 mV and 30 mA. MSN particle size and morphology were analyzed using a JEOL/JEM-2100 (200 kV) transmission electron microscope (TEM). The specific surface area, pore volume, and pore size distribution of MSNs were determined via the Brunauer–Emmett–Teller (BET) and density functional theory (DFT) methods using nitrogen adsorption–desorption isothermal curves on a Quantachrome/NOVAtouch LX-2. Average particle size measurements of MSNs were performed using dynamic light scattering (DLS) with a Malvern Zetasizer Nano-ZS ZEN3600 operated at room temperature. Fourier transform infrared spectroscopy with attenuated total reflection (FTIR-ATR) was performed to characterize the chemical bonds in MSNs and verify the removal of CTAB surfactant template from the pores after the acid washing step. Cross-sectional imaging of the DSSC layers and MSN film microstructure was performed with a JEOL/JSM-F100 Schottky field emission scanning electron microscope (FE-SEM). Optical spectroscopy of the MSNs’ diffuse reflectance properties, absorbance of CEs, and transmittance of the DSSC layers was performed using a Shimadzu UV-3600 Plus spectrophotometer using an integrating sphere, where full DSCCs with a large effective area of 3 cm2 were fabricated to fit the aperture of the spectrophotometer.
The PV performance of the fabricated DSSCs was evaluated under 1 sun conditions (1.5 G AM) at an intensity of 100 mW/cm2 using an ORIEL LCS-100TM solar simulator calibrated with a standard silicon cell and connected to a Keithley source meter (Model 2400), providing J-V curves from which the VOC, JSC, FF, and PCE can be measured under operation. Electrochemical impedance spectroscopy (EIS) potentiostatic measurements were performed under illumination in a frequency range of 0.1 Hz to 1 MHz using a Ω Metrohm Autolab to obtain the interfacial impedance and electron lifetime in the DSSC layers, allowing for the analysis of the charge transfer kinetics.
Synthesis of MSNs. MSNs were synthesized following a modified procedure from the literature [32,33,34]. This procedure was chosen due to the long-range order of hexagonal pores that extend in parallel along the synthesized spheroidal particles. In a typical experiment, 2.00 g (5.48 mmol) of CTAB was added to a solution containing 0.56 g (14.0 mmol) NaOH dissolved in 480 mL of nanopure water. The solution was heated to 85˚C and stirred for 1 h to completely dissolve the CTAB. Then, 10 mL of TEOS was rapidly injected into the solution and stirred at 85 °C for 2 h, precipitating into a white suspension of MSN–CTAB. The precipitate was filtered and rinsed twice with nanopure water and once with methanol, then dried overnight in a vacuum oven. Subsequently, 1.5 g of the MSN–CTAB was refluxed in a solution containing 160 mL of methanol and 9 mL of HCl (37%) (18:1 v/v) for 24 h at 75 °C to remove the surfactant template (CTAB). The resulting MSN hot suspension was then filtered, rinsed three times with methanol, and left to dry overnight.
Photoanode Preparation. FTO substrates were patterned via chemical etching, where zinc paste (100 mg Zn powder + 0.5 mL nanopure H2O) was deposited on the FTO layer and etched with aqueous HCl (18.5% v/v) added dropwise, then rinsed with nanopure water. To ensure the removal of surface contaminants, the patterned substrates were thoroughly cleaned by ultrasonication in the following steps: (1) a soap solution of Hellmanex III in nanopure water (2%), (2) nanopure water, (3) acetone, (4) ethanol, and (5) isopropanol at 80 °C; at each step, the substrates were cleaned for 15 min and dried under nitrogen flow. The substrates were treated with an MTI EQ-PCE-66 UV ozone cleaner for 30 min to further remove organic surface contaminants and ensure proper adhesion of the TiO2 layer with FTO. A compact layer of TiO2 (c-TiO2) was deposited via the spray pyrolysis method, where 0.4 M solution of TTIP was sprayed on the effective area of pre-annealed substrates at 450 °C, and then further annealed at 450 °C for 30 min to remove the organic compounds in the precursor and crystallize into the c-TiO2 layer. This serves as an interfacial layer between the m-TiO2 and FTO, as interfaces between the FTO–m-TiO2 and FTO–electrolyte act as recombination sites for photo-generated charge carriers. TiO2 paste was applied on top of the c-TiO2 layer via doctor blading and annealed at 450 °C for 60 min to remove the surfactant template and crystallize into a mesoporous TiO2 layer (m-TiO2), using a mask to produce an effective area of 0.15 cm2. The thickness of c-TiO2 and m-TiO2 films were measured with cross-sectional FE-SEM imaging to be 60 nm and 11.6 µm, respectively (see Figure 1). The m-TiO2 layers were sensitized by submerging the substrates in photoactive N719 dye (0.4 mM) for 20 h and then rinsing with ethanol to remove excess dye from the pores.
Counter Electrode Preparation. FTO substrates were cleaned with the same procedure as the photoanodes. An amount of 30 µL of Plastisol-T was drop-casted onto the substrate and annealed at 450 °C for 30 min to obtain a Pt catalytic layer. This layer catalyzes the reduction of electrolyte at the counter electrode while ensuring rapid and efficient charge transport, which is essential for the overall performance of the device. The MSN reflector solution was prepared by dissolving 25 mg of PVB in 1.5 mL of ethanol and then adding 350 mg of MSNs. PVB was chosen as a binder for the MSNs thanks to its high performance in optical coatings and adhesion with silica. Ethanol acts as an effective solvent for both PVB and MSNs while also providing an adequate evaporation rate at room temperature, allowing for the facile fabrication of smooth and uniform reflector films. The solution was stirred for 1 h until homogeneous and then applied onto the glass side of the Pt coated CE substrate via bar coating. The thickness of the Pt and MSNs films were 25 nm and 50 µm, respectively, as measured by FE-SEM and shown in Figure 2. The photoanode and CE are clipped together with the sensitized m-TiO2 layer facing the Pt layer, minimizing the gap between these layers to reduce the diffusion distance for electrolyte species. The I − / I 3 − redox electrolyte was then inserted via pipette into the gap between the two electrodes, where it infiltrates the mesoporous TiO2 structure to serve as a mediator between the N719 dye molecules and Pt CE. The DSSCs were assembled in a sandwich architecture, shown in Figure 3, where light is initially absorbed by the photoanode, and then unabsorbed light is reflected by the MSN film.

3. Results

3.1. MSNs Characterization

Figure 4a shows TEM images of MSNs with an elongated spheroid morphology and an average particle size of ~300 nm. Pore channels were observed with long range order and in parallel along the semimajor axis. N2 adsorption/desorption measurements (Figure S1) showed a typical type IV isotherm with no hysteresis, indicative of a mesoporous network of narrow width. The specific surface area calculated by the BET method was 1119 m2∙g, while the pore size distribution calculated by the DFT method indicated a uniform average pore diameter of 4.1 nm. DLS measurements (Figure S2) showed a particle size of 281 nm with a standard deviation of ±53 nm.
The low-angle XRD diffraction pattern is shown in Figure 4b and has the characteristic MSN peak at 2θ = 2.18° Bragg’s angle corresponding to the (100) diffraction lattice plane of ordered hexagonal porous structures [35]. Two additional peaks are observed at 2θ = 3.73° and 2θ = 4.30°, which are attributed to the (110) and (200) lattice planes, respectively, indicative of the long-range order of the pore structure. FTIR spectroscopy (Figure S3) of MSNs, MSN–CTAB, and MSN–PVB powder showed silicon dioxide absorption peaks at 1050 cm−1 and 798 cm−1 corresponding to the vibration of Si−O−Si and Si−O bonds, respectively [36,37]. The absence of the CTAB C−N vibration peak at 1479 cm−1 in the MSN spectrum confirmed the removal of surfactant from the mesopores after the acid washing step (as shown in the supporting information).
To investigate the light scattering properties of MSNs, a diffuse reflectance measurement was performed via UV–visible spectroscopy, shown in Figure 4c. The spectrum showed >80% reflectance in the visible range, coinciding with the absorbance range of the N719 dye (350–700 nm) [38]. MSNs with 6.67 wt% PVB were also characterized to determine the effect of binder on light scattering and showed the same magnitude of reflectance with a slight increase in the visible and UV range.
FE-SEM imaging of the MSN reflector microstructure (Figure 5a) shows the arrangement of randomly oriented particles that compose the film. To determine the amount of light being trapped by MSN reflectors applied to DSSCs, UV–visible transmittance measurements were performed (Figure 5b), which demonstrated a highly reduced transmittance in the N719 dye photoactive range compared to a reference DSSC.

3.2. Photovoltaic Measurements

The derived PV parameters, including current density (JSC), open-circuit voltage (VOC), fill factor (FF), and PCE, are summarized in Table 1. With the addition of MSNs as reflectors, the PCE of DSSCs was improved to 6.68% from a reference PCE of 5.57%, showing a 20% increase. This is correlated with an increase in JSC from 12.41 mA/cm2 in reference to 14.60 mA/cm2 with an MSN reflector. These results indicate that the scattering properties of MSNs were successfully employed to diffusely reflect unabsorbed light, extending their path length in the photoactive layers, and thereby increasing the absorption and photocurrent. The VOC also showed a marginal increase from 0.66 V in reference to 0.68 V with MSN reflectors, while the FF remained consistent. The current density versus voltage (J-V) characteristics are plotted in Figure 6a.
To verify the reproducibility of DSSCs enhanced by MSN reflectors, ten reference devices and ten devices with MSN reflectors were fabricated. Shown in Figure 6b, the MSN reflectors reliably increased the PCE, with a deviation of ±0.2%. For all enhanced devices, the JSC was increased with a deviation of ±0.7 mA/cm2. The narrow deviation in these results indicate that this method is a reliable option for boosting DSSC performance.

3.3. Charge Transport Measurements

The PV performance was further evaluated by analyzing the charge transfer mechanisms using EIS measurements, with the charge transfer resistances and electron lifetime summarized in Table 2. Nyquist and Bode plots were obtained under illumination using the obtained VOC values to estimate the charge transport kinetics within the cell. The Nyquist plots, shown in Figure 6c, show two semicircles fitted with an equivalent circuit model (Inset of Figure 6c), where Q is the constant phase element. The diameter of the first semicircle in the high-frequency range is the charge transfer resistance at the CE–electrolyte interface (R1) and the diameter of the second semicircle in the low-frequency range is the resistance at the photoanode–electrolyte interface (R2). The series resistance (Rs) is obtained from the real-axis intercept of the high-frequency semicircle. A decrease in R2 is observed with the addition of MSN reflectors, indicating reduced resistance for the transport of electrons in the photoanode, which is in congruence with the increased JSC. A marginal increase in R1 is also observed, likely as a result of increasing temperature due to absorption of reflected photons by the CE layers, as measured by UV–vis absorbance of the CEs with and without MSN reflectors (Figure S4).
To further elucidate the charge transport kinetics, the electron lifetime in the photoanode–electrolyte interface was estimated from the maximum angular frequency (ꞷmax) using Equation (1):
  τ = 1 ω m a x = 1 2 π ƒ m a x
where ƒ m a x is the maximum frequency in the low frequency region of the Bode plot (Figure 6d). The electron lifetime remained the same after the addition of MSN reflectors, suggesting that the rate of recombination was not significantly affected.

4. Discussion

MSNs have unique optical properties due to their size, morphology, and mesoporous structure. The particle size of ~300 nm measured by TEM and DLS is reported to produce Mie scattering of light in the visible range [22,39,40,41]. Moreover, the spheroidal morphology and geometrical irregularities on the particle surface amplify backward scattering [42,43,44]. The large specific surface area as calculated by the BET method exceeds 1100 m2/g, while the pore size distribution calculated by the DFT method indicates a uniform average of pores. As showed by the TEM images, the MSNs showcase uniform parallel pores which contributes to the light management, as could be inferred from the ability of these overall amorphous materials to exhibit X-ray diffraction. The sum of these properties increases the diffuse reflectance of MSNs, which showed that ~85% of light in the visible range is reflected. These results indicate that the optical properties of MSNs are closely aligned with the requirements for reflective layers in DSSCs. When applied as a reflector film, the multi-oriented mesoporous particles act as multiple scattering modes that confine unabsorbed light within the system [45]. The UV–visible transmittance of a DSSC with MSN reflector showed a significant portion of light being trapped, with near-zero transmittance from 300–550 nm. This confirms that MSNs recycle unabsorbed light back into the photoactive layers, serving as an effective light trapping layer for increasing light absorption.
The addition of MSN reflectors reliably enhanced light harvesting in DSSCs, as evidenced by the increased PCE and JSC. Photons are diffusely reflected by the MSN, extending their path length and rate of absorption in the sensitized film, thereby increasing the concentration of charge carriers according to published reports in the field [46,47]. As a result, the introduction of MSNs led to an increase in the photocurrent of the device, driven by its significant dependence on the quantity of absorbed photons, in direct correlation with the photocurrent. The decrease in R2 indicates an improvement in the electron transport rate owing to reduced impedance at the photoanode–electrolyte interface [48,49]. Since there was no change in the electron lifetime at this interface, the reduced impedance can be attributed to a decrease in the diffusion resistance across the m-TiO2 layer, corroborating the improved charge transport kinetics and facilitating the generation of a higher photocurrent [50,51]. The increased VOC is likely caused by an increase in temperature due to the absorption of photons by the CE layers. This is supported by the increase in R1, which corresponds to the counter electrode–electrolyte interface, along with UV–visible absorbance measurements of CEs that showed increased absorbance of visible light with the addition of MSNs.
These results agree with the existing literature for DSSC back reflectors. Zdyb and Krawczak, for instance, achieved a 15.7% increase in PCE with a 19.7% increase in JSC by using BaSO4 as a back reflector on DSSCs using N719 dye, and obtained even larger increases in PCE when used on alternative sensitizing dyes [52]. This speaks to the promise that highly reflective materials have for increasing light harvesting in solar cells. Employing materials with low-cost and simple fabrication, such as MSNs, is crucial for the integration of this method into existing and future PV technologies. Such methods that achieve high PCE in DSSCs are an essential requirement for their use in portable electronics, as the output of energy must be sufficient to balance the costs of fabrication and implementation.

5. Conclusions

In conclusion, MSNs were successfully employed as scattering back reflectors in DSSCs, resulting in their improved light harvesting capability by reusing unabsorbed incident light and hence enhancing the overall PCE of DSSCs. The synthesized MSNs exhibited significant diffuse reflectance of visible light, coinciding with the absorption range of N719 dye. The uniform, parallel pores of MSNs coated in thin films facilitated the trapping of unabsorbed photons and reflected them back into the photoactive layers, increasing light absorption. As a result, MSN reflectors successfully improved the performance of DSSCs, showing a 20% increase in PCE from a reference 5.57% to 6.68%. The main contributor to this enhancement is the JSC, which increased from 12.41 mA/cm2 in the reference cell to 14.60 mA/cm2 with MSNs, owing to their diffuse reflectance of unabsorbed photons. Other performance parameters, such as VOC and charge transport rate, were also improved, demonstrating additional benefits from the implementation of MSN reflectors, as the enhanced flow of electrons through the device layers improved the overall operation of the device.
The use of MSNs as a CE back reflector was demonstrated to be an effective method for boosting the performance of thin film solar cells. This heightens the viability of DSSCs for integration into electronic devices, as the increased harvesting of ambient light enhances their performance in indoor and low-light conditions. Improving the efficiency of PV energy conversion is essential for the commercial viability and widespread adoption of emergent PV technology. Additional research into the optimization of nanoparticle properties, materials, and fabrication methods could further enhance the performance of diffuse back reflectors. Investigations into the scalability of MSN reflectors and their compatibility with industrial manufacturing methods are still necessary to gain further understanding of the role these reflectors play in developing solar cell technology.

Supplementary Materials

The following supporting information can be downloaded at: https://www.mdpi.com/article/10.3390/electronicmat4030010/s1, Figure S1. MSN Nitrogen porosity measurements; Figure S2. DLS distribution curve of MSNs dispersed in ethanol; Figure S3. FTIR spectra of MSN before and after surfactant removal; and after formulated into PVB; Figure S4. UV–visible absorbance spectrum of platinum counter electrodes with and without MSN reflector film.

Author Contributions

Conceptualization: J.F., N.K., C.-Y.L. and D.R.R.; methodology: J.F. and N.K.; formal analysis, J.F., N.K. and C.-Y.C.; data curation, J.F., N.K. and C.-Y.C.; writing—original draft preparation, J.F. and N.K; writing—review and editing, D.R.R. and C.-Y.L.; supervision, D.R.R. and C.-Y.L.; project administration, D.R.R.; funding acquisition, D.R.R. and C.-Y.L. All authors have read and agreed to the published version of the manuscript.

Funding

This material is based upon work supported in part by NASA Award #80NSSC19M0201, NASA Award #80NSSC21M0310, and the National Science Foundation under Grant No. DMR-2122078 and Grant No. CBET-1924412.

Data Availability Statement

Data is available from the authors upon reasonable request.

Acknowledgments

The authors thank Jake Carrier for help in collecting and analyzing the BET and DFT data.

Conflicts of Interest

The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript; or in the decision to publish the results.

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Figure 1. Cross-sectional SEM image of c-TiO2 and m-TiO2 films.
Figure 1. Cross-sectional SEM image of c-TiO2 and m-TiO2 films.
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Figure 2. Cross-sectional SEM image of Pt and MSN films.
Figure 2. Cross-sectional SEM image of Pt and MSN films.
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Figure 3. Concept visualization of DSSCs with MSN reflector films.
Figure 3. Concept visualization of DSSCs with MSN reflector films.
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Figure 4. (a) TEM image of MSNs with inset showing the parallel pores. (b) XRD spectrum of MSNs as synthesized (MSN-As) and after acid wash (MSN-Aw). (c) UV–visible reflectance spectrum of MSNs.
Figure 4. (a) TEM image of MSNs with inset showing the parallel pores. (b) XRD spectrum of MSNs as synthesized (MSN-As) and after acid wash (MSN-Aw). (c) UV–visible reflectance spectrum of MSNs.
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Figure 5. (a) FE-SEM image of MSN reflector microstructure (b) UV–visible transmittance spectrum of full DSSCs with and without MSN reflectors.
Figure 5. (a) FE-SEM image of MSN reflector microstructure (b) UV–visible transmittance spectrum of full DSSCs with and without MSN reflectors.
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Figure 6. (a) J-V curves of reference DSSCs and DSSCs with MSN reflector films. (b) Reproducibility of reference DSSCs and DSSCs with MSN reflector films. (c) Nyquist plots of reference DSSCs and DSSCs with MSN reflectors fitted with the equivalent circuit model. (d) Bode plots of reference DSSCs and DSSCs with MSN reflector films.
Figure 6. (a) J-V curves of reference DSSCs and DSSCs with MSN reflector films. (b) Reproducibility of reference DSSCs and DSSCs with MSN reflector films. (c) Nyquist plots of reference DSSCs and DSSCs with MSN reflectors fitted with the equivalent circuit model. (d) Bode plots of reference DSSCs and DSSCs with MSN reflector films.
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Table 1. PV Parameters of DSSCs with and without MSN reflectors.
Table 1. PV Parameters of DSSCs with and without MSN reflectors.
Device ConfigurationJSC (mA/cm2)VOC (V)FFPCE (%)
FTO/c-TiO2/m-TiO2/N719/Electrolyte/Pt/FTO12.410.660.675.57
FTO/c-TiO2/m-TiO2/N719/Electrolyte/Pt/FTO/MSNs14.600.680.676.68
Table 2. PV Parameters of DSSCs with and without MSN reflectors.
Table 2. PV Parameters of DSSCs with and without MSN reflectors.
Device ConfigurationR1 (Ω · cm2)R2 (Ω · cm2)Rs (Ω · cm2)τ (ms)
FTO/c-TiO2/m-TiO2/N719/Electrolyte/Pt/FTO1.813.176.6210.1
FTO/c-TiO2/m-TiO2/N719/Electrolyte/Pt/FTO/MSNs1.933.096.3010.1
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Fina, J.; Kaur, N.; Chang, C.-Y.; Lai, C.-Y.; Radu, D.R. Enhancing Light Harvesting in Dye-Sensitized Solar Cells through Mesoporous Silica Nanoparticle-Mediated Diffuse Scattering Back Reflectors. Electron. Mater. 2023, 4, 124-135. https://doi.org/10.3390/electronicmat4030010

AMA Style

Fina J, Kaur N, Chang C-Y, Lai C-Y, Radu DR. Enhancing Light Harvesting in Dye-Sensitized Solar Cells through Mesoporous Silica Nanoparticle-Mediated Diffuse Scattering Back Reflectors. Electronic Materials. 2023; 4(3):124-135. https://doi.org/10.3390/electronicmat4030010

Chicago/Turabian Style

Fina, Jeffrie, Navdeep Kaur, Chen-Yu Chang, Cheng-Yu Lai, and Daniela R. Radu. 2023. "Enhancing Light Harvesting in Dye-Sensitized Solar Cells through Mesoporous Silica Nanoparticle-Mediated Diffuse Scattering Back Reflectors" Electronic Materials 4, no. 3: 124-135. https://doi.org/10.3390/electronicmat4030010

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