The Crystal Chemistry of Inorganic Hydroborates †
Abstract
:1. Introduction
2. Anions Packing
3. Controlling Anions Packing
4. Preferred Cation Sites
5. Anions and Cations Dynamics
6. Anions Chemistry
7. Classification of Inorganic Hydroborates
8. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References and Note
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Cation | Compound | Space Group | Structural Prototype | Cation Coordination by Anions | Cation Coordination by Hydrogen and Halogen | Anion Coordination | Aristotype of Anion Packing | Ref. |
---|---|---|---|---|---|---|---|---|
Li+closo- | rt-α-Li2B12H12 | Pa | anti-CaF2, cF12, 225 | Tri-bi | Oct | Oct | ccp | [62] |
closo- | ht-β-Li2B12H12 | Fm | anti-CaF2, cF12, 225 | Tri | ccp | [63,64] | ||
closo- | rt-Li2B10H10 | P6222 | anti-CaF2, cF12, 225 | Tri-bi | Oct | 6-fold | {336.446.59} 14-c net; tcc-x | [29] |
closo- | ht-Li2B10H10 | [29] | ||||||
closo- | rt-LiCB11H12 | Pca21 | NaCl, cF8, 225 | Tri-bi | Oct | Tri | ccp | [65] |
closo- | ht-LiCB11H12 | Fmm | ccp | [65] | ||||
closo- | rt-α-LiCB11H6Cl6 | Pnma | NaCl, cF8, 225 | Lin-tri | Oct | NLin | ccp | [66] |
closo- | ht-γ-LiCB11H6Cl6 | P63/mmc | Lin, Tri | hcp | [66] | |||
closo- | rt-α-LiCB11H6Br6 | Pnma | NaCl, cF8, 225 | Lin-tri | Oct | NLin | ccp | [66] |
closo- | ht-γ-LiCB11H6Br6 | P63/mmc | Lin, Tri | hcp | [66] | |||
closo- | rt-LiCB9H10 | [48] | ||||||
closo- | ht1-LiCB9H10 | Cmc21 | wurtzite, hP4, 186 | hcp | [48] | |||
closo- | ht2-LiCB9H10 | P31c | wurtzite, hP4, 186 | hcp | [48] | |||
nido- | rt-LiB11H14 | Pbca | sphalerite, cF8, 216 | Tri-mon | Oct | NTri | ccp | [67] |
nido- | ht-LiB11H14 | Fm | sphalerite, cF8, 216 | Tri | ccp | [67] | ||
closo- | rt1-Li2(CB9H10) (CB11H12) | P31c | wurtzite, hP4, 186 | hcp | [68] | |||
closo- | rt2-Li2(CB9H10) (CB11H12) | Fmm | ccp | [68] | ||||
nido, closo- | Li(B11H14)x (CB11H12)1−x (x = 1/2, 1/3, 2/3) | Pca21 | NaCl, cF8, 225 | Tri | Tri | ccp | [67] | |
nido, closo- | Li2-x(B11H14)x(B12H12)1−x (x = 1/2) | Pa | anti-CaF2, cF12, 225 | Tri | Tri | ccp | [67] | |
nido, closo- | Li(B11H14)x (CB9H10)1−x (x = 1/2) | P31c | wurtzite, hP4, 186 | Tet | Tet | hcp | [67] | |
Na+closo- | α-rt-Na2B12H12 | P21/n (P21/c) | anti-CaF2, cF12, 225 | Tet-mon, bi, tri | 10-fold | Cub | ccp | [21,30] |
closo- | β-ht1-Na2B12H12 | Pmn | Ag2S, cI20, 229 | Tet | bcc | [21,30] | ||
closo- | γ-ht2-Na2B12H12 | Imm | Ag2S, cI20, 229 | Tet | bcc | [21,30] | ||
closo- | δ-ht3-Na2B12H12 | Fm | anti-CaF2, cF12, 225 | Tet | Cub | ccp | [21] | |
closo- | ε-hp1-Na2B12H12 | Pbca | anti-CaF2, cF12, 225 | Tri-bi, tri | 7-fold | Oct | ccp | [69] |
closo- | ζ-hp2-Na2B12H12 | Pnnm | anti-CaF2, cF12, 225 | Tet-mon, bi, tri | 9-fold | Cub | ccp | [69] |
closo- | m-Na2B12H12−xIx | Pc | Ni2In (Co1.75Ge), hP6, 194 | Tet, Tri | 6-fold | hcp | [21] | |
closo- | h-Na2B12H12−xIx | P63mc | Ni2In (Co1.75Ge), hP6, 194 | Tet, Tri | Tet | hcp | [21] | |
closo- | rt-Na2B10H10 | P21/c | anti-CaF2, cF12, 225 | Tet-bi, Tet-mon, bi, tri | 8-fold, 7-fold | Cub | ccp | [70] |
closo- | ht-Na2B10H10 | Fmm | anti-CaF2, cF12, 225 | Tet, Oct | ccp | [70] | ||
arachno- | NaB3H8 | Pmn21 | NaCl, cF8, 225 | Oct-mon, bi | 11-fold | Oct | ccp | [71] |
closo- | rt-NaCB11H12 | Pca21 | NaCl, cF8, 225 | Tri-bi | Oct | Tri | ccp | [65] |
closo- | ht-NaCB11H12 | Fmm | ccp | [65] | ||||
closo- | rt-α-NaCB11H6Cl6 | Pbca | sphalerite, cF8, 216 | Tri-bi, tri | PentBiPyr | NTri | ccp | [66] |
closo- | ht-γ-NaCB11H6Cl6 | P63/mmc | Lin, Tri | hcp | [66] | |||
closo- | ht-γ-NaCB11H6Br6 | P63/mmc | Lin, Tri | hcp | [66] | |||
closo- | lt-NaCB9H10 | P21/c | AgI, cI38, 229 | Tet-bi | 8-fold | Tet | bcc | [72] |
closo- | rt-NaCB9H10 | Pna21 | AgI, cI38, 229 | Tet-bi | 8-fold | Tet | bcc | [72] |
closo- | ht-NaCB9H10 | P31c | wurtzite, hP4, 186 | hcp | [48] | |||
nido- | rt-NaB11H14 | Pna21 | wurtzite, hP4, 186 | Tet, Oct | Tet | hcp | [47,73] | |
nido- | lt-NaB11H14 | Pna21 | wurtzite, hP4, 186 | Tet-bi, tri | 9-fold | Tet | hcp | [47] |
nido- | ht-NaB11H14 | I3d | bcc | [73] | ||||
nido- | rt-Na-7-CB10H13 | Pna21 | wurtzite, hP4, 186 | Tet-mon, bi, tri | SqAntPris | 4-fold | hcp | [73] |
nido- | ht-Na-7-CB10H13 | Fmm | ccp | [73] | ||||
nido- | rt-Na-7,8-C2B9H12 | P21 | [73] | |||||
nido- | ht-Na-7,8-C2B9H12 | P31c | hcp | [73] | ||||
nido- | rt-Na-7,9-C2B9H12 | Pna21 | wurtzite, hP4, 186 | Tet-mon, bi, tri | 1cap-SqAntPris | 4-fold | hcp | [73] |
nido- | ht-Na-7,9-C2B9H12 | Fmm | ccp | [73] | ||||
closo- | Na2(B12H12)0.75(B10H10)0.25 | bcc | [74] | |||||
closo- | Na2(B12H12)0.50(B10H10)0.50 | Fmm | anti-CaF2, cF12, 225 | Tet, Oct | ccp | [75] | ||
closo- | rt-Na2-x(CB11H12)x(B12H12)1−x (x = 1/2, 1/3, 2/3) | I23 | Ag3SI, (anti-perovskite) cP5, 221 | Tet | bcc | [22] | ||
closo- | ht1-Na2-x(CB11H12)x(B12H12)1−x (x = 1/3) | Pmn | Ag3SI, (anti-perovskite) cP5, 221 | Tet | bcc | [22] | ||
closo- | ht2-Na2-x(CB11H12)x(B12H12)1−x (x = 1/3) | Imm | Ag3SI, (anti-perovskite) cP5, 221 | Tet | bcc | [22] | ||
closo- | Na3(CB9H10) (B12H12) | P21c | Ag3SI, (anti-perovskite) cP5, 221 | Tet | bcc | [18] | ||
closo- | Na3(CB11H12) (B10H10) | Pnnm | anti-CaF2, cF12, 225 | Tet, Tri | ccp | [18] | ||
closo- | rt1-Na2(CB9H10) (CB11H12) | P31c | wurtzite, hP4, 186 | Tri | hcp | [18,68] | ||
closo- | rt2-Na2(CB9H10) (CB11H12) | Fmm | ccp | [68] | ||||
nido, closo- | Na2-x(B11H14)x(B12H12)1−x (x = 1/2, 2/3) | Imm | Ag3SI, (anti-perovskite) cP5, 221 | Tet | bcc | [47] | ||
nido, closo- | rt-Na2-x(B11H14)x(B12H12)1−x (x = 1/3) | Pmn | Ag3SI, (anti-perovskite) cP5, 221 | Tet | bcc | [47] | ||
nido, closo- | ht-Na2-x(B11H14)x(B12H12)1−x (x = 1/3) | Imm | Ag3SI, (anti-perovskite) cP5, 221 | Tet | bcc | [47] | ||
nido, closo- | Na3BH4B12H12 | Cmc21 | novel | Tet | CrB | [23] | ||
K+closo- | K2B12H12 | Fm | anti-CaF2, cF12, 225 | Tet-tri | Cuboct | Cub | ccp | [76] |
closo- | K2B10H10 | P21/c | Ni2In (Co1.75Ge), hP6, 194 | Tet-tri, Oct-mon, bi, tri, tetra | 12-fold, 14-fold | 2cap-SqAntPris | hcp | [77] |
arachno- | α-KB3H8 | P21/m | NaCl, cF8, 225 | Oct-tri, tetra, penta | 24-fold | Oct | ccp | [78] |
arachno- | α’-KB3H8 | Cmcm | NaCl, cF8, 225 | Oct-bi, tri, tetra | 18-fold | Oct | ccp | [78] |
arachno- | β-KB3H8 | Fmm | NaCl, cF8, 225 | Oct | Oct | ccp | [78] | |
closo- | K2B6H6 | Fmm | anti-CaF2, cF12, 225 | Tet-tri | Cuboct | Cub | ccp | [79] |
closo- | rt-KCB11H12 | P21/c | NaCl, cF8, 225 | Oct-mon, bi, tri | 12-fold, 10-fold | Oct | ccp | [80] |
closo- | ht-KCB11H12 | Fmm | NaCl, cF8, 225 | Oct | Oct | ccp | [80] | |
closo, closo- | KB21H18 | C2 | NiAs, hP4, 194 | TriAntPris-mon, tri | 14-fold | TriPris | hcp | [81] |
nido, closo- | m-K3BH4B12H12 | P2/c | Ag3SI, (anti-perovskite) cP5, 221 | Oct-bi, tri | 14-fold | BH4-Oct, B12H12-Cuboct | bcc | [82] |
nido, closo- | r-K3BH4B12H12 | Rm | Ag3SI, (anti-perovskite) cP5, 221 | Oct | BH4-Oct, B12H12-Cuboct | bcc | [82] | |
nido, closo- | c-K3BH4B12H12 | P23 | Ag3SI, (anti-perovskite) cP5, 221 | Oct | BH4-Oct, B12H12-Cuboct | bcc | [82] | |
Rb+closo- | Rb2B12H12 | Fm | anti-CaF2, cF12, 225 | Tet-tri | Cuboct | Cub | ccp | [83] |
closo- | rt-Rb2B10H10 | P21/c | Ni2In (Co1.75Ge), hP6, 194 | Tet-bi, tri, tetra Oct-mon, bi, tri, tetra | 12-fold, 17-fold | 3cap-SqAntPris | hcp | [77,84] |
closo- | lt-Rb2B10H10 | P | Ni2In (Co1.75Ge), hP6, 194 | Tet-bi, tri, tetra Oct-mon, bi, tri, tetra | 12-fold, 17-fold | 3cap-SqAntPris | hcp | [84] |
closo- | Rb2B9H9 | P4/nmm | anti-BiF3, cF16, 225 | Tet-tri, SqPyr-bi, tri | Cuboct, 14-fold | 4cap-TriPris | ccp | [85] |
closo, closo- | Rb2B20H18 | Pna21 | anti-MoSi2, tI6, 139 | SqPyr-mon, tri | 13-fold | 2cap-Cub | Mo in MoSi2 {348.466.56} 16-c net | [86] |
nido, closo- | Rb3BH4B12H12 | P23 | Ag3SI, (anti-perovskite) cP5, 221 | Oct | BH4-Oct, B12H12-Cuboct | bcc | [87] | |
Cs+closo- | rt-Cs2B12H12 | Fm | anti-CaF2, cF12, 225 | Tet-tri | Cuboct | Cub | ccp | [88] |
closo- | ht-Cs2B12H12 | Fmm | anti-CaF2, cF12, 225 | Tet | Cub | ccp | [89] | |
closo- | Cs2B6H6 | Fmm | anti-CaF2, cF12, 225 | Tet-tri | Cuboct | Cub | ccp | [90] |
arachno- | CsB3H8 | Ama2 | NaCl, cF8, 225 | Oct-bi, tri, tetra | 16-fold | Oct | ccp | [90] |
closo- | Cs2B8H8 | Pnma | Ni2In (Co1.75Ge), hP6, 194 | Tet-tri, SqPyr-bi, tri | 12-fold | 1cap-SqAntPris | hcp | [91] |
nido- | CsB9H14 | P | CsCl, cP2, 221 | Cub | Cub | aa | [92] | |
closo, closo- | CsB21H18 | P21/c | NaCl, cF8, 225 | TriAntPris-mon, bi, tri | 15-fold | TriAntPris | ccp | [93] |
closo- | rt-CsCB11H12 | R3 (R3/c above 323 K) | novel | Oct-bi, tri | 15-fold | 6-fold | hcp | [94] |
closo- | ht-CsCB11H12 | I3d | Th3P4, cI28, 220 | Oct-bi, tri | 14-fold | 8-fold | hcp | [94] |
closo- | CsCB11H6Cl6 | P2/c | CsCl, cP2, 221 | Cub-bi, tri | 6cap-Cub, 16-fold | Cub | aa | [95] |
closo- | CsCB11H11Br1 | P21/n | NaCl, cF8, 225 | Oct-mon, bi, tri | 12-fold | Oct | ccp | [96] |
closo- | CsCB11H6Br6 | P2/c | CsCl, cP2, 221 | Cub-bi, tri | 6cap-Cub, 16-fold | Cub | aa | [95] |
closo- | CsCB9H5Br5 | P4/nmm | sphalerite, cF8, 216 | Tet-tri | Cuboct | Tet | ccp | [95] |
nido- | α-CsC2B9H12 | I4 | AgI, cI38, 229 | Tet | SqPris | bcc | [97] | |
nido- | β-CsC2B9H12 | P21/c | NiAs, hP4, 194—CsCl, cP2, 221 | 8-fold | 8-fold | hcp | [97] | |
nido- | γ-CsC2B9H12 | P21/c | NiAs, hP4, 194 | Oct | TriPris | hcp | [97] | |
closo, closo- | Cs(B21H18–xFx) (x = 2.55–2.85) | P21/n (P21/c) | NiAs, hP4, 194 | TriAntPris-bi, tri, tetra | 18-fold | TriPris | hcp | [93] |
closo, closo- | Cs(B21H18–xFx) (x = 2.85–3) | P212121 | NiAs, hP4, 194 | TriAntPris-bi, tri, tetra | 18-fold | TriPris | hcp | [93] |
nido, closo- | Cs3BH4B12H12 | P23 | Ag3SI, (anti-perovskite) cP5, 221 | Oct-bi | Cuboct | BH4-Oct, B12H12-Cuboct | bcc | [98] |
Be2+arachno- | Be(B3H8)2 | P21/c | Lin-bi | Tet | ccp of Be(B3H8)2 molecules | [99] | ||
arachno- nido- | Be(B5H10)BH4 | P21/c | Lin-bi | Tet | ccp of Be(B5H10)BH4 molecules | [100] | ||
Ca2+closo- | CaB12H12 | C2/c | BN-b, hP4, 194 | TriBiPyr-mon, bi | 8-fold | TriBiPyr | hcp | [101] |
closo- | α-CaB10H10 | Cc | wurtzite, hP4, 186 | Tet-mon, tri | 10-fold | Tet | hcp | [102] |
closo- | β-CaB10H10 | Pbca | FePO4, oP48, 61 | Tet-bi, tri | 10-fold | Tet | hcp | [102] |
Sr2+closo- | SrB12H12 | P31c | wurtzite, hP4, 186 | Tet-tri | Cuboct | Tet | hcp | [103] |
Ba2+closo- | BaB12H12 | P31c | wurtzite, hP4, 186 | Tet-tri | Cuboct | Tet | hcp | [103] |
Cr2+arachno- | Cr(B3H8)2 | P | Lin-bi | Sq | aa of Cr(B3H8)2 molecules | [104] | ||
Mn2+closo- | MnB12H12 | P31c | BN-b, hP4, 194 | Lin-tri | Oct | Lin | hcp | [105] |
Fe2+closo- | FeB12H12 | R | Lin-tri | Oct | Tri | bcc | [105] | |
Co2+closo- | CoB12H12 | R | Lin-tri | Oct | Tri | bcc | [106] | |
Ni2+closo- | NiB12H12 | R | Lin-tri | Oct | Tri | bcc | [106,107] | |
Cu+closo- | Cu2B12H12 | Pn | Cu2O, cP6, 224 | Lin-bi | 4-fold | Tet | bcc | [106] |
Ag+closo- | α-Ag2B12H12 | Pa | anti-CaF2, cF12, 225 | Tri-bi | TriAntPris | TriAntPris | ccp | [108] |
closo- | β-Ag2B12H12 | Fmm | anti-CaF2, cF12, 225 | Tet | Cub | ccp | [108] | |
closo- | α-Ag2B10H10 | P4/nnc | anti-CaF2, cF12, 225 | Tet-tri | Cuboct | Cub | ccp | [108] |
closo- | β-Ag2B10H10 | Fmm | anti-CaF2, cF12, 225 | Tet | Cub | ccp | [108] | |
closo- | AgCB9H10 | P21/m | NaCl, cF8, 225 | TriAntPris-mon, tri | 10-fold | TriPris | ccp | [109] |
closo- | AgCB11H6Br6 | Pnma | NaCl, cF8, 225 | Lin-tri | Oct | NLin | ccp | [110] |
Hg2+closo- | HgB12H12 | P | CsCl, cP2, 221 | Cub | Cub | ccp | [111] | |
Tl+closo- | Tl2B10H10 | Fm | anti-CaF2, cF12, 225 | Tet-tri | Cuboct | Cub | ccp | [112] |
Pb2+closo- | PbB12H12 | P31c | wurtzite, hP4, 186 | Tet-tri | Cuboct | Tet | hcp | [113] |
Cation | Compound | Space Group | Structural Prototype | Cation Coordination by Anions | Cation Coordination by Hydrogen | Anion Coordination | Anion Packing | Ref. |
---|---|---|---|---|---|---|---|---|
Li+, Na+closo- | rt-(Lix,Na1−x)2B12H12 (x = 0.33–0.67) | Pa | anti-CaF2, cF12, 225 | Tri-bi | Oct | Oct | ccp | [114] |
closo- | ht-(Lix,Na1−x)2B12H12 (x = 0.377) | Fmm | anti-CaF2, cF12, 225 | Tri | ccp | [115] | ||
nido-, closo- | (Li0.7Na0.3)3BH4B12H12 | Pna21 | novel | Tet | FeB | [23] | ||
Li+, K+closo- | rt-LiKB12H12 | P63mc | Ni2In (Co1.75Ge), hP6, 194 | Li-Tri-bi, K-Oct-bi, tri | Li-TriPris K-15-fold | 3cap-TriPris | hcp | [116] |
closo- | ht-(Lix,K1−x)2B12H12 (x = 0.8) | P63mc | Ni2In (Co1.75Ge), hP6, 194 | Li-Tri, (K,Li)-Oct | 3cap-TriPris | hcp | [21] | |
Li+, Cs+closo- | rt-LiCsB12H12 | Pn21a | Ni2In (Co1.75Ge), hP6, 194 | Li-Tri, Cs-Oct | 3cap-TriPris | hcp | [21] | |
closo- | ht-LiCsB12H12 | P63mc | Ni2In (Co1.75Ge), hP6, 194 | Li-Tri, Cs-Oct | 3cap-TriPris | hcp | [21] | |
closo- | meta-(Lix,Cs1−x)2B12H12 (x = 0.11) | P63mc | Ni2In (Co1.75Ge), hP6, 194 | (Cs,Li)-Tri, Tet Cs-Oct | 10-fold | hcp | [21] | |
Na+, K+closo- | rt-(Nax,K1−x)2B12H12 (x = 0.5) | Fm | anti-CaF2, cF12, 225 | Tet-tri | Cuboct | Cub | ccp | [21] |
closo- | ht-(Nax,K1−x)2B12H12 (x = 0.5) | Pmn | Ag2S, cI20, 229 | Tet | bcc | [21] | ||
closo- | rt-NaKB12H12 | P1 | Ni2In (Co1.75Ge), hP6, 194 | Na-Tet, K-Oct | 4cap-TriPris | hcp | [21] | |
closo- | ht-NaKB12H12 | P63mc | Ni2In (Co1.75Ge), hP6, 194 | Na-Tet, K-Oct | 4cap-TriPris | hcp | [21] | |
Na+, Cs+closo- | rt-NaCsB12H12 | P | Ni2In (Co1.75Ge), hP6, 194 | Na-Tet, Cs-Oct | 4cap-TriPris | hcp | [21] | |
closo- | ht1-NaCsB12H12 | P21/c | Ni2In (Co1.75Ge), hP6, 194 | Na-Tet, Cs-Oct | 4cap-TriPris | hcp | [21] | |
closo- | ht2-NaCsB12H12 | Pn21a | Ni2In (Co1.75Ge), hP6, 194 | Na-Tet, Cs-Oct | 4cap-TriPris | hcp | [21] | |
closo- | ht3-NaCsB12H12 | P63mc | Ni2In (Co1.75Ge), hP6, 194 | Na-Tet, Cs-Oct | 4cap-TriPris | hcp | [21] | |
Cs+,Cu+closo- | Cs(CuB10H10) | Pbcn | novel | Cs- Oct-mon, bi, tri Cu-Lin-bi | Cs-15-fold Cu-Tet | 8-fold | ccp | [117] |
Cs+,Ag+closo- | Cs(AgB10H10) | Pbcm | anti-BiF3, cF16, 225 | Cs-Oct-mon, bi, tri Ag-Tet-bi | Cs-15-fold Ag-8-fold | 2cap-SqAntPris | ccp | [118] |
Cation | Compound | Space Group | Structural Prototype | Cation Coordination by Anions | Cation Coordination by Hydrogen | Anion Coordination | Anion Packing | Ref. |
---|---|---|---|---|---|---|---|---|
NH4+ closo- | (NH4)2B12H12 | Fm | anti-CaF2, cF12, 225 | Tet-tri | Cuboct | Cub | ccp | [83] |
closo- | (NH4)2B10H10 | P21/c | Ni2In (Co1.75Ge), hP6, 194 | Tet, Oct | 8-fold | hcp | [119] | |
arachno- | NH4B3H8 | Cmcm | NaCl, cF8, 225 | Oct-bi, tri, tetra | 18-fold | Oct | ccp | [120] |
N2H5+ closo- | (N2H5)2B12H12 | C2/c | anti-AlB2, hP3, 191 | TriPris | HexPris | aa | [121] | |
N(n-Bu4)+ closo- | N(n-Bu4)B8H9 | P41 | LiSe subnet in NH4LiSeO4, oP28, 33 | Tet | Sq | aa | [91] | |
closo- | N(n-Bu4)2B7H7 | P21/n (P21/c) | anti-NiP subnet in Ba2Ni(PO4)2, mP52, 14 | Tri, Lin | TriBiPyr | hcp | [122] | |
closo- | N(n-Bu4)B7H8 | P41 | LiSe subnet in NH4LiSeO4, oP28, 33 | Sq | Sq | aa | [122] | |
Ph4P+ closo- | lt-(Ph4P)B8H9 | P2/c | CsCl, cP2, 221 | SqAntPris | Cub | aa | [91] | |
closo- | rt-(Ph4P)B8H9 | P4/n | CsCl, cP2, 221 | SqAntPris | Cub | aa | [91] | |
Ph3P+ nido- | (Ph3P)B11H14 | P21/m | BN-b, hP4, 194 | TriBiPyr | TriBiPyr | aa | [123] | |
PNP+ closo- | (PNP)B7H8 | P21/c | novel | 9-fold | 9-fold | aa | [122] | |
HAgu+ closo- | (HAgu)2B12H12 | P | anti-AlB2, hP3, 191 | TriPris | HexPris | aa | [124] | |
HAgu+ Cu2+ closo- | (Cu0.61H0.78Agu2)B12H12 | P | CsCl, cP2, 221 | RhoPris | RhoPris | aa | [124] |
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Černý, R.; Brighi, M.; Murgia, F. The Crystal Chemistry of Inorganic Hydroborates. Chemistry 2020, 2, 805-826. https://doi.org/10.3390/chemistry2040053
Černý R, Brighi M, Murgia F. The Crystal Chemistry of Inorganic Hydroborates. Chemistry. 2020; 2(4):805-826. https://doi.org/10.3390/chemistry2040053
Chicago/Turabian StyleČerný, Radovan, Matteo Brighi, and Fabrizio Murgia. 2020. "The Crystal Chemistry of Inorganic Hydroborates" Chemistry 2, no. 4: 805-826. https://doi.org/10.3390/chemistry2040053