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Open AccessFeature PaperCommunication

A Brucite-Like Mixed-Valent Cluster Capped by [MnIIIp-tBu-calix[4]arene] Moieties

EaStCHEM School of Chemistry, University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh EH9 3FJ, UK
Institute of Chemical Sciences, School of Engineering and Physical Sciences, Heriot-Watt University, Riccarton, Edinburgh EH14 4AS, UK
Authors to whom correspondence should be addressed.
Current address: Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, 18071 Granada, Spain.
Chemistry 2020, 2(2), 253-261;
Received: 30 March 2020 / Revised: 7 April 2020 / Accepted: 8 April 2020 / Published: 9 April 2020
(This article belongs to the Special Issue Supramolecular Chemistry in the 3rd Millennium)
p-tBu-calix[4]arene (H4TBC[4]) has proven to be an incredibly versatile ligand for the synthesis of 3d- and 3d/4f- clusters, in particular those containing mixed-valent Mn ions. These are of interest to the magnetochemist for the diversity of magnetic behaviours that can be shown, along with a huge variety of nuclearities and topologies accessible, which allow one to outline magneto-structural correlations and a quantitative understanding of their properties. This contribution reports the synthesis, analysis and magnetic properties of a Brucite-like Mn-oxo/hydroxo octanuclear fragment encapsulated within/capped by four [MnIII-TBC[4]] moieties. A diol coligand in the reaction mixture plays a seemingly important role in determining the outcome, though it is not incorporated in the final structure. View Full-Text
Keywords: calixarenes; coordination clusters; manganese; molecular magnetism calixarenes; coordination clusters; manganese; molecular magnetism
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Coletta, M.; Palacios, M.A.; Brechin, E.K.; Dalgarno, S.J. A Brucite-Like Mixed-Valent Cluster Capped by [MnIIIp-tBu-calix[4]arene] Moieties. Chemistry 2020, 2, 253-261.

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