A Brucite-Like Mixed-Valent Cluster Capped by [MnIIIp-tBu-calix[4]arene]− Moieties
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis and Structural Studies
2.2. Magnetic Behaviour
3. Conclusions
Author Contributions
Funding
Conflicts of Interest
Appendix A
References
- Ferreira, K.N.; Iverson, T.M.; Maghlaoui, K.; Barber, J.; Iwata, S. Architecture of the photosynthetic oxygen-evolving center. Science 2004, 303, 1831–1838. [Google Scholar] [CrossRef] [Green Version]
- Ali, B.; Iqbal, M.A. Coordination complexes of manganese and their biomedical applications. ChemistrySelect 2017, 2, 1586–1604. [Google Scholar] [CrossRef]
- Sampson, M.D.; Nguyen, A.D.; Grice, K.A.; Moore, C.E.; Rheingold, A.L.; Kubiak, C.P. Manganese catalysts with bulky bipyridine ligands for the electrocatalytic reduction of carbon dioxide: Eliminating dimerization and altering catalysis. J. Am. Chem. Soc. 2014, 136, 5460–5471. [Google Scholar] [CrossRef] [PubMed]
- Diehl, S.J.; Lehmann, K.J.; Gaa, J.; McGill, S.; Hoffmann, V.; Georgi, M. MR Imaging of pancreatic lesions. Comparison of manganese-DPDP and gadolinium chelate. Invest. Radiol. 1999, 34, 589–595. [Google Scholar] [CrossRef] [PubMed]
- Davis, K.M.; Palenik, M.C.; Yan, L.; Smith, P.F.; Seidler, G.T.; Dismukes, G.C.; Pushkar, N. X-ray Emission Spectroscopy of Mn Coordination Complexes towards Interpreting the Electronic Structure of the Oxygen Evolving Complex of Photosystem II. J. Phys. Chem. C 2016, 120, 3326–3333. [Google Scholar] [CrossRef]
- Sessoli, R.; Boulon, M.-E.; Caneschi, A.; Mannini, M.; Poggini, L.; Wilhelm, F.; Rogalev, A. Strong magneto-chiral dichroism in a paramagnetic molecular helix observed by hard X-ray. Nat. Phys. 2015, 11, 69–74. [Google Scholar] [CrossRef] [Green Version]
- Shiga, T.; Nojiri, H.; Oshio, H. A Ferromagnetically Coupled Octanuclear Manganese(III) Cluster: A Single-Molecule Magnet with a Spin Ground State of S = 16. Inorg. Chem. 2020. [Google Scholar] [CrossRef]
- Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M.A. Magnetic bistability in a metal-ion cluster. Nature 1993, 365, 141–143. [Google Scholar] [CrossRef]
- McCusker, J.K.; Schmitt, E.A.; Hendrickson, D.N. High Spin Inorganic Clusters: Spin Frustration in Polynuclear Manganese and Iron Complexes. In Magnetic Molecular Materials; Gatteschi, D., Kahn, O., Miller, J.S., Palacio, F., Eds.; NATO ASI Series (Series E: Applied Sciences); Springer: Dordrecht, The Netherlands, 1991; Volume 198. [Google Scholar]
- Liedy, F.; Eng, J.; McNab, R.; Inglis, R.; Penfold, T.J.; Brechin, E.K.; Johansson, J.O. Vibrational coherences in manganese single-molecule magnets after ultrafast photoexcitation. Nat. Chem. 2020. [Google Scholar] [CrossRef]
- Evangelisti, M.; Brechin, E.K. Recipes for enhanced molecular cooling. Dalton Trans. 2010, 39, 4672–4676. [Google Scholar] [CrossRef] [Green Version]
- Asfari, F.; Bilyk, A.; Bond, C.; Harrowfield, J.M.; Koutsantonis, G.A.; Langkeek, N.; Mocerino, M.; Skelton, B.W.; Sovolev, A.N.; Strano, S.; et al. Factors influencing solvent adduct formation by calixarenes in the solid state. Org. Biomol. Chem. 2004, 2, 387–396. [Google Scholar] [CrossRef] [PubMed]
- Karotsis, G.; Teat, S.J.; Wernsdorfer, W.; Piligkos, S.; Dalgarno, S.J.; Brechin, E.K. Calix[4]arene-based single-molecule magnest. Angew. Chem. Int. Ed. 2009, 48, 8285–8288. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Karotsis, G.; Evangelisti, M.; Dalgarno, S.J.; Brechin, E.K. A calix[4]arene 3d/4f magnetic cooler. Angew. Chem. Int. Ed. 2009, 48, 9928–9931. [Google Scholar] [CrossRef] [PubMed]
- Taylor, S.M.; McIntosh, R.D.; Piligkos, S.; Dalgarno, S.J.; Brechin, E.K. Calixarene-supported clusters: Employment of complementary cluster ligands for the construction of a ferromagnetic [Mn5] cage. Chem. Commun. 2012, 48, 11190–11192. [Google Scholar] [CrossRef] [Green Version]
- McLellan, R.; Palacios, M.A.; Sanz, S.; Brechin, E.K.; Dalgarno, S.J. Importance of Steric Influences in the Construction of Multicomponent Hybrid Polymetallic Clusters. Inorg. Chem. 2017, 56, 10044–10053. [Google Scholar] [CrossRef] [Green Version]
- Coletta, M.; Brechin, E.K.; Dalgarno, S.J. Structural trends in calix[4]arene-supported cluster chemistry. In Calixarenes and Beyond; Neri, P., Sessler, J.L., Wang, M.-X., Eds.; Springer International Publishing: Cham, Switzerland, 2016; Chapter 25; pp. 671–689. [Google Scholar]
- Sone, T.; Ohba, Y.; Moriya, K.; Kumada, H.; Kazuski, I. Synthesis and properties of sulfur-bridged analogs of p-tert-Butylcalix[4]arene. Tetrahedron 1997, 53, 10689–10698. [Google Scholar] [CrossRef]
- Mislin, G.; Graf, E.; Hosseini, M.W.; Bilyk, A.; Hall, A.K.; Harrowfield, J.M.; Skelton, B.W.; White, A.H. Thiacalixarenes as cluster keepers: Synthesis and structural analysis of a magnetically coupled tetracopper(II) square. Chem. Commun. 1999, 373–374. [Google Scholar] [CrossRef]
- Iki, N.; Kabuto, C.; Fukushima, T.; Kumagai, H.; Takeya, H.; Miyanari, S.; Miyashi, T.; Miyano, S. Synthesis of p-tert-Butylthiacalix[4]arene and its Inclusion Property. Tetrahedron 2000, 56, 1437–1443. [Google Scholar] [CrossRef]
- Morohashi, N.; Iki, N.; Sugawara, A.; Miyano, S. Selective oxidation of thiacalix[4]arenes to the sulfinyl and sulfonyl counterparts and their complexation abilities toward metal ions as studied by solvent extraction. Tetrahedron 2001, 57, 5557–5563. [Google Scholar] [CrossRef]
- Bi, Y.F.; Du, S.C.; Liao, W.P. Thiacalixarene-based nanoscale polyhedral coordination cages. Coord. Chem. Rev. 2014, 276, 61–72. [Google Scholar] [CrossRef]
- Su, K.Z.; Jiang, F.L.; Qian, J.J.; Chen, L.; Pang, J.D.; Bawaked, S.M.; Mokhtar, M.; A-Thabaiti, S.A.; Hong, M.C. Stepwise Construction of Extra-Large Heterometallic Calixarene-Based Cages. Inorg. Chem. 2015, 54, 3183–3188. [Google Scholar] [CrossRef] [PubMed]
- Schnack, J. Effects of frustration on magnetic molecules: A survey from Olivier Kahn until today. Dalton Trans. 2010, 39, 4677–4686. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Coletta, M.; Sanz, S.; McCormick, L.J.; Teat, S.J.; Brechin, E.K.; Dalgarno, S.J. The remarkable influence of N,O-ligands in the assembly of a bis-calix[4]arene-supported [Mn IV2MnIII10Mn II8] cluster. Dalton Trans. 2017, 46, 16807–16811. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Rajaraman, G.; Murugesu, M.; Sañudo, E.C.; Soler, M.; Wernsdorfer, W.; Helliwell, M.; Muryn, C.; Raftery, J.; Teat, S.J.; Christou, G.; et al. A Family of Manganese Rods: Syntheses, Structures, and Magnetic Properties. J. Am. Chem. Soc. 2004, 126, 15445–15457. [Google Scholar] [CrossRef] [PubMed]
- Manoli, M.; Collins, A.; Parsons, S.; Candini, A.; Evangelisti, M.; Brechin, E.K. Mixed-Valent Mn Supertetrahedra and Planar Discs as Enhanced Magnetic Coolers. J. Am. Chem. Soc. 2008, 130, 11129–11139. [Google Scholar] [CrossRef] [Green Version]
- Berg, N.; Rajeshkumar, T.; Taylor, S.M.; Brechin, E.K.; Rajaraman, G.; Jones, L.F. What Controls the Magnetic Interaction in bis-μ-Alkoxo MnIIIDimers? A Combined Experimental and Theoretical Exploration. Chem. Eur. J. 2012, 18, 5906–5918. [Google Scholar] [CrossRef] [Green Version]
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Coletta, M.; Palacios, M.A.; Brechin, E.K.; Dalgarno, S.J. A Brucite-Like Mixed-Valent Cluster Capped by [MnIIIp-tBu-calix[4]arene]− Moieties. Chemistry 2020, 2, 253-261. https://doi.org/10.3390/chemistry2020016
Coletta M, Palacios MA, Brechin EK, Dalgarno SJ. A Brucite-Like Mixed-Valent Cluster Capped by [MnIIIp-tBu-calix[4]arene]− Moieties. Chemistry. 2020; 2(2):253-261. https://doi.org/10.3390/chemistry2020016
Chicago/Turabian StyleColetta, Marco, Maria A. Palacios, Euan K. Brechin, and Scott J. Dalgarno. 2020. "A Brucite-Like Mixed-Valent Cluster Capped by [MnIIIp-tBu-calix[4]arene]− Moieties" Chemistry 2, no. 2: 253-261. https://doi.org/10.3390/chemistry2020016