Material and Imaging Analysis Procedure for the Investigation of Paintings in the Archbishop’s Palace of Seville
Abstract
:1. Introduction
2. Materials and Methods
3. UV and IRR Examination
4. Material Study
4.1. Preparation and Priming
4.2. Pigments
4.2.1. The Virgin and Child
4.2.2. Joseph Sold to the Medianite Merchants
4.3. Later Interventions
5. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
- Valdivieso, E.; Serrera, J.M. Catálogo de las Pinturas del Palacio Arzobispal de Sevilla; Editorial Sever Cuesta: Sevilla, Spain, 1979. [Google Scholar]
- Falcón Márquez, T. El Palacio Arzobispal de Sevilla; Historia y Patrimonio; Archidiócesis de Sevilla: Sevilla, Spain, 2018. [Google Scholar]
- Gómez Sánchez, J.A.; Gutiérrez Carrasquilla, E. La Restauración del Tríptico del Maestro de la Mendicidad del Ayuntamiento de Sevilla; Departamento de Publicaciones Ayuntamiento de Sevilla: Sevilla, Spain, 2014. [Google Scholar]
- Valdivieso, E. Nuevas obras de Pieter Van Lint; Unas vanitas de Arellano y Camilo, Universidad de Valladolid, Seminario de Estudios de Arte y Arqueología: Valladolid, Spain, 1979. [Google Scholar]
- Dorrell, P. Photography in Archaeology and Conservation; Cambridge University Press: Cambridge, UK, 1989. [Google Scholar]
- Mairinger, F. The ultraviolet and fluorescence study of paintings and manuscripts. In Radiation in Art and Archeometry; Creagh, D.C., Bradley, D.A., Eds.; Elsevier: Amsterdam, The Netherlands, 2000; pp. 56–75. [Google Scholar] [CrossRef]
- Mairinger, F. UV-, IR- and X-ray imaging. In Non-Destructive Microanalysis of Cultural Heritage Materials; Janssens, K., Van Grieken, R., Eds.; Elsevier: Amsterdam, The Netherlands, 2004; pp. 15–71. [Google Scholar] [CrossRef]
- Stuart, B.H. Analytical Techniques in Materials Conservation; John Wiley & Sons, Ltd.: Chichester, UK, 2007. [Google Scholar] [CrossRef]
- Hain, M.; Bartl, J.; Jacko, V. Multispectral analysis of cultural heritage artefacts. Meas. Sci. Rev. 2003, 3, 9–12. [Google Scholar]
- van Asperen de Boer, J.R.J. Infrared Reflectography: A Method for the Examination of Paintings. Appl. Opt. 1968, 7, 1711–1714. [Google Scholar] [CrossRef] [PubMed]
- Mairinger, F. The infrared examination of paintings. In Radiation in Art and Archeometry; Creagh, D.C., Bradley, D.A., Eds.; Elsevier: Amsterdam, The Netherlands, 2000; pp. 40–55. [Google Scholar] [CrossRef]
- Faries, M. Analytical capabilities of infrared reflectography: An art historian’s perspective. In Scientific Examination of Art: Modern Techniques in Conservation and Analysis; National Academies Press: Washington, DC, USA, 2005; pp. 87–104. [Google Scholar]
- Ferretti, M. X-ray Fluorescence Applications for the Study and Conservation of Cultural Heritage. In Radiation in Art and Archeometry; Creagh, D.C., Bradley, D.A., Eds.; Elsevier: Amsterdam, The Netherlands, 2000; pp. 285–296. [Google Scholar] [CrossRef]
- Janssens, K. X-ray based methods of analysis. In Non-Destructive Microanalysis of Cultural Heritage Materials; Janssens, K., Van Grieken, R., Eds.; Elsevier: Amsterdam, The Netherlands, 2000; pp. 129–226. [Google Scholar] [CrossRef]
- Glinsman, L.D. The practical application of air-path X-ray fluorescence spectrometry in the analysis of museum objects. Stud. Conserv. 2005, 50, 3–17. [Google Scholar] [CrossRef]
- Artiolo, G. Scientific Methods of Cultural Heritage; Oxford University Press: Oxford, UK, 2010. [Google Scholar]
- Matteini, M.M.A. Scienza e Restauro; Metodi d´indagine, Nardini: Firenze, Italy, 1994. [Google Scholar]
- Volpin, S.A.L. Le Analisi di Laboratorio Applicate ai Beni Artistici Policromi; Il Prato: Padova, Italy, 1999. [Google Scholar]
- Townsend, J.; Doherty, T.; Heydenreich, G.; Ridge, J. Preparation for Paintings: The Artist’s Choice and Its Consequences; Archetype Books: London, UK, 2008. [Google Scholar]
- Barnett, J.R.; Miller, S.; Pearce, E. Colour and art: A brief history of pigments. Opt. Laser Technol. 2006, 38, 445–453. [Google Scholar] [CrossRef]
- Feller, R.L. Roy Ashok FitzHugh Elisabeth West. Berrie Barbara Hepburn. In Artists’ Pigments: A Handbook of Their History and Characteristics; National Gallery of Art: Washington, DC, USA, 1986. [Google Scholar]
- Seccaroni, C.; Moioli, P. Fluorescenza X. Prontuario per l’Analisi XRF Portatile Applicata a Superfici Policrome; Nardini Editore: Firenze, Italy, 2004. [Google Scholar]
- Barbieri, M.; Masi, U.; Tolomeo, L. Origin and distribution of strontium in the travertines of Latium (central Italy). Chem. Geol. 1979, 24, 181–188. [Google Scholar] [CrossRef]
- Harley, R.D. Artists’ Pigments c. 1600–1835; Archetype Publications: London, UK, 2001. [Google Scholar]
- Eastaugh, N.; Walsh, V.; Chaplin, T.; Siddall, R. Pigment Compendium: A Dictionary and Optical Microscopy of Historic Pigments; Butterworth-Heinemann: Oxford, UK, 2008. [Google Scholar]
Preparation/Colour | Pigment | Chemical Formula |
---|---|---|
Preparation | Gypsum | CaSO4 |
Chalk | CaCO3 | |
White | Lead white | 2PbCO3·Pb(OH)2 |
Titanium white | TiO2 | |
Zinc white | ZnO | |
Green | Malachite | CuCO3·Cu(OH)2 |
Verdigris | Cu(CH3COO)2·2H2O | |
Copper resinate | Cu(C19H29COO)2 | |
Chrome green | Cr2H4O5 | |
Yellow | Lead-tin yellow | Pb2SnO4 |
Yellow earth/ochre | Fe(OH)2 | |
Yellow lake | unidentified, Ca substr | |
Red | Red earth/ochre | Fe2O3 |
Vermilion | HgS | |
Minium red | Pb3O4 | |
Red lake | unidentified, Ca substr | |
Cadmium red | CdSe | |
Blue | Azurite | 2CuCO·Cu(OH)2 |
Smalt | not a definite chemical compound, containing Co, Si, K, As (Ni, Bi…) | |
Prussian blue | C18Fe7N18 | |
Brown | Umber | Fe2O3 + MnO2 + nH2O + Si + Al2O3 |
Black | Bone black | Ca3(PO4)2 + CaCO3 + C |
Layer | EDX | Interpretation/Composition | |
---|---|---|---|
Sample (A) | Preparation | Mg, Al, Si, Ca, Mn | Calcite (chalk) with earth grains |
First colour layer | Al, Si, Fe, Sn, Pb | Lead white, lead-tin yellow, earths | |
Second colour layer | Al, Si, Fe, Sn, Pb | Lead white, lead-tin yellow, earths | |
External colour layer | Pb, Sn | Lead white, lead-tin yellow | |
Partial repaint | Mg, Al, Si, Ca, Fe, Pb, | Calcite, earths, lead white. | |
Sample (B) | Preparation | Mg, Al, Si, Ca, Mn | Calcite (chalk) with earth grains |
External colour layer | Al, Si, P, S, Cl, K, Ca, Mn, Fe, Cu, Pb | Calcite, red earths, bone black, umber, lead white, copper resinate, Prussian blue. | |
Sample (C) | Preparation | Mg, Al, Si, Ca, Mn | Calcite (chalk) with earth grains |
External colour layer | Mg, Al, Si, P, Cl, K, Ca, Cu, Pb | bone black, lead white, possible copper resinate |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Moreno-Soto, J.; Križnar, A.; Ager, F.J.; Gómez, A.; Gamero-Osuna, A.; Martín-de-Soto, A.; Respaldiza, M.Á. Material and Imaging Analysis Procedure for the Investigation of Paintings in the Archbishop’s Palace of Seville. Heritage 2023, 6, 4527-4541. https://doi.org/10.3390/heritage6060240
Moreno-Soto J, Križnar A, Ager FJ, Gómez A, Gamero-Osuna A, Martín-de-Soto A, Respaldiza MÁ. Material and Imaging Analysis Procedure for the Investigation of Paintings in the Archbishop’s Palace of Seville. Heritage. 2023; 6(6):4527-4541. https://doi.org/10.3390/heritage6060240
Chicago/Turabian StyleMoreno-Soto, Javier, Anabelle Križnar, Francisco José Ager, Auxiliadora Gómez, Antonio Gamero-Osuna, Agustín Martín-de-Soto, and Miguel Ángel Respaldiza. 2023. "Material and Imaging Analysis Procedure for the Investigation of Paintings in the Archbishop’s Palace of Seville" Heritage 6, no. 6: 4527-4541. https://doi.org/10.3390/heritage6060240