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Exchange-Coupling Behavior in SrFe12O19/La0.7Sr0.3MnO3 Nanocomposites

1
Department of Physics, The University of California Merced, Merced, CA 95343, USA
2
Department of Physics and Materials Science, The University of Memphis, Memphis, TN 38152, USA
*
Author to whom correspondence should be addressed.
Ceramics 2019, 2(1), 100-111; https://doi.org/10.3390/ceramics2010010
Received: 12 December 2018 / Revised: 2 February 2019 / Accepted: 6 February 2019 / Published: 8 February 2019
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Abstract

Magnetically hard-soft (100-x) SrFe12O19-x wt % La0.7Sr0.3MnO3 nanocomposites were synthesized via a one-pot auto-combustion technique using nitrate salts followed by heat treatment in air at 950 °C. X-ray diffraction (XRD), transmission electron microscopy (TEM), and vibrating sample magnetometry (VSM) were used to characterize the structural and magnetic properties of the samples. XRD spectra revealed the formation of a mixture of ferrite and magnetite phases without any trace of secondary phases in the composite. Microstructural images show the proximity grain growth of both phases. The room temperature hysteresis loops of the samples showed the presence of exchange-coupling between the hard and soft phases of the composite. Although saturation magnetization reduced by 41%, the squareness ratio and coercivity of the nanocomposite improved significantly up to 6.6% and 81.7%, respectively, at x = 40 wt % soft phase content in the nanocomposite. The enhancement in squareness ratio and coercivity could be attributed to the effective exchange-coupling interaction, while the reduction in saturation magnetization could be explained on the basis of atomic intermixing between phases in the system. Overall, these composite particles exhibited magnetically single-phase behavior. The adopted synthesis method is low cost and rapid and results in pure crystalline nanocomposite powder. This simple method is a promising way to tailor and enhance the magnetic properties of oxide-based hard-soft magnetic nanocomposites. View Full-Text
Keywords: Sr-hexaferrite; nanocomposite; exchange-coupling; hard-soft nanocomposite; LaSrMnO3 Sr-hexaferrite; nanocomposite; exchange-coupling; hard-soft nanocomposite; LaSrMnO3
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Dahal, J.N.; Neupane, D.; Mishra, S.R. Exchange-Coupling Behavior in SrFe12O19/La0.7Sr0.3MnO3 Nanocomposites. Ceramics 2019, 2, 100-111.

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